Hybrid solid-state cell with a sealed anode structure
An electrochemical cell is provided which includes a cathode, an anode, an electrolyte separator, and an anode current collector located on the anode. The anode is a three-dimensional (3D) porous anode including ionically conducting electrolyte strands and pores which extend through the anode from the anode current collector to the electrolyte separator. The anode also includes electronically conducting networks extending on sidewall surfaces of the pores from the anode current collector to the electrolyte separator.
1. An electrochemical cell comprising:
a cathode;
an anode;
an electrolyte separator, comprised of a ceramic material, located between the cathode and the anode; and
an anode current collector, wherein the anode is located between the anode current collector and the electrolyte separator,
wherein the anode comprises a three dimensional (3D) porous anode including:
ionically conducting electrolyte strands extending through the anode from the anode current collector to the electrolyte separator;
pores extending through the anode from the anode current collector to the electrolyte separator; and
an electronically conducting network extending on sidewall surfaces of the pores from the anode current collector to the electrolyte separator,
wherein:
the anode is disposed in an anode receptive space, the cathode is disposed in a cathode receptive space, the anode receptive space is sealed, and the cathode receptive space is partially sealed; and
the cathode receptive space includes a filling aperture including a seal configured to isolate a catholyte material contained in the cathode receptive space, and the seal is configured to provide pressure relief for the cathode receptive space.
2. The electrochemical cell of claim 1 , wherein the electronically conducting network comprises partial coverage of the sidewall surfaces of the pores.
3. The electrochemical cell of claim 2 , wherein the partial coverage ranges between 30-70% of a total of the sidewall surfaces of the pores.
4. The electrochemical cell of claim 1 , wherein a thickness of the electronically conducting network is between 0.01 μm and 1.0 μm.
5. The electrochemical cell of claim 4 , wherein a diameter of each of the pores is less than 100 μm, preferably less than 50 μm, less than 10 μm, and more preferably less than 5 μm.
6. The electrochemical cell of claim 1 , wherein the electronically conducting network is comprised of at least one material from a group consisting of a metal, a carbon material, a semiconductor material, a conducting polymer, and an electronically conducting ceramic, or combinations thereof.
7. The electrochemical cell of claim 1 , wherein the electronically conducting network is comprised of lithium.
8. The electrochemical cell of claim 1 , wherein the electronically conducting network is comprised of a carbon material including at least one selected from a group consisting of carbon black, activated carbon, graphite, graphene, carbon fiber, and carbon nanotubes, or combinations thereof.
9. The electrochemical cell of claim 1 , wherein the electronically conducting network is comprised of at least one material selected from a group consisting of silver, copper, and nickel, or combinations thereof.
10. The electrochemical cell of claim 1 , wherein the electronically conducting network is comprised of a material formed from an electronically conducting material precursor incorporated into a sacrificial pore forming material used to create the pores, wherein the sacrificial pore forming material is configured to decompose during formation of the pores, and wherein the electronically conducting material precursor is configured to coat the sidewall surfaces of the pores to form the electronically conducting network upon completion of formation of the pores.
11. The electrochemical cell of claim 1 , wherein the electrochemical cell is configured to be used to form a lithium-ion battery, and wherein the electronically conducting network is comprised of a material which conducts electrons from the anode current collector along the sidewall surfaces of the pores to combine with lithium ions from the ionically conducting electrolyte strands at the sidewall surfaces of the pores to form lithium in the pores during charging of the lithium-ion battery.
12. An electrochemical cell comprising:
a cathode;
an anode;
an electrolyte separator, comprised of a ceramic material, located between the cathode and the anode; and
an anode current collector, wherein the anode is located between the anode current collector and the electrolyte separator,
wherein the anode comprises a three dimensional (3D) porous anode including:
ionically conducting electrolyte strands extending through the anode from the anode current collector to the electrolyte separator;
pores extending through the anode from the anode current collector to the electrolyte separator; and
an electronically conducting network extending on sidewall surfaces of the pores from the anode current collector to the electrolyte separator, and
wherein the cathode is comprised of a catholyte which includes liquid catholyte material located in a cathode receptive space.
13. An electrochemical cell comprising:
a cathode;
an anode;
an electrolyte separator, comprised of a ceramic material, located between the cathode and the anode; and
an anode current collector, wherein the anode is located between the anode current collector and the electrolyte separator,
wherein the anode comprises a three dimensional (3D) porous anode including:
ionically conducting electrolyte strands extending through the anode from the anode current collector to the electrolyte separator;
pores extending through the anode from the anode current collector to the electrolyte separator; and
an electronically conducting network extending on sidewall surfaces of the pores from the anode current collector to the electrolyte separator, and
wherein the cathode is comprised of a catholyte which includes powder catholyte material located in a cathode receptive space.
14. The electrochemical cell of claim 12 , wherein the anode comprises a low porosity border configured to completely seal the anode from a surrounding environment.
15. The electrochemical cell of claim 1 , wherein the anode comprises a low porosity border configured to completely seal the anode from a surrounding environment.
16. The electrochemical cell of claim 12 , wherein the electronically conducting network is comprised of a material formed from an electronically conducting material precursor incorporated into a sacrificial pore forming material used to create the pores, wherein the sacrificial pore forming material is configured to decompose during formation of the pores, and wherein the electronically conducting material precursor is configured to coat the sidewall surfaces of the pores to form the electronically conducting network upon completion of formation of the pores.
17. The electrochemical cell of claim 12 , wherein the electrochemical cell is configured to be used to form a lithium-ion battery, and wherein the electronically conducting network is comprised of a material which conducts electrons from the anode current collector along the sidewall surfaces of the pores to combine with lithium ions from the ionically conducting electrolyte strands at the sidewall surfaces of the pores to form lithium in the pores during charging of the lithium-ion battery.
18. The electrochemical cell of claim 1 , wherein the cathode is comprised of a catholyte which includes liquid catholyte material located in the cathode receptive space.
19. The electrochemical cell of claim 1 , wherein the cathode is comprised of a catholyte which includes powder catholyte material located in the cathode receptive space.
20. The electrochemical cell of claim 2 , wherein the electronically conducting network comprises a web or mesh type structure on the sidewall surfaces of the pores.