Golf balls having covers made with thermoplastic polyurethane and polydimethylsiloxane blend compositions
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and polydimethylsiloxane compound. Functionalized polydimethylsiloxane compounds also can be used to treat thermoplastic polyurethane golf ball covers. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)—light stabilizers, and other additives. The coating methods have many benefits and the finished balls with thermoplastic polyurethane covers have good physical properties.
1. A golf ball comprising:
i) a core having at least one layer; and
ii) an outer cover layer disposed about the core, the outer cover layer comprising a thermoplastic polyurethane composition, the composition comprising a reaction product of thermoplastic polyurethane and functionalized polydimethylsiloxane compound;
wherein the functionalized polydimethylsiloxane compound is a di-functional hydroxyl-terminated compound and has a hydroxyl value in the range of about 18 to about 28 KOH/g.
2. The golf ball of claim 1 , wherein the polyurethane is the reaction product of polyisocyanate and polyol compounds and hydroxyl-terminated chain extender, and the polyisocyanate is selected from the group consisting of 4,4′-methylene diphenyl diisocyanate; 2,4′-methylene diphenyl diisocyanate; toluene 2,4-diisocyanate; toluene 2,6-diisocyanate; 4,4′-dicyclohexylmethane diisocyanate; p-phenylene diisocyanate; isophorone diisocyanate; 1,6-hexamethylene diisocyanate; and oligomers and homopolymers and copolymers and blends thereof.
3. The golf ball of claim 1 , wherein the polyurethane is the reaction product of polyisocyanate and polyol compounds and hydroxyl-terminated chain extender, and the polyol is selected from the group consisting of polyether polyols, hydroxyl-terminated polybutadiene, polyester polyols, polycaprolactone polyols, and polycarbonate polyols, and mixtures thereof.
4. The golf ball of claim 1 , wherein the polyurethane is the reaction product of polyisocyanate and polyol compounds and hydroxyl-terminated chain extender, and the chain extender is selected from the group consisting of 1,4-butylene glycol, ethylene glycol, diethylene glycol, butanediol, hexanediol, trimethylolpropane, and poly(tetramethylene ether) glycol; and mixtures thereof.
5. The golf ball of claim 1 , wherein the core comprises an inner core and surrounding outer core layer.
6. The golf ball of claim 1 , wherein the reaction product is of a thermoplastic polyurethane, functionalized polydimethylsiloxane compound, and catalyst.
7. The golf ball of claim 6 , wherein the catalyst is selected from the group consisting of dibutyl tin dilaurate, dibutyl tin acetylacetonate, dibutyl tin dibutoxide, dibutyl tin sulfide, dibutyl tin di-2-ethylhexanoate, dibutyl tin (IV) diacetate, dialkyltin (IV) oxide, tributyl tin laurylmercaptate, dibutyl tin dichloride, organo lead, tetrabutyl titanate, tertiary amines, mercaptides, stannous octoate, potassium octoate, zinc octoate, diazo compounds, and potassium acetate, and mixtures thereof.
8. The golf ball of claim 1 , wherein the thermoplastic polyurethane composition further comprises an ultraviolet-light stabilizer.
9. The golf ball of claim 1 , wherein the thermoplastic polyurethane composition further comprises a pigment.