Curable composition, storage container, and three-dimensional object producing method
A curable composition is provided. The curable composition contains a multifunctional urethane (meth)acrylate monomer (component 1), a (meth)acrylate monomer (component 2), and an inorganic filler (component 3). A mass content ratio (component 1:component 2) of the component 1 to the component 2 is from 65:35 through 40:60.
1 . A curable composition, comprising:
a multifunctional urethane (meth)acrylate monomer, represented as component 1;
a (meth)acrylate monomer, represented as component 2; and
an inorganic filler, represented as component 3,
wherein a mass content ratio (component 1:component 2) of the component 1 to the component 2 is from 65:35 through 40:60.
2 . The curable composition according to claim 1 ,
wherein a refractive index difference Δn25D (1_3) between a refractive index n25D (1) of the component 1 and a refractive index n25D (3) of the component 3 is 0.07 or less.
3 . The curable composition according to claim 1 ,
wherein a refractive index difference Δn25D (2_3) between a refractive index n25D (2) of the component 2 and a refractive index n25D (3) of the component 3 is 0.07 or less, and
a viscosity of the component 2 at 25° C. is 50 mPa·s or lower.
4 . The curable composition according to claim 1 ,
wherein a refractive index n25D (3) of the component 3 is 1.40 or higher and 1.50 or lower.
5 . The curable composition according to claim 1 ,
wherein a refractive index n25D (2) of the component 2 is 1.48 or lower.
6 . The curable composition according to claim 1 ,
wherein the component 2 includes either or both of ethylene glycol dimethacrylate (n=1) and diethylene glycol dimethacrylate (n=2), which are represented by General formula (2) below,
7 . The curable composition according to claim 1 ,
wherein the component 2 includes a monofunctional (meth)acrylate having a refractive index n25D of 1.48 or lower and a viscosity of 50 mPa·s or lower at 25° C.
8 . The curable composition according to claim 1 ,
wherein the component 1 is an aliphatic urethane dimethacrylate represented by Structural formula (1) below, and
a refractive index n25D (1) of the aliphatic urethane dimethacrylate is 1.50 or lower,
9 . The curable composition according to claim 1 ,
wherein a content of the component 3 is 20% by mass or greater and 60% by mass or less relative to a total amount of the component 1 and the component 2.
10 . The curable composition according to claim 1 ,
wherein a volume mean primary particle diameter of the component 3 is 10 nm or greater and 300 nm or less, and
the component 3 includes silica particles.
11 . The curable composition according to claim 10 ,
wherein carbon is contained in surfaces of the silica particles, and
a content of the carbon is 0.5% by mass or greater and 1.5% by mass or less relative to a mass of the silica particles.
12 . The curable composition according to claim 1 ,
wherein a viscosity of the curable composition at 25° C. is 400 mPa·s or lower.
13 . A storage container, comprising
the curable composition of claim 1 ,
wherein the curable composition is stored in the storage container.
14 . A three-dimensional object producing method, comprising:
discharging the curable composition of claim 1 by an inkjet method; and
curing the curable composition by irradiation with active energy rays.
15 . The curable composition according to claim 1 , wherein the content of the component 1 is 40% by mass or greater relative to the whole amount of the curable composition.
16 . The curable composition according to claim 15 , wherein the content of the component 2 is 35% by mass or greater.
17 . The curable composition according to claim 1 , wherein the inorganic filler content in the composition is about 19% to about 39%.
18 . The curable composition according to claim 12 , wherein the inorganic filler content in the composition is about 19% to about 39%.
19 . The curable composition according to claim 12 ,
wherein the content of the component 1 is 40% by mass or greater and 65% by mass or less relative to the whole amount of the curable composition,
wherein the content of the component 2 is 35% by mass or greater and 60% by mass or less relative to the whole amount of the curable composition, and
wherein the content of the component 3 is 19% by mass or greater and 60% by mass or less relative to a total amount of the component 1 and the component 2.
20 . The curable composition according to claim 12 , wherein the content of the component 1 is 50% by mass or greater and 60% by mass or less relative to the whole amount of the curable composition,
wherein the content of the component 2 is 40% by mass or greater and 50% by mass or less relative to the whole amount of the curable composition, and
wherein the content of the component 3 is 19% by mass or greater and 40% by mass or less relative to a total amount of the component 1 and the component 2.