Compatibilization of immiscible polymers using carbon nanotubes
The present disclosure provides a polymer blend that includes at least two polymers which are immiscible to one another and a carbon nanotube pulp comprising entangled carbon nanotubes as a compatibilizing agent and to a method of preparing the same.
1 . A polymer blend comprising at least two immiscible polymers and a carbon nanotube pulp comprising entangled carbon nanotubes characterized as having two or more of the following characteristics: (i) a diameter of between about 10-100 nm, (ii) a length of between about 0.1-10 mm, (iii) a density of between about 0.3-1.9 g/cm 3 , (iv) an aspect ratio of at least about 250,000, (v) a strain to failure of between about 1.8-7%, and (vi) a surface area from about 100-300 m 2 /g, wherein a first immiscible polymer and a second immiscible polymer are selected from: polyethylene and polyester, polystyrene and polyethylene, maleic anhydride grafted polystyrene and polyethylene, ethylene vinyl acetate and polyvinyl chloride, maleic anhydride grafted polyvinyl chloride and ethylene vinyl acetate, polyvinyl chloride and polycarbonate, polyvinyl chloride and polymethyl methacrylate, polymethyl methacrylate and polyvinyl chloride, styrene acrylonitrile and polycarbonate, polycarbonate and polycaprolactam, polycarbonate and polypropylene, polycarbonate and polyethylene, ethylene vinyl acetate and polypropylene, polyethylene and polypropylene, polyethylene and polystyrene, acrylonitrile butadiene styrene copolymer and polyvinylchloride, polyethylene and polyvinylchloride and polystyrene and polyvinylchloride.
2 . The polymer blend of claim 1 , wherein the carbon nanotubes are non-functionalized.
3 . The polymer blend of claim 1 , wherein the carbon nanotubes are functionalized.
4 . The polymer blend of claim 1 , wherein the carbon nanotube pulp is present in an amount of between about 0.001% by weight to about 20% by weight, based on the total weight of the immiscible polymers.
5 . The polymer blend of claim 4 , wherein the carbon nanotube pulp is present in an amount of between about 0.5% by weight to about 5% by weight, based on the total weight of the immiscible polymers.
6 . The polymer blend of claim 1 , wherein the first immiscible polymer is present in an amount of about 10%-90% by weight and the second immiscible polymer is present in an amount of about 90%-10% by weight, based on the total weight of the immiscible polymers.
7 . The polymer blend of claim 1 , wherein a total amount of immiscible polymers present in the polymer blend is between about 5% by weight to about 99.9% by weight, based on the total weight of the polymer blend.
8 . The polymer blend of claim 1 , further comprising at least one of a surfactant, an electrically conductive filler, an impact modifier, antioxidant, nucleating agent, coupling agent, UV absorber, UV stabilizer, pigment, dye, reinforcing filler, slip agent, plasticizer, processing aid, lubricant, viscosity control agent, tackifier, anti-blocking agent, extender oil, metal deactivator, voltage stabilizer, flame retardant filler, booster, catalyst, smoke suppressant, mold release agent and non-conductive filler.
9 . A polymer blend of claim 1 for use in flame retardant applications, high impact applications and conducting applications.
10 . A pellet comprising the polymer blend of claim 1 .
11 . An article comprising the polymer blend of claim 1 .