IP Library Granted Patent US 12,662,606
Granted Patent B2
US 12,662,606 · App. 17/998,608 · Granted Jun 23, 2026

Three-dimensional printing with food contact compliant agents

Inventors: Emre Hiro Discekici (San Diego, CA); Graciela E Negri Jimenez (San Diego, CA); Thomas M Sabo (San Diego, CA); Jason Butler (San Diego, CA)
Assignee: Peridot Print LLC
C09D171/02B33Y70/00C09D7/20C09D7/45C09D7/61C09D7/63B29C64/165B29K2071/02B33Y30/00C08K3/04C08K5/13C08K5/175C08K5/42
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Quick Facts
Patent No.
US 12,662,606
App. No.
17/998,608
Granted
Jun 23, 2026
Kind
B2
Abstract

The present disclosure is drawn to food contact compliant three-dimensional printing kits, materials, compositions, systems, and methods. In one example, a multi-fluid kit of food contact compliant agents for three-dimensional printing can include a food contact compliant fusing agent and a food contact compliant detailing agent. The food contact compliant fusing agent can include from about 70 wt % to about 96 wt % water, from about 3 wt % to about 10 wt % by solids weight of a food contact compliant carbon black dispersion, and from about 1 wt % to about 25 wt % of a food contact compliant water-soluble first co-solvent. The food contact compliant detailing agent can include from about 75 wt % to about 99 wt % water and from about 0.01 wt % to about 1 wt % of a food contact compliant chelating compound.

Claims (56)

1 . A multi-fluid kit of food contact compliant agents for three-dimensional printing, the multi-fluid kit comprising:

a food contact compliant fusing agent that is jettable from a fluid jet printer, the food contact compliant fusing agent comprising:

from about 70 wt % to about 96 wt % of water based on the total weight of the food contact compliant fusing agent;

a food contact compliant carbon black dispersion present in an amount of from about 3 wt % to about 10 wt % by solids weight of the carbon black dispersion out of the total weight of the food contact compliant fusing agent;

from 0.1 wt % to 0.3 wt % of dioctyl sulfosuccinate sodium salt;

a food contact compliant water-soluble first co-solvent present in the food contact compliant fusing agent in an amount of from about 1 wt % to about 25 wt % based on the total weight of the food contact compliant fusing agent, wherein the food contact compliant water-soluble first co-solvent comprises glycerol and polyethylene glycol; and

2-phenoxyethanol,

wherein the food contact compliant fusing agent is devoid of sodium dodecyl sulfate; and

a food contact compliant detailing agent comprising:

from about 75 wt % to about 99 wt % of water based on the total weight of the food contact compliant detailing agent;

a food contact compliant chelating compound present in an amount of from about 0.01 wt % to about 1 wt % based on the total weight of the food contact compliant detailing agent; and

2-phenoxyethanol.

2 . The multi-fluid kit of claim 1 , wherein the food contact compliant detailing agent further comprises a food contact compliant water-soluble second co-solvent present in an amount of from about 2 wt % to about 24 wt % based on the total weight of the food contact compliant detailing agent, wherein the food contact compliant water-soluble second co-solvent comprises glycerol and propylene glycol.

3 . The multi-fluid kit of claim 1 , wherein:

the 2-phenoxyethanol is present in the food contact compliant fusing agent in an amount of from about 0.2 wt % to about 1 wt % based on the total weight of the food contact compliant fusing agent; and

the 2-phenoxyethanol is present in the food contact compliant detailing agent in an amount of from about 0.2 wt % to about 1 wt % based on the total weight of the food contact compliant detailing agent.

4 . The multi-fluid kit of claim 1 , wherein the food contact compliant detailing agent comprises from about 75 wt % to about 80 wt % of the water based on the total weight of the food contact compliant detailing agent.

5 . The multi-fluid kit of claim 1 , wherein the food contact compliant chelating compound of the food contact compliant detailing agent is disodium ethylenediaminetetraacetate dihydrate.

6 . A three-dimensional printing kit, comprising:

a food contact compliant fusing agent that is jettable from a fluid jet printer, the food contact compliant fusing agent comprising:

from about 70 wt % to about 96 wt % of water based on the total weight of the food contact compliant fusing agent;

a food contact compliant carbon black dispersion present in an amount of from about 3 wt % to about 10 wt % by solids weight of the carbon black dispersion out of the total weight of the food contact compliant fusing agent;

from 0.1 wt % to 0.3 wt % of dioctyl sulfosuccinate sodium salt;

a food contact compliant water-soluble first co-solvent present in the food contact compliant fusing agent in an amount of from about 1 wt % to about 25 wt % based on the total weight of the food contact compliant fusing agent, wherein the food contact compliant water-soluble first co-solvent comprises glycerol and polyethylene glycol; and

2-phenoxyethanol,

wherein the food contact compliant fusing agent is devoid of sodium dodecyl sulfate;

a food contact compliant detailing agent comprising:

from about 75 wt % to about 99 wt % of water based on the total weight of the food contact compliant detailing agent;

a food contact compliant chelating compound present in an amount of from about 0.01 wt % to about 1 wt % based on the total weight of the food contact compliant detailing agent; and

2-phenoxyethanol; and

a thermoplastic polymer powder.

7 . The three-dimensional printing kit of claim 6 , wherein the thermoplastic polymer powder is selected from the group consisting of polyamide-6 powder, polyamide-9 powder, polyamide-11 powder, polyamide-12 powder, polyamide-66 powder, polyamide-612 powder, polyethylene powder, thermoplastic polyurethane powder, thermoplastic polyamide powder, polypropylene powder, polyester powder, polycarbonate powder, polyether ketone powder, polyacrylate powder, polystyrene powder, polyvinylidene fluoride powder, and a combination thereof.

8 . The three-dimensional printing kit of claim 6 , wherein the thermoplastic polymer powder has an average particle size of from about 10 microns to about 200 microns.

9 . The three-dimensional printing kit of claim 6 , wherein:

the food contact compliant detailing agent comprises from about 75 wt % to about 80 wt % of the water based on the total weight of the food contact compliant detailing agent;

the food contact compliant chelating compound is disodium ethylenediaminetetraacetate dihydrate; and

the food contact compliant detailing agent further comprises a food contact compliant water-soluble second co-solvent present in an amount of from about 2 wt % to about 24 wt % based on the total weight of the food contact compliant detailing agent.

10 . A three-dimensional printing system, comprising:

a powder bed comprising a thermoplastic polymer powder;

a fluid jet printer, comprising:

a first fluid ejector in communication with a reservoir of a food contact compliant fusing agent to jet the food contact compliant fusing agent onto the powder bed, wherein the food contact compliant fusing agent comprises:

about 70 wt % to about 96 wt % of water based on the total weight of the food contact compliant fusing agent;

a food contact compliant carbon black dispersion present in an amount of from about 3 wt % to about 10 wt % based on the total weight of the food contact compliant fusing agent;

from 0.1 wt % to 0.3 wt % of dioctyl sulfosuccinate sodium salt;

a food contact compliant water-soluble first co-solvent present in the food contact compliant fusing agent in an amount of from about 1 wt % to about 25 wt % based on the total weight of the food contact compliant fusing agent, wherein the food contact compliant water-soluble first co-solvent comprises glycerol and polyethylene glycol; and

2-phenoxyethanol,

wherein the food contact compliant fusing agent is devoid of sodium dodecyl sulfate; and

a second fluid ejector in communication with a reservoir of a food contact compliant detailing agent to print the food contact compliant detailing agent onto the powder bed, wherein the food contact compliant detailing agent comprises:

from about 75 wt % to about 99 wt % of water based on the total weight of the food contact compliant detailing agent;

a food contact compliant chelating compound present in an amount of from about 0.01 wt % to about 1 wt % based on the total weight of the food contact compliant detailing agent; and

2-phenoxyethanol; and

a fusing radiation source to expose the powder bed to electromagnetic radiation sufficient to fuse thermoplastic polymer powder that has been printed with the food contact compliant fusing agent.

11 . The three-dimensional printing system of claim 10 , wherein:

the food contact compliant detailing agent comprises from about 75 wt % to about 80 wt % of the water based on the total weight of the food contact compliant detailing agent;

the food contact compliant chelating compound is disodium ethylenediaminetetraacetate dihydrate; and

the food contact compliant detailing agent further comprises a food contact compliant water-soluble second co-solvent present in an amount of from about 2 wt % to about 24 wt % based on the total weight of the food contact compliant detailing agent.