Grain-oriented electrical steel sheet and method for forming insulating coating
This grain-oriented electrical steel sheet includes: a base steel sheet; and an insulating coating formed on a surface of the base steel sheet, in which the insulating coating includes an intermediate layer formed on a base steel sheet side and containing a crystalline metal phosphate, and a tension coating layer formed on a surface side of the insulating coating, the surface of the base steel sheet has an etch pit structure, an average thickness of the intermediate layer is 0.2 to 10.0 μm, an average thickness of the insulating coating is 2.0 to 10.0 μm, the tension coating layer contains a metal phosphate and silica, and an amount of the silica in the tension coating layer is 20 to 60 mass %.
1 . A grain-oriented electrical steel sheet comprising:
a base steel sheet; and
an insulating coating formed on a surface of the base steel sheet,
the insulating coating includes
an intermediate layer formed on a base steel sheet side and containing a crystalline metal phosphate, and
a tension coating layer formed on a surface side of the insulating coating,
the surface of the base steel sheet has an etch pit structure,
an average thickness of the intermediate layer is 0.2 to 10.0 μm,
an average thickness of the insulating coating is 2.0 to 10.0 μm,
the tension coating layer contains a metal phosphate and silica, and
an amount of the silica in the tension coating layer is 20 to 60 mass %,
wherein a forsterite-based coating is not formed on the surface of the base steel sheet.
2 . The grain-oriented electrical steel sheet according to claim 1 ,
wherein the crystalline metal phosphate of the intermediate layer comprises one or more of zinc phosphate, manganese phosphate, iron phosphate, and zinc calcium phosphate.
3 . A method for forming the insulating coating included in the grain-oriented electrical steel sheet according to claim 1 , the method comprising:
a secondary recrystallisation annealing process of applying an annealing separating agent containing 10 to 100 mass % of Al 2 O 3 to a steel sheet, drying the steel sheet, and performing secondary recrystallisation annealing on the steel sheet;
an annealing separating agent removing process of removing an excess amount of the annealing separating agent from the steel sheet after the secondary recrystallisation annealing process;
an acid treatment process of immersing the steel sheet after the annealing separating agent removing process in a mixed acid in which a concentration of one or more of sulfuric acid, phosphoric acid, and nitric acid is 0.5 to 20 wt % and a liquid temperature is 40° C. to 90° C. for 5 to 50 seconds;
an immersion process of immersing the steel sheet after the acid treatment process in a treatment liquid containing 5 to 50 mass % of a metal phosphate at a liquid temperature of 40° C. to 85° C. for 5 to 150 seconds;
a drying process of pulling up the steel sheet after the immersion process from the treatment liquid, removing an excess amount of the treatment liquid, and drying the steel sheet; and
a tension coating layer forming process of applying a coating liquid containing a metal phosphate and colloidal silica so that an amount of the colloidal silica is 30 to 150 parts by mass with respect to 100 parts by mass of the metal phosphate to the steel sheet after the drying process, drying the steel sheet, and holding the steel sheet in a state in which a sheet temperature is 700° C. to 950° C. for 10 to 120 seconds.
4 . The method for forming the insulating coating according to claim 3 ,
wherein the annealing separating agent further contains one or two of MgO: 5 to 90 mass % and a chloride: 0.5 to 10.0 mass %.