SiC semiconductor substrate and fabrication method of the SiC semiconductor substrate
A semiconductor substrate ( 1 ) includes: an SiC single crystal substrate ( 10 SB), a first graphene layer ( 11 GR 1 ) disposed on an Si plane of the SiC single crystal substrate 10 SB; an SiC epitaxial growth layer ( 12 RE) formed above the SiC single crystal substrate via the first graphene layer; and a second graphene layer ( 11 GR 2 ) disposed on an Si plane of the SiC epitaxial growth layer. There is also included an SiC polycrystalline substrate ( 16 P) provisionally bonded onto the SiC epitaxial growth layer via the second graphene layer. The SiC single crystal substrate is able to be reused by being separated from the SiC epitaxial growth layer. This semiconductor substrate further includes an SiC polycrystalline growth layer ( 18 PC) CVD grown on the C plane of the SiC epitaxial growth layer; and the SiC epitaxial growth layer is transferred to the SiC polycrystalline growth layer.
1 . An SiC semiconductor substrate, comprising:
an SiC single crystal substrate having an Si plane;
a first graphene layer formed directly on the Si plane of the SiC single crystal substrate;
an SiC epitaxial layer disposed above the SiC single crystal substrate via the first graphene layer, and having an Si plane; and
a second graphene layer having a first surface formed directly on the Si plane of the SiC epitaxial layer, and a second surface opposed to the first surface and having a flat surface on an entirety of the second surface.
2 . The SiC semiconductor substrate according to claim 1 , further comprising
an SiC polycrystalline substrate that is provisionally bonded to the SiC epitaxial layer via the second graphene layer.
3 . The SiC semiconductor substrate according to claim 1 , wherein
the first graphene layer comprises a single-layer structure or multi-layer laminated structure of graphene.
4 . The SiC semiconductor substrate according to claim 2 , wherein
the first graphene layer comprises a single-layer structure or multi-layer laminated structure of graphene.
5 . The SiC semiconductor substrate according to claim 2 , wherein
the SiC polycrystalline substrate comprises a sintered SiC substrate or a CVD substrate.
6 . The SiC semiconductor substrate according to claim 1 , wherein
the SiC single crystal substrate can be reused by being removed from the SiC epitaxial layer.
7 . The SiC semiconductor substrate according to claim 2 , wherein
the SiC single crystal substrate can be reused by being removed from the SiC epitaxial layer.
8 . The SiC semiconductor substrate according to claim 3 , wherein
the SiC single crystal substrate can be reused by being removed from the SiC epitaxial layer.
9 . The SiC semiconductor substrate according to claim 4 , wherein
the SiC single crystal substrate can be reused by being removed from the SiC epitaxial layer.
10 . The SiC semiconductor substrate according to claim 1 , further comprising
an SiC polycrystalline layer grown by CVD on a C plane of the SiC epitaxial layer, wherein
the SiC epitaxial layer is transferred to the SiC polycrystalline layer.
11 . The SiC semiconductor substrate according to claim 2 , further comprising
an SiC polycrystalline layer grown by CVD on a C plane of the SiC epitaxial layer, wherein
the SiC epitaxial layer is transferred to the SiC polycrystalline layer.
12 . The SiC semiconductor substrate according to claim 3 , further comprising
an SiC polycrystalline layer grown by CVD on a C plane of the SiC epitaxial layer, wherein
the SiC epitaxial layer is transferred to the SiC polycrystalline layer.
13 . The SiC semiconductor substrate according to claim 1 , wherein
the SiC single crystal substrate comprises any one crystal structure selected from a group consisting of 4H—SiC, 6H—SiC, and 2H—SiC crystal structures.
14 . The SiC semiconductor substrate according to claim 10 , further comprising
a doped layer formed between the SiC epitaxial layer and the SiC polycrystalline layer, the doped layer having a higher impurity concentration than that of the SiC epitaxial layer.
15 . A fabrication method of an SiC semiconductor substrate, comprising:
forming a first graphene layer directly on an Si plane of an SiC single crystal substrate serving as a basis;
epitaxially growing a first layer formed of a single-crystal SiC semiconductor via the first graphene layer;
forming a second graphene layer directly on an Si plane of the first layer, the second graphene layer having a first surface formed directly on the Si plane of the first layer, and a second surface opposed to the first surface and having a flat surface on an entirety of the second surface;
forming a polycrystal SiC semiconductor substrate via the second graphene layer;
removing the single crystal substrate serving as the basis from the first graphene layer;
eliminating the first graphene layer to expose a C plane of the first layer;
forming a second layer on the C plane of the first layer by CVD growth;
removing the polycrystal SiC semiconductor substrate; and
eliminating the second graphene layer.
16 . The fabrication method of the SiC semiconductor substrate according to claim 15 , wherein
the epitaxially growing the first layer comprises growing the first layer by remote epitaxy on the single crystal substrate serving as the basis.
17 . The fabrication method of the SiC semiconductor substrate according to claim 15 , wherein
a front side surface of the first layer is an Si plane of [0001] orientation of 4H—SiC, and
a C plane of the first layer is a plane of [000-1] orientation of 4H—SiC.
18 . The fabrication method of the SiC semiconductor substrate according to claim 15 , wherein
the forming of the second layer by the CVD growth comprises forming the second layer formed of a polycrystalline SiC semiconductor.
19 . The fabrication method of the SiC semiconductor substrate according to claim 15 , further comprising, after the exposing of the C plane of the first layer, forming a layer having a higher impurity concentration than that of the first layer on the C plane of the first layer.
20 . The fabrication method of the SiC semiconductor substrate according to claim 15 , wherein
the epitaxially growth of the first layer formed of the single-crystal SiC semiconductor via the first graphene layer comprises forming a layer having a higher impurity concentration than that of the first layer at an initial stage of the epitaxial growth.