Paste for ceramic 3D shaping and method for manufacturing three-dimensional shaped object
A paste for ceramic 3D shaping according to the present invention is a paste for ceramic 3D shaping containing a curable resin and inorganic particles, in which the inorganic particles contain ceramic particles and glass particles.
1 . A paste for ceramic 3D shaping comprising:
a curable resin and
inorganic particles,
wherein the inorganic particles comprise ceramic particles and glass particles,
wherein the ceramic particles comprise titanium-oxide based ceramic particles,
wherein an average particle diameter of the ceramic particles is 0.01 μm to 0.49 μm, and
wherein the titanium-oxide based ceramic particles/(the ceramic particles+the glass particles) is, in volume ratio, 0.001 to 0.1.
2 . The paste for ceramic 3D shaping according to claim 1 , wherein the glass particles/(the ceramic particles+the glass particles) is, in volume ratio, 0.01 to 0.5.
3 . The paste for ceramic 3D shaping according to claim 1 , wherein a content of the inorganic particles is 15 vol % or more.
4 . The paste for ceramic 3D shaping according to claim 1 , wherein a content of the ceramic particles is 10 vol % or more.
5 . The paste for ceramic 3D shaping according to claim 1 , wherein the glass particles have a softening point of 550° C. to 1200° C.
6 . The paste for ceramic 3D shaping according to claim 1 , wherein a glass composition of the glass particles comprises, in mass %, 10% to 60% of SiO 2 , 0 to 15% of Al 2 O 3 , 0 to 50% of B 2 O 3 , 0 to 40% of ZnO, 0 to 30% of BaO, 0 to 25% of CaO, 0 to 20% of SrO, 0 to 7% of Na 2 O, 0 to 2% of K 2 O, 0 to 5% of P 2 O 5 , 0 to 3% of ZrO, and 0 to 5% of F 2 .
7 . The paste for ceramic 3D shaping according to claim 1 , wherein the curable resin is a photo-curable resin.
8 . A method for manufacturing a three-dimensional shaped object using the paste for ceramic 3D shaping according to claim 1 , the method comprising:
irradiating the paste for ceramic 3D shaping with an active energy ray to cure the curable resin to obtain a precursor; and
heat-treating the precursor to remove the curable resin and sintering the ceramic particles and the glass particles.
9 . The paste for ceramic 3D shaping according to claim 1 , wherein the titanium-oxide based ceramic particles comprises at least one of titania, barium titanate, and strontium titanate.