Gradient structure cubic boron nitride composite sheet and preparation method thereof
The disclosure provides a gradient structure cubic boron nitride composite sheet and a preparation method thereof. The gradient structure cubic boron nitride composite sheet consists of a cemented carbide substrate, a gradient transition layer, and a CBN layer from bottom to top. The gradient transition layer consists of N gradient layers, and the N is 4 to 18. From bottom to top, there are sequentially a first gradient layer, a second gradient layer, an Nth gradient layer, and so on. Any of the gradient layers consists of CBN and cemented carbide, in which the volume fraction of the cemented carbide in the Nth layer is 5 to 30% less than the volume fraction of the cemented carbide in the N−1th layer, and the volume fraction of the CBN in the Nth layer is 5 to 30% more than the volume fraction of the CBN in the N−1th layer.
1 . A gradient structure cubic boron nitride composite sheet, consisting of a cemented carbide substrate, a gradient transition layer, and a CBN layer from bottom to top, wherein the gradient transition layer consists of N layers of gradient layers, the N is 4 to 18, there are sequentially a first layer of the gradient layers, a second layer of the gradient layers, and Nth layer of the gradient layers from bottom to top, any one layer of the gradient layers consists of CBN and cemented carbide, a volume fraction of the cemented carbide in the Nth layer is 5 to 30% less than a volume fraction of the cemented carbide in the N−1th layer, and a volume fraction of the CBN in the Nth layer is 5 to 30% more than a volume fraction of the CBN in the N−1th layer.
2 . The gradient structure cubic boron nitride composite sheet as claimed in claim 1 , wherein the cemented carbide in the cemented carbide substrate and the gradient layer is Co-WC, a mass fraction of Co is 3 to 30%, and a mass fraction of WC is 70 to 97%.
3 . The gradient structure cubic boron nitride composite sheet as claimed in claim 1 , wherein a total thickness of the gradient transition layer is 0.04 to 5 mm, and a thickness of any one of the gradient layers is 0.01 to 0.5 mm.
4 . A preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 1 , comprising:
mixing a CBN powder and a binder to obtain a CBN mixture;
mixing a CBN powder, a Co powder, a WC powder, and a binder according to designed components of each of the gradient layers to obtain N groups of gradient layer mixtures;
mixing, granulating, and drawing respectively on the prepared CBN mixture and the N groups of gradient layer mixtures to obtain N+1 groups of filament materials;
printing the N+1 groups of filament materials with a 3D printer to obtain N+1 groups of green bodies;
assembling the N+1 groups of green bodies with the cemented carbide substrate to obtain a composite green body; and
performing degreasing and synthesis under a high temperature and a high pressure on the composite green body to obtain the gradient structure cubic boron nitride composite sheet.
5 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , wherein a particle size of the CBN powder is 1 to 100 μm, and a particle size of the Co powder and the WC powder is smaller than or equal to 100 μm;
in the CBN mixture, a mass ratio of the CBN powder to the binder is 2 to 20:1;
in any one group of the gradient layer mixtures, a mass ratio of a total mass of the CBN powder, the Co powder, and the WC powder to the binder is 2 to 20:1.
6 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , wherein a composition of the binder in the CBN mixture and the N groups of gradient layer mixtures is, in terms of a mass percentage, as follows: ethylene-vinyl acetate copolymer 20 to 70%, polystyrene 5 to 35%, polyurethane 5 to 35%, hydrogenated styrene-butadiene block copolymer 1 to 8%, dioctyl phthalate 1 to 7%, vinyl bis stearamide 1 to 6%, and stearic acid 1 to 6%.
7 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , wherein a mixing temperature is 100 to 300° C., and a drawing speed is 10 rpm to 200 rpm; and
diameters of the N+1 group of filament materials are all 1.65 mm to 1.85 mm.
8 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , wherein during the 3D printing process, a printing speed is 10 to 300 mm/s, and a printing temperature is 100 to 350° C.
9 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , comprising:
performing solvent degreasing by first placing the composite green body in a cyclohexane solution and then performing thermal degreasing in a vacuum environment; wherein
a solvent degreasing temperature is 40° C. to 80° C., and a solvent degreasing time is 2 to 6 hours; and
a thermal degreasing process is as the following: first, raising a temperature from a room temperature to 80° C. to 120° C. at a temperature rise rate of 4 to 6° C./min and maintaining for 0.5 to 1 hour; next, raising the temperature to 200° C. to 270° C. at a temperature rise rate of 3 to 6° C./min and maintaining for 2 to 2.5 h; then, raising the temperature to 380° C. to 450° C. at a temperature rise rate of 2.5 to 4° C./min and maintaining for 1 to 2 h; and finally, raising the temperature to 580° C. to 620° C. at a temperature rise rate of 2 to 4° C./min and maintaining for 1.5 to 2 hours.
10 . The preparation method of the gradient structure cubic boron nitride composite sheet as claimed in claim 4 , wherein:
a synthesis temperature of the degreased composite green body is 1400° C. to 2200° C., a synthesis pressure is 3 to 8 GPa, and a synthesis time is 120 s to 1000 s.