Lubricating oil viscosity index improver and lubricating oil composition containing the same
Proposed is a lubricating oil viscosity index improver containing a liquid alpha-olefin copolymer in which ethylene and an alpha-olefin monomer having 3 or more carbon atoms are copolymerized, wherein the liquid alpha-olefin copolymer is characterized by having a weight average molecular weight (Mw) in the range of 10,000 to 120,000 g/mol, a permanent shear stability index (PSSI) of greater than 1 and less than 25, and a thickening power of greater than 2.5 cSt and less than 3.6 cSt at a temperature of 100° C. In addition, proposed is a lubricating oil composition containing the lubricating oil viscosity index improver.
1 . A lubricating oil viscosity index improver comprising a liquid alpha-olefin copolymer in which ethylene and an alpha-olefin monomer having 3 or more carbon atoms are copolymerized,
wherein the liquid alpha-olefin copolymer has a weight average molecular weight (Mw) in a range of 10,000 to 120,000 g/mol, a permanent shear stability index (PSSI) of greater than 1 and less than 25, and a thickening power of greater than 2.5 cSt and less than 3.6 cSt at a temperature of 100° C., and
wherein the liquid alpha-olefin copolymer has a specific gravity in a range of 0.8 to 0.95 at a temperature of 20° C.
2 . The lubricating oil viscosity index improver of claim 1 , wherein the liquid alpha-olefin copolymer is a copolymer in which ethylene and an alpha-olefin monomer having 3 to 6 carbon atoms are copolymerized.
3 . The lubricating oil viscosity index improver of claim 1 , wherein the liquid alpha-olefin copolymer comprises 40 to 60 mol % of an ethylene monomer and 60 to 40 mol % of an alpha-olefin monomer having 3 to 20 carbon atoms.
4 . The lubricating oil viscosity index improver of claim 1 , wherein the liquid alpha-olefin copolymer has a viscosity index (VI) in a range of 130 to 150 when being diluted in a base oil to a concentration of 5 wt %.
5 . The lubricating oil viscosity index improver of claim 1 , wherein the liquid alpha-olefin copolymer has an Mw in a range of 20,000 to 80,000 g/mol.
6 . The lubricating oil viscosity index improver of claim 5 , wherein the liquid alpha-olefin copolymer has a PSSI in a range of 1.5 to 3.5.
7 . A lubricating oil composition comprising:
a base oil; and
the lubricating oil viscosity index improver of claim 1 .
8 . The lubricating oil composition of claim 7 , wherein the lubricating
oil composition comprises 0.1 to 15 wt % of the lubricating oil viscosity index improver and the remainder being the base oil.
9 . The lubricating oil composition of claim 7 , wherein the lubricating oil composition is for use in a gasoline engine oil.
10 . The lubricating oil composition of claim 9 , wherein the lubricating oil composition has a mini-rotary viscometer (MRV) viscosity in a range of 15,000 to 19,000 cP at a temperature of −35° C.
11 . The lubricating oil composition of claim 9 , wherein the lubricating oil composition has a cold cranking simulator (CCS) viscosity of 7,000 cP or less at a temperature of −30° C.
12 . The lubricating oil composition of claim 9 , wherein the lubricating oil composition has a viscosity loss rate of 2% or less at a temperature of 100° C. after 30 cycles of shear in a Bosch pump.
13 . The lubricating oil composition of claim 9 , wherein the lubricating oil composition has a viscosity loss rate of 3% or less at a temperature of 40° C. after 30 cycles of shear in a Bosch pump.
14 . The lubricating oil composition of claim 7 , wherein the lubricating oil composition is for use in a heavy-duty diesel engine oil.
15 . The lubricating oil composition of claim 14 , wherein the lubricating oil composition has an mini-rotary viscometer (MRV) viscosity in a range of 19,000 to 30,000 cP at a temperature of −30° C.
16 . The lubricating oil composition of claim 14 , wherein the lubricating oil composition has a cold cranking simulator (CCS) viscosity of 9,000 cP or less at a temperature of −25° C.
17 . The lubricating oil composition of claim 14 , wherein the lubricating oil composition has a viscosity loss rate of 6% or less at a temperature of 100° C. after 90 cycles of shear in a Bosch pump.
18 . The lubricating oil composition of claim 14 , wherein the lubricating oil composition has a viscosity loss rate of 5% or less at a temperature of 40° C. after 90 cycles of shear in a Bosch pump.