Paramagnetic garnet-type transparent ceramic, magneto-optical device, and production method for paramagnetic garnet-type transparent ceramic
A paramagnetic garnet-type transparent ceramic that exhibits a high laser damage threshold, said ceramic being a sintered body of a Tb-containing rare earth-aluminum garnet represented by formula (1), and being characterized in that the average sintered grain size is 10-40 μm, and the insertion loss at a wavelength of 1,064 nm in the optically effective region along the length direction of a 20 mm-long sample is 0.05 dB or less. ( T b 1 - x - y Y x S c y ) 3 ( Al 1 - z Sc z ) 5 O 12 ( 1 ) ( In the formula , 0 ≤ x < 0.45 , 0 ≤ y < 0.08 , 0 ≤ z < 0.2 , and 0.001 < y + z < 0.2 . )
1 . A paramagnetic garnet type transparent ceramic material which is a sintered body of Tb-containing rare earth aluminum garnet having the formula (1):
(
T
b
1
-
x
-
y
Y
x
S
c
y
)
3
(
Al
1
-
z
Sc
z
)
5
O
12
(
1
)
wherein 0.199≤x<0.45, 0≤y<0.08, 0≤z<0.2, and 0.001<y+z<0.20,
wherein the paramagnetic garnet type transparent ceramic material has an average sintered grain size of from 10 μm to 40 μm, and in the form of a sample of 20 mm long has an insertion loss of up to 0.05 dB at wavelength 1,064 nm in an optical effective region in its longitudinal direction.
2 . The paramagnetic garnet type transparent ceramic material of claim 1 , having a laser-induced damage threshold of at least 20 J/cm 2 at wavelength 1,064 nm and pulse duration 5 ns.
3 . A magneto-optical device constructed using the paramagnetic garnet type transparent ceramic material of claim 1 .
4 . The magneto-optical device of claim 3 which is an optical isolator comprising a Faraday rotator composed of the paramagnetic garnet type transparent ceramic material and polarizers disposed forward and backward of the Faraday rotator on its optical axis, the optical isolator being utilized in a wavelength band of from 0.9 μm to 1.1 μm.
5 . A method of preparing the paramagnetic garnet type transparent ceramic material of claim 1 , comprising the steps of:
pressure-sintering a sintered body of a Tb-containing rare earth aluminum garnet having the formula (1):
(
T
b
1
-
x
-
y
Y
x
S
c
y
)
3
(
Al
1
-
z
Sc
z
)
5
O
12
(
1
)
wherein 0.199≤x<0.45, 0≤y<0.08, 0≤z<0.2, and 0.001<y+z<0.20,
heating the pressure-sintered body at a temperature higher than the pressure-sintering temperature for re-sintering to form a re-sintered body having an average sintered grain size of at least 10 μm, and
oxidatively annealing the re-sintered body in an oxidative atmosphere at a temperature of at least 1,400° C.