Method of producing electrode
An active material powder that includes a foreign particle and an active material particle is prepared. A first electrode material that includes the active material powder is prepared. Dry classification treatment is performed on the first electrode material, and thereby the foreign particle included in the first electrode material is decreased. An active material layer that includes the first electrode material after the dry classification treatment is formed. The first electrode material is in powder form. The foreign particle includes a metal foreign object and is a coarse particle.
1 . A method of producing an electrode comprising:
(a) preparing an active material powder, the active material powder including a foreign particle and an active material particle;
(b) preparing a first electrode material including the active material powder;
(c) performing a dry classification treatment on the first electrode material to separate out coarse particles and decrease the foreign particle included in the first electrode material, wherein the dry classification treatment is performed with a cut size greater than a D99 of the active material powder, where D99 refers to a particle size in a volume-based particle size distribution at which cumulative frequency of particle sizes accumulated from a small size side reaches 99% of all particles; and
(d) forming an active material layer including the first electrode material after the dry classification treatment by:
(d1) performing a magnetic separation treatment on a conductive material to decrease a magnetic metal particle included in the conductive material;
(d2) preparing a powdery and granular composition by mixing the first electrode material after the dry classification treatment with a second electrode material comprising the conductive material; and
(d3) coating a surface of a substrate with the powdery and granular composition by electrostatic coating,
wherein:
the first electrode material is in powder form,
the foreign particle includes a metal foreign object and is a coarse particle; and
coating the surface of the substrate with the powdery and granular composition by electrostatic coating comprises:
feeding the powdery and granular composition into a vessel;
adsorbing the powdery and granular composition from the vessel onto a first roll by a magnetic force of the first roll;
conveying the substrate, using a second roll, to a roll gap between the first roll and a third roll, wherein the first roll, the second roll, and the third roll have parallel axes;
supporting the substrate on a surface of the third roll; and
forming an electric field between the first roll and the third roll such that an electrostatic force pulls the powdery and granular composition toward the third roll and causes the powdery and granular composition to become adhered to the substrate.
2 . The method of producing an electrode according to claim 1 , wherein the powdery and granular composition has a solid fraction from 70 to 100% by mass.
3 . The method of producing an electrode according to claim 1 , wherein the active material particle is magnetic.
4 . The method of producing an electrode according to claim 1 , wherein
the coarse particle has a shorter diameter and a longer diameter,
the shorter diameter is twice the D99 of the active material powder, or greater.
5 . The method of producing an electrode according to claim 1 , wherein:
the conductive material is in powder form; and
performing the magnetic separation treatment on the conductive material comprises passing the conductive material through a magnet filter.
6 . The method of producing an electrode according to claim 5 , wherein the conductive material comprises a conductive carbon particle, a conductive carbon fiber, or both.
7 . The method of producing an electrode according to claim 5 , wherein the conductive material is selected from the group consisting of carbon black, vapor grown carbon fiber, carbon nanotube, graphene flake, and graphite.
8 . The method of producing an electrode according to claim 5 , wherein the conductive material is carbon black selected from the group consisting of acetylene black, furnace black, channel black, and thermal black.
9 . The method of producing an electrode according to claim 1 , further comprising mixing the powdery and granular composition in the vessel with a ferromagnetic substance.