Super absorbent polymer
A polyacrylic acid (salt)-based super absorbent polymer, includes carbon, oxygen, and sodium on the surface thereof, and satisfies Equation 1: X C═O +X O-C═O ≥6(at %) wherein, X C═O represents the content (at %) of carbon included in a CO bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis, and X O—C═O represents the content (at %) of carbon included in a O—C═O bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis.
1 . A polyacrylic acid (salt)-based super absorbent polymer, comprising:
carbon, oxygen, and sodium on the surface thereof; and
the super absorbent polymer satisfies Equation 1 below:
X C═O +X O—C═O ≥6(at %) [Equation 1]
wherein,
X C═O represents a content (at %) of carbon included in a C═O bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis, and
X O—C═O represents a content (at %) of carbon included in a O—C═O bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis,
wherein the super absorbent polymer satisfies Equation 2 below:
X C═O +X O—C═O ≤15(at %) [Equation 2]
2 . The super absorbent polymer of claim 1 , wherein the super absorbent polymer satisfies Equation 3 below:
X C═O ≥ XO—C═O [Equation 3].
3 . The super absorbent polymer of claim 1 , wherein the X O—C═O is 2.5 at % or greater.
4 . The super absorbent polymer of claim 1 , wherein the X C═O is 3.5 at % or greater.
5 . The super absorbent polymer of claim 1 , wherein the super absorbent polymer satisfies Equation 4 below:
(X O—C═O /X C )×100(%)≤10(%) [Equation 4]
wherein,
X C represents a total content (at %) of carbon among all elements present on the surface of the super absorbent polymer according to XPS analysis.
6 . The super absorbent polymer of claim 1 , wherein a content (X o ) of an oxygen element with respect to all elements present on the surface of the super absorbent polymer according to XPS analysis is 50 at % or less.
7 . The super absorbent polymer of claim 1 , wherein a content (X Na ) of a sodium element with respect to all elements present on the surface of the super absorbent polymer according to XPS analysis is 6 at % or less.
8 . The super absorbent polymer of claim 1 , wherein a content (X Si ) of a silicon element with respect to all elements present on the surface of the super absorbent polymer according to XPS analysis is 15 at % or less.
9 . The super absorbent polymer of claim 1 , wherein the super absorbent polymer satisfies Equation 6 below:
X C═O +X O—C═O >X Na [Equation 6]
wherein,
X Na represents a content (at %) of sodium among all elements present on the surface of the super absorbent polymer according to XPS analysis.
10 . The super absorbent polymer of claim 1 , wherein the super absorbent polymer comprises one or more elements selected from the group consisting of silicon, nitrogen, aluminum, and sulfur on the surface of the super absorbent polymer.
11 . The super absorbent polymer of claim 1 , wherein when the super absorbent polymer is swollen for 1 minute with water having an electrical conductivity value of 100 μS/cm to 130 μS/cm, a free swell capacity of water containable by the super absorbent polymer is 130 g/g or greater.
12 . A polyacrylic acid (salt)-based super absorbent polymer, comprising:
carbon, oxygen, and sodium on the surface thereof; and
the super absorbent polymer satisfies Equation 1 below:
X C═O +X O—C═O ≥6(at %) [Equation 1]
wherein,
X C═O represents a content (at %) of carbon included in a C═O bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis, and
X O—C═O represents a content (at %) of carbon included in a O—C═O bond structure among all elements present on the surface of the super absorbent polymer according to XPS analysis,
wherein the super absorbent polymer satisfies Equation 4 below:
(X O—C═O /X C )×100(%)≤10(%) [Equation 4]
wherein,
X C represents a total content (at %) of carbon among all elements present on the surface of the super absorbent polymer according to XPS analysis.