Diffraction element
Provided is a diffraction element having excellent aligning properties of a liquid crystal compound. The diffraction element includes an optically-anisotropic layer that has a liquid crystal alignment pattern in which an orientation of an optical axis derived from a liquid crystal compound changes while continuously rotating in at least one in-plane direction, in which a birefringence Δn of the optically-anisotropic layer is 0.20 or more, the optically-anisotropic layer includes a surfactant, and in a case where components in a depth direction are analyzed by time-of-flight secondary ion mass spectrometry from one surface to another surface of the optically-anisotropic layer, a depth-direction profile of a secondary ion intensity derived from the surfactant is obtained, a position corresponding to a thickness of 20% from the one surface of the optically-anisotropic layer is represented by a position D 20 , a position corresponding to a thickness of 80% from the one surface is represented by a position D 80 , and an average value of secondary ion intensities derived from the surfactant between the position D 20 and the position D 80 is calculated, in a region from the position D 20 to the position D 80 , a peak having a size of 1.1 times or more the average value is observed and a peak having a size of 5 times or more the average value is not observed.
1 . A diffraction element comprising:
an optically-anisotropic layer that has a liquid crystal alignment pattern in which an orientation of an optical axis derived from a liquid crystal compound changes while continuously rotating in at least one in-plane direction,
wherein a birefringence Δn of the optically-anisotropic layer is 0.20 or more,
the optically-anisotropic layer includes a surfactant, and
in a case where components of the optically-anisotropic layer in a depth direction are analyzed by time-of-flight secondary ion mass spectrometry while irradiating the optically-anisotropic layer with an ion beam from one surface to another surface of the optically-anisotropic layer, a depth-direction profile of a secondary ion intensity derived from the surfactant is obtained, a depth position corresponding to a thickness of 20% from the one surface to the other surface side of the optically-anisotropic layer is represented by a position D 20 , a depth position corresponding to a thickness of 80% from the one surface to the other surface side of the optically-anisotropic layer is represented by a position D 80 , and an average value of secondary ion intensities derived from the surfactant between the position D 20 and the position D 80 is calculated, in a region from the position D 20 to the position D 80 , a peak that shows a secondary ion intensity having a size of 1.1 times or more the average value is observed and a peak that shows a secondary ion intensity having a size of 5 times or more the average value is not observed.
2 . The diffraction element according to claim 1 ,
wherein in a case where two or more peaks that show the secondary ion intensity having a size of 1.1 times or more the average value are provided, a distance between the peaks adjacent to each other is represented by T, and
a length over which the orientation of the optical axis derived from the liquid crystal compound in the liquid crystal alignment pattern rotates by 180° in a plane is set as a single period Λ,
the distance T between the peaks and the single period Λ of the liquid crystal alignment pattern satisfy
0
.
0
5
≤
T
/
Λ
≤
0
.
2
5
.
3 . The diffraction element according to claim 2 ,
wherein the optically-anisotropic layer has a region where the optical axis of the liquid crystal compound is twisted in a thickness direction, and
a twisted angle of the optically-anisotropic layer in the thickness direction is 10° to 360°.
4 . The diffraction element according to claim 2 ,
wherein the surfactant includes a fluorine atom and has a molecular weight of 800 to 2000.
5 . The diffraction element according to claim 2 ,
wherein the birefringence Δn of the optically-anisotropic layer is 0.40 or less.
6 . The diffraction element according to claim 2 ,
wherein the surfactant includes a fluorine atom, the fluorine atom is a perfluoroalkyl group, and the surfactant has 4 or less carbon atoms.
7 . The diffraction element according to claim 1 ,
wherein the optically-anisotropic layer has a region where the optical axis of the liquid crystal compound is twisted in a thickness direction, and
a twisted angle of the optically-anisotropic layer in the thickness direction is 10° to 360°.
8 . The diffraction element according to claim 7 ,
wherein the surfactant includes a fluorine atom and has a molecular weight of 800 to 2000.
9 . The diffraction element according to claim 7 ,
wherein the birefringence Δn of the optically-anisotropic layer is 0.40 or less.
10 . The diffraction element according to claim 1 ,
wherein the surfactant includes a fluorine atom and has a molecular weight of 800 to 2000.
11 . The diffraction element according to claim 10 ,
wherein the surfactant includes a fluorine atom, the fluorine atom is a perfluoroalkyl group, and the surfactant has 4 or less carbon atoms.
12 . The diffraction element according to claim 10 ,
wherein the birefringence Δn of the optically-anisotropic layer is 0.40 or less.
13 . The diffraction element according to claim 1 ,
wherein the birefringence Δn of the optically-anisotropic layer is 0.40 or less.
14 . The diffraction element according to claim 13 ,
wherein the surfactant includes a fluorine atom, the fluorine atom is a perfluoroalkyl group, and the surfactant has 4 or less carbon atoms.
15 . The diffraction element according to claim 1 ,
wherein the surfactant includes a fluorine atom, the fluorine atom is a perfluoroalkyl group, and the surfactant has 4 or less carbon atoms.