IP Library Granted Patent US 12677592
Granted Patent B2
US 12677592 · App. 17/290,181 · Granted Jul 7, 2026

Organic electroluminescent compound and organic electroluminescent device comprising the same

Inventors: Jin-Ri Hong (Gyeonggi-do, KR); Hyo-Soon Park (Gyeonggi-do, KR); Hyo-Jung Lee (Gyeonggi-do, KR); Hyun-Ju Kang (Gyeonggi-do, KR)
Assignee: DuPont Specialty Materials Korea Ltd.
H10K85/6572C07D209/94C07D403/10C09K11/06H10K85/636H10K85/654C09K2211/1018H10K50/11H10K2101/10
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Quick Facts
Patent No.
US 12677592
App. No.
17/290,181
Granted
Jul 7, 2026
Kind
B2
Abstract

The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound according to the present disclosure, an organic electroluminescent device having a low driving voltage and/or a high luminous efficiency and/or a long lifespan can be provided.

Claims (26)

1 . An organic electroluminescent compound represented by any one of the following formulae 2, 3, and 5:

Wherein,

Y and Y 1 each independently represent —N-L 1 -Ar 1 , —O—, —S—, or —CR 1 R 2 ;

L 1 represents a single bond, a substituted or unsubstituted (C1-C30)alkylene, a substituted or unsubstituted (C6-C30)arylene, a substituted or unsubstituted (3-to 30-membered) heteroarylene, or a substituted or unsubstituted (C3-C30)cycloalkylene;

Ar 1 represents a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3-to 30-membered) heteroaryl, or —NR 3 R 4 ;

R 1 to R 4 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3-to 30-membered) heteroaryl, or a substituted or unsubstituted (C3-C30)cycloalkyl; or may be linked to an adjacent substituent to form a substituted or unsubstituted ring;

Z 1 to Z 12 each independently represent N or CR a ; and

R a each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3-to 30-membered) heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted mono- or di-(C1-C30)alkylamino, a substituted or unsubstituted mono- or di-(C6-C30)arylamino, a substituted or unsubstituted (C1-C30)alkyl(C6-30)arylamino, a substituted or unsubstituted mono- or di-(3-to 30-membered)heteroarylamino, or a substituted or unsubstituted (C6-C30)aryl (3-to 30-membered)heteroarylamino.

2 . The organic electroluminescent compound according to claim 1 , wherein the substituents of the substituted (C1-C30)alkyl(ene), the substituted (C6-C30)aryl(ene), the substituted (3-to 30-membered)heteroaryl(ene), the substituted (C3-C30)cycloalkyl(ene), the substituted (C1-C30)alkoxy, the substituted tri(C1-C30)alkylsilyl, the substituted di(C1-C30)alkyl(C6-C30)arylsilyl, the substituted (C1-C30)alkyldi(C6-C30)arylsilyl, the substituted tri(C6-C30)arylsilyl, the substituted mono- or di-(C1-C30)alkylamino, the substituted mono- or di-(C6-C30)arylamino, the substituted (C1-C30)alkyl(C6-30)arylamino, and the substituted ring in Ar 1 , L 1 , R 1 to R 4 , and R a each independently represent at least one selected from the group consisting of deuterium, halogen, cyano, carboxyl, nitro, hydroxyl, (C1-C30)alkyl, halo(C1-C30)alkyl, (C2-C30)alkenyl, (C2-C30)alkynyl, (C1-C30)alkoxy, (C1-C30)alkylthio, (C3-C30)cycloalkyl, (C3-C30)cycloalkenyl, (3-to 7-membered)heterocycloalkyl, (C6-C30)aryloxy, (C6-C30)arylthio, (C6-C30)aryl, (3-to 30-membered) heteroaryl, tri(C1-C30)alkylsilyl, tri(C6-C30)arylsilyl, di(C1-C30)alkyl(C6-C30)arylsilyl, (C1-C30)alkyldi(C6-C30)arylsilyl, amino, mono- or di-(C1-C30)alkylamino, (C1-C30)alkyl-substituted or unsubstituted mono- or di-(C6-C30)arylamino, (C1-C30)alkyl(C6-C30)arylamino, (C1-C30)alkylcarbonyl, (C1-C30)alkoxycarbonyl, (C6-C30)arylcarbonyl, di(C6-C30)arylboronyl, di(C1-C30)alkylboronyl, (C1-C30)alkyl(C6-C30)arylboronyl, (C6-C30)ar(C1-C30)alkyl, and (C1-C30)alkyl(C6-C30)aryl.

3 . The organic electroluminescent compound according to claim 1 , wherein Ar 1 and R a each independently represent any one of the substituents selected from the following Group 1:

wherein,

D1 and D2 each independently represent a benzene ring or a naphthalene ring;

X 11 represents O, S, NR 11 , or CR 12 R 13 ;

X 12 each independently represent CR 31 or N; provided that at least one X 12 is N;

X 13 each independently represent CR 32 or N;

L 11 to L 18 each independently represent a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3-to 30-membered)heteroarylene;

R 11 to R 22 , R 31 , and R 32 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3-to 30-membered)heteroaryl, or a substituted or unsubstituted (C3-C30)cycloalkyl; or may be linked to an adjacent substituent to form a substituted or unsubstituted ring;

aa, ff, and gg each independently represent an integer of 1 to 5, bb represents an integer of 1 to 7, cc to ee represent an integer of 1 to 4; and

when aa to gg are 2 or more, each of R 11 to R 17 may be the same or different.

4 . The organic electroluminescent compound according to claim 1 , wherein Ar 1 and R a each independently represent any one of the substituents selected from the following Group 2:

wherein,

L is as defined of L 1 in claim 1 ; and

A 1 to A 3 each independently represent a substituted or unsubstituted (C1-C30)alkyl or a substituted or unsubstituted (C6-C30)aryl.

5 . The organic electroluminescent compound according to claim 1 , wherein, Ar 1 , R 1 to R 4 , and R a each independently represent any one of the substituents selected from the following Group 3.

6 . The organic electroluminescent compound according to claim 1 , wherein the compound represented by formulae 2, 3, and 5 is selected from the group consisting of:

7 . An organic electroluminescent device comprising the organic electroluminescent compound according to claim 1 as host materials.