Method of processing substrate, method of manufacturing semiconductor device, substrate processing apparatus, and recording medium
There is provided a technique which includes: forming a first film containing silicon, oxygen, carbon and nitrogen on a substrate by performing a first cycle a predetermined number of times, the first cycle including forming a first layer containing silicon, oxygen, carbon and nitrogen by supplying a first precursor containing silicon, nitrogen and carbon and an oxidant to the substrate, and performing a first modifying process to the first layer at a first temperature to desorb impurities contained in the first layer and densify the first layer; and performing, after forming the first film, a second modifying process to the first film at a second temperature that is not less than the first temperature to desorb impurities contained in the first film and densify the first film.
1 . A method of processing a substrate, comprising:
forming a first film containing silicon, oxygen, carbon and nitrogen on a substrate by performing a first cycle multiple times, the first cycle including:
forming a first layer containing silicon, oxygen, carbon and nitrogen by supplying a first precursor containing silicon, nitrogen and carbon and an oxidant to the substrate; and
performing a first modifying process to the first layer at a first temperature to desorb impurities contained in the first layer and densify the first layer; and
performing, after forming the first film, a second modifying process to the first film at a second temperature that is not less than the first temperature to desorb impurities contained in the first film and densify the first film.
2 . The method according to claim 1 , further comprising supplying a second precursor containing silicon, nitrogen and carbon that is different from the first precursor to the substrate.
3 . The method according to claim 2 , wherein the act of forming the first layer comprises supplying the second precursor, the first precursor and the oxidant.
4 . The method according to claim 2 , further comprising:
forming a second film containing silicon, oxygen, carbon and nitrogen by performing a second cycle a predetermined number of times, the second cycle including:
forming a second layer containing silicon, oxygen, carbon and nitrogen by supplying the second precursor and the oxidant to the substrate; and
performing the first modifying process to the second layer under the first temperature; and
forming a laminated film in which the first film and the second film are alternately laminated on the substrate by alternately performing the act of forming the first film and the act of forming the second film,
wherein the act of performing the second modifying process comprises performing the second modifying process to the laminated film.
5 . The method according to claim 4 , wherein a composition of the first layer is different from a composition of the second layer, and
wherein a composition of the first film is different from a composition of the second film.
6 . The method according to claim 4 , wherein a carbon concentration, a nitrogen concentration or a ratio of the carbon concentration to the nitrogen concentration in the first layer is different from that in the second layer, and
wherein a carbon concentration, a nitrogen concentration or a ratio of the carbon concentration to the nitrogen concentration in the first film is different from that in the second film.
7 . The method according to claim 4 , wherein the oxidant is continuously supplied in the act of forming the first film.
8 . The method according to claim 4 , wherein the oxidant is continuously supplied in the act of forming the second film.
9 . The method according to claim 4 , wherein the oxidant is continuously supplied in the act of forming the laminated film.
10 . The method according to claim 4 , wherein the supply of the oxidant starts prior to the supply of the first precursor in the act of forming the first film.
11 . The method according to claim 4 , wherein the supply of the oxidant starts prior to the supply of the second precursor in the act of forming the second film.
12 . The method according to claim 2 , wherein the first precursor includes first aminosilane and the second precursor includes second aminosilane or alkoxysilane.
13 . The method according to claim 12 , wherein a number of amino ligands in one molecule of the first aminosilane is different from a number of amino ligands in one molecule of the second aminosilane.
14 . The method according to claim 2 , wherein a number of carbon atoms in one molecule of the first precursor is different from a number of carbon atoms in one molecule of the second precursor.
15 . The method according to claim 2 , wherein a number of nitrogen atoms in one molecule of the first precursor is different from a number of nitrogen atoms in one molecule of the second precursor.
16 . The method according to claim 2 , wherein a ratio of a number of carbon atoms to a number of nitrogen atoms in one molecule of the first precursor is different from a ratio of a number of carbon atoms to a number of nitrogen atoms in one molecule of the second precursor.
17 . The method according to claim 1 , wherein the oxidant is continuously supplied in the act of forming the first film.
18 . The method according to claim 1 , wherein the supply of the oxidant starts prior to the supply of the first precursor in the act of forming the first film.
19 . The method according to claim 1 , wherein the first precursor includes first aminosilane.
20 . The method according to claim 1 , wherein the oxidant includes a nitrogen oxide-based gas.
21 . The method according to claim 1 , wherein the act of forming the first layer comprises simultaneously supplying the first precursor and the oxidant.
22 . A method of manufacturing a semiconductor device comprising the method of claim 1 .
23 . A substrate processing apparatus comprising:
a precursor supply system configured to supply a precursor containing silicon, nitrogen and carbon to the substrate;
an oxidant supply system configured to supply an oxidant to the substrate;
a heater configured to heat the substrate; and
a controller configured to be capable of controlling the precursor supply system, the oxidant supply system and the heater so as to:
form a film containing silicon, oxygen, carbon and nitrogen on the substrate by performing a cycle multiple times, the cycle including:
forming a layer containing silicon, oxygen, carbon and nitrogen by supplying the precursor and the oxidant to the substrate; and
performing a first modifying process to the layer at a first temperature to desorb impurities contained in the layer and densify the layer; and
perform, after forming the film by performing the cycle multiple times, a second modifying process to the film at a second temperature that is not less than the first temperature to desorb impurities contained in the film and densify the film.
24 . A non-transitory computer-readable recording medium storing a program that causes, by a computer, a substrate processing apparatus to perform a process comprising:
forming a film containing silicon, oxygen, carbon and nitrogen on a substrate by performing a cycle multiple times, the cycle including:
forming a layer containing silicon, oxygen, carbon and nitrogen by supplying a precursor containing silicon, nitrogen and carbon and an oxidant to the substrate; and
performing a first modifying process to the layer at a first temperature to desorb impurities contained in the layer and densify the layer; and
performing, after forming the film by performing the cycle multiple times, a second modifying process to the film at a second temperature that is not less than the first temperature to desorb impurities contained in the film and densify the film.