Reactor system and method thereof for degassing sulfur
A reactor system can include a reactor, including: a first inlet for a first stream including a liquid sulfur including a dissolved hydrogen sulfide, a polysulfide, or a combination thereof. A second inlet can be for a second stream, wherein the second stream can be an oxygen-containing gas with no more than about 2%, by weight nitrogen. A packing can be in contact with a catalyst.
1 . A method of degassing hydrogen sulfide in a liquid sulfur, the method comprising:
providing through a first inlet of a reactor a first stream including the liquid sulfur, wherein the first stream comprises no more than about 600 ppm, by weight, hydrogen sulfide;
providing through a second inlet of the reactor a second stream of oxygen-containing gas with about 0.0001% to about 2%, by weight, nitrogen and no more than about 28 vol. % oxygen;
generating an off-gas stream from the reactor;
passing the off-gas stream from the reactor to a sulfur recovery zone;
removing at least a portion of sulfur compounds in the off-gas stream to generate a tail gas stream;
treating the tail gas stream in a tail gas treatment zone to generate a treated tail gas stream comprising carbon dioxide and water;
purifying the carbon dioxide in the treated tail gas stream in a carbon dioxide conditioning zone to produce a stream comprising carbon dioxide; and
providing carbon dioxide from the stream to the second inlet,
wherein the second stream comprises a stream comprising carbon dioxide from the carbon dioxide conditioning zone and a stream comprising oxygen from the sulfur recovery zone.
2 . The method of claim 1 , wherein the first stream comprises no more than about 400 ppm, by weight, hydrogen sulfide.
3 . The method of claim 1 , wherein the second stream comprises a Claus tail gas stream from the sulfur recovery zone.
4 . The method of claim 1 , wherein the second stream comprises oxygen and carbon dioxide.
5 . The method of claim 1 , wherein the second stream comprises no more than about 1%, by weight, nitrogen.
6 . The method of claim 1 , wherein the second stream comprises about 0.0001% to about 0.001%, by weight, nitrogen.