Strontium-catalyzed boehmite formation
A strontium-catalyzed process for preparing boehmite includes combining a strontium material, flash calcined gibbsite, and water to obtain an aqueous suspension; contacting the aqueous suspension with a water-soluble carbonate material; and heating the aqueous suspension to a temperature, and for a time, sufficient to form at least about 5 wt. % of boehmite.
1 . A strontium-catalyzed process for preparing boehmite, the process comprising:
combining a strontium material, flash calcined gibbsite, and water to obtain an aqueous suspension;
contacting the aqueous suspension with a water soluble carbonate material; and
heating the aqueous suspension to a temperature and for a time sufficient to form at least about 5 wt. % of boehmite based on total weight of the solid;
wherein the process further comprises removing strontium from the boehmite.
2 . The process of claim 1 , wherein the strontium material comprises strontium carboxylate, strontium nitrate, strontium chloride, strontium bromide, strontium iodide, or a mixture of any two or more thereof.
3 . The process of claim 1 , wherein the strontium material is present in an amount below the saturation point of the strontium material in the aqueous solution.
4 . The process of claim 1 , wherein the aqueous suspension comprises about 1 wt. % to about 40 wt. % solids.
5 . The process of claim 1 , wherein the process further comprises heating the aqueous suspension to a temperature of about 30° C. to about 110° C. prior to contacting the aqueous suspension with the water soluble carbonate material.
6 . The process of claim 1 , wherein the aqueous solution has a pH of about 7 to about 10.
7 . The process of claim 1 , wherein at least about 10 wt. % to 100 wt. % of boehmite is formed based on the total weight of solids.
8 . The process of claim 1 , wherein the process has a faster crystallite size growth rate relative to a boehmite formation process that is not strontium-catalyzed.
9 . The process of claim 1 , wherein the boehmite has a crystallite size of about 100 Å to about 200 Å.
10 . The process of claim 1 , wherein removing strontium from the boehmite comprises: combining the boehmite with water and a weak acid to obtain a reaction mixture; heating the reaction mixture; and removing the boehmite from the reaction mixture.