Solvent composition for a urease inhibitor, application and use thereof
This invention relates to solvent compositions comprising an alkyl glycol ester-type solvent and a glycol-type solvent, non-aqueous solvent delivery formulations comprising the solvent composition, a urease inhibitor dissolved in the solvent composition, and fertilisers comprising a urea-based component and the non-aqueous solvent delivery formulation and the use of the fertilisers in agricultural applications.
1 . A solvent composition, the solvent composition comprising:
(A) an alkyl glycol ester-type solvent of the formula (I)
wherein
R is hydrogen or a linear or branched C1 to C5 alkyl group,
R2 is hydrogen or a methyl group,
R3 is hydrogen or a methyl group,
X is from 1 to 4,
R6 is a linear or branched C1 to C6 alkyl group,
wherein R2 and R3 may be different for each X, and wherein X is the alkoxylation degree and a number average; and
(B) a glycol-type solvent of the formula (II)
wherein
R4 is hydrogen or a C1 to C3 alkyl group,
R5 is hydrogen or a C1 to C3 alkyl group, and
Z is an integer from 0 to 4;
and wherein the glycol-type solvent of the formula (II) and the alkyl glycol ester-type solvent of the formula (I) are in a mass ratio in the range of from 3:1 to 9:1.
2 . The solvent composition of claim 1 , wherein
(A) the alkyl glycol ester-type solvent of the formula (I) and
(B) the glycol-type solvent of the formula (II) together form greater than 70 wt % of the solvent composition.
3 . The solvent composition of claim 1 , wherein independent from each other
a) R is a C1 to C4 alkyl group; and
b) R6 is a linear or branched C1 to C4 alkyl group.
4 . The solvent composition of claim 1 , wherein R2 and R3 are selected such that the alkylene glycol group (AG)
represents an ethylene oxide (EO) unit or a propylene oxide (PO) unit or both.
5 . The solvent composition of claim 1 , wherein independent from each other
a) R4 is hydrogen or a C1 to C2 alkyl group;
b) R5 is hydrogen or a C1 to C2 alkyl group; and
c) Z is an integer from 0 to 3.
6 . The solvent composition of claim 1 , wherein the solvent composition does not comprise N-methyl-2-pyrrolidone.
7 . The solvent composition of claim 1 , wherein;
a) R is a methyl group,
b) R2 is hydrogen,
c) R3 is hydrogen,
d) X is from 1 to 2.2,
e) R4 is a methyl group and R5 is hydrogen, or R4 is hydrogen and R5 is a methyl group,
f) R6 is n-butyl, and
g) Z is 0.
8 . A non-aqueous solvent delivery formulation comprising:
the solvent composition claim 1 ; and
a urease inhibitor dissolved in the solvent composition,
wherein the concentration of the urease inhibitor in the non-aqueous solvent delivery formulation is up to 40 wt % based on the total mass of the non-aqueous solvent delivery formulation.
9 . The non-aqueous solvent delivery formulation of claim 8 , wherein the urease inhibitor comprises or consists of an N-alkyl thiophosphoric triamide.
10 . The non-aqueous solvent delivery formulation of claim 8 wherein the concentration of the solvent composition is at least 50 wt. % based on the total mass of the non-aqueous solvent delivery formulation.
11 . The non-aqueous solvent delivery formulation of claim 8 , wherein the non-aqueous solvent delivery formulation further comprises one or more nitrification inhibitors.
12 . The non-aqueous solvent delivery formulation of claim 8 , wherein the non-aqueous solvent delivery formulation further comprises one or more pesticide actives.
13 . The non-aqueous solvent delivery of formulation claim 8 , wherein the non-aqueous solvent delivery formulation further comprises additives.
14 . A fertiliser comprising at least
a urea-based component and
the non-aqueous solvent delivery formulation of claim 8 .
15 . The fertiliser of claim 14 , wherein the fertiliser is a solid fertiliser.
16 . A method for obtaining a fertiliser, the method comprising:
providing a urea component; and
treating the urea component with the non-aqueous solvent delivery formulation of claim 8 to produce a fertilizer.
17 . The solvent composition of claim 1 , wherein
(A) the alkyl glycol ester-type solvent of the formula (I) and
(B) the glycol-type solvent of the formula (II)
together form greater than 90 wt % of the solvent composition.
18 . The solvent composition of claim 1 , wherein
(A) the alkyl glycol ester-type solvent of the formula (I) and
(B) the glycol-type solvent of the formula (II)
together form greater than 95 wt % of the solvent composition.
19 . The solvent composition of claim 1 , wherein the solvent composition exclusively consists of (A) and (B).
20 . The non-aqueous solvent delivery formulation of claim 11 , wherein said nitrification inhibitors comprise dicyandiamide, nitrapyrin, pronitridine, allylthiourea, 3,4-dimethylpyrazole phosphate, or mixtures thereof.
21 . The non-aqueous solvent delivery formulation of claim 12 , wherein said pesticide actives comprise herbicides, fungicides, insecticides, or mixtures thereof.
22 . The non-aqueous solvent delivery formulation of claim 13 , wherein said additives comprise micronutrients, biostimulants, plant growth regulators, or mixtures thereof.