Polyamide composition and article made therefrom with improved mold shrinkage
Described herein is a polyamide composition comprising two polyamides and glass fiber, wherein one of the polyamides is a polyphthalamide formed by polycondensation from various monomers: dicarboxylic acid(s) with diamine(s) and/or amino acid(s), wherein at least one monomer contains a cyclohexyl group. It was surprisingly discovered that the polyamide composition has improved warpage and/or mold shrinkage properties, excellent mechanical performance and high Tg and/or Tm. Due to the excellent performance, the polyamide composition is suitable for molding and can be desirably incorporated into mobile electronic device applications.
1 . A polyamide composition comprising:
a polyamide (PA1),
a polyamide (PA2) having a glass transition temperature Tg which is lower than the Tg of the polyamide (PA1) and/or having a melting temperature Tm which is lower than the Tm of the polyamide (PA1), and
from 15 percent by weight (wt. %) to 60 wt. % of a glass fiber, said wt. % being based on the total weight of the polyamide composition,
wherein the polyamide composition has a PA1 weight ratio of at least 0.05 and at most 0.95, said PA1 weight ratio being calculated as the weight of PA1 in the polyamide composition based on the combined weights of PA1 and PA2 in the polyamide composition,
wherein the polyamide (PA1) is a copolyamide comprising:
recurring units (R PA1 ) of formula (1), (R PA2 ) of formula (2), and (R PA3 ) of formula (3) or (4):
wherein n 1 to n 3 are mol. % of recurring units (R PA1 ), (R PA2 ) and (R PA3 ), respectively;
or a copolyamide comprising:
recurring units (R PA1 ) of said formula (1), (R PA2 ) of said formula (2), (R PA3* ) of formula (5), and (R PA4* ) of formula (6),
wherein n 1 to n 4 are mol. % of recurring units (R PA1 ) (R P,A2 ), (R PA3* ), and (R PA4* ), respectively (n 1 +n 2 +n 3 +n 4 ≤100 mol. %);
and
wherein
R 1 is a C 4 to C 8 aliphatic alkylene;
R 2 is a C 9 to C 12 aliphatic alkylene group;
R 5 is a C 1 to C 3 alkylene group;
R″, at each location, is independently selected from the group consisting of an alkyl, an aryl, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, and a quaternary ammonium;
j is an integer from 0 to 10;
T in Formula (3) is represented by either one of the following formulae (7) or (8):
wherein
R 3 and R 4 , are independently selected from the group consisting of a bond and a C 1 to C 10 alkylene groups;
R′, at each location, is independently selected from the group consisting of an alkyl, an aryl, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, and a quaternary ammonium; and
each i is an independently selected integer from 0 to 10; and the ‘*’ denotes a bond to one of the two explicit nitrogen atoms in Formula (3).
2 . The polyamide composition of claim 1 , wherein the recurring units (R PA1 ) and (R PA2 ) are formed from polycondensation of hexamethylenediamine and 1,10-diaminodecane with terephthalic acid.
3 . The polyamide composition of claim 1 , wherein the recurring unit (R PA3 ) is formed from:
polycondensation of terephthalic acid with either 1,3-bis(aminomethyl)cyclohexane (1,3-BAC) or 1,4-bis(aminomethyl)cyclohexane (1,4-BAC); or
polycondensation of 4-aminomethylcyclohexanecarboxylic acid (4-AMCC); or
wherein the recurring units (R PA3* ) and (R PA4* ) are formed from polycondensation of hexamethylenediamine and 1,10-diaminodecane with 1,4-cyclohexane dicarboxylic acid (1,4-CHDA).
4 . The polyamide composition of claim 1 , wherein,
when the polyamide (PA1) comprises recurring units (R PA1 ) of formula (1), (R PA2 ) of formula (2), and (R PA3 ) of formula (3) or (4), n 1 +n 2 +n 3 is at least 50 mol. % based on the total number of recurring unit in the polyamide (PA1) and n 3 in (R PA3 ) is greater than 0.5 mol. %; or
when the polyamide (PA1) comprises recurring units (R PA1 ) of formula (1), (R PA2 ) of formula (2), (R PA3* ) of formula (5), and (R PA4* ) of formula (6), n 1 +n 2 +n 3 +n 4 is at least 50 mol. % based on the total number of recurring units in the polyamide (PA1), and n 3 in (R PA3* ) and/or n 4 in (R PA4* ) is greater than 0.5 mol. %.
5 . The polyamide composition of claim 1 , wherein the polyamide (PA2) has a glass temperature Tg of at least 50° C. and/or a melting temperature Tm of at least 220° C.
6 . The polyamide composition of claim 1 , wherein the polyamide (PA2) comprises a semi-aromatic polyamide.
7 . The polyamide composition of claim 1 , wherein the polyamide (PA2) is selected from the group consisting of PA10,T/10,I; PA10,T; PA6, T/6,I; PA6,T; PA9,T; PAMXD6; PAPXD10; and any combination thereof.
8 . The polyamide composition of claim 1 , wherein the PA1 weight ratio is
at least 0.1 and/or
at most 0.9.
9 . The polyamide composition of claim 1 , wherein the glass fiber concentration in the polyamide composition is from 20 wt. % to 55 wt. %, based on the total weight of the polyamide composition.
10 . The polyamide composition of claim 1 , wherein the glass fiber is a round or flat glass fiber selected from the group consisting of:
E-glass fiber;
low D k glass fiber having a dielectric constant of 4.0 to 5.5 at a frequency of 1 MHz measured according to ASTM D150;
high modulus glass fiber having a tensile modulus of at least 76 GPa as measured according to ASTM D2343; and
combinations thereof.
11 . The polyamide composition of claim 1 , having a glass transition temperature Tg of at least 50° C. and/or no more than 150° C., and a melting temperature Tm of at least 180° C. and/or no more than 340° C., wherein the Tg and Tm are measured according to ASTM D3418.
12 . The polyamide composition of claim 1 , further comprising at least one optional component selected from the group consisting of tougheners, plasticizers, light stabilizers, ultra-violet stabilizers, heat stabilizers, pigments, dyes, antistatic agents, flame retardants, impact modifiers, lubricants, nucleating agents, antioxidants, processing aids, and any combination of two or more thereof.
13 . A method for making the polyamide composition of claim 1 , comprising melt-blending the polyamide (PA1), the polyamide (PA2), the glass fiber and any optional component selected from the group consisting of a reinforcing agent different than the glass fiber, tougheners, plasticizers, light stabilizers, ultra-violet stabilizers, heat stabilizers, pigments, dyes, antistatic agents, flame retardants, impact modifiers, lubricants, nucleating agents, antioxidants, processing aids, and any combination of two or more thereof.
14 . A molded article comprising the polyamide composition of claim 1 , having a reduced transverse shrinkage and/or warpage compared to polyamide compositions containing only the polyamide (PA1) or only the polyamide (PA2), the other components being the same.
15 . A mobile electronic device component comprising the polyamide composition of claim 1 .
16 . The mobile electronic device component of claim 15 , being an antenna, an antenna window, an antenna housing or a mobile electronic housing.
17 . The polyamide composition of claim 1 , wherein the polyamide (PA2) comprises a polyphthalamide.
18 . The polyamide composition of claim 1 , further comprising at least one impact modifer.