Curable resin composition and display device

1 . A curable resin composition comprising: quantum dots (A); a resin (B); a photopolymerizable compound (C); a photopolymerization initiator (D); and an antioxidant (E),

wherein a ratio of contents of the antioxidant (E) to the photopolymerization initiator (D) in the curable resin composition is greater than 1 in terms of mass ratio; and

wherein the photopolymerization initiator (D) contains an oxime compound having a first molecular structure represented by the following formula (1):

wherein R 1 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN;

R 11 , R 12 , and R 13 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms, or a heterocyclic group having 2 to 20 carbon atoms;

the hydrogen atoms of the group represented by R 11 , R 12 , or R 13 are optionally replaced by OR 21 , COR 21 , SR 21 , NR 22 Ra 23 , CONR 22 R 23 , —NR 22 —OR 23 , —N(COR 22 )—OCOR 23 , —C(═N—OR 21 )—R 22 , —C(═N—OCOR 21 )—R 22 , CN, a halogen atom, or COOR 21 ;

R 21 , R 22 , and R 23 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms, or a heterocyclic group having 2 to 20 carbon atoms;

the hydrogen atoms of the group represented by R 21 , R 22 , or R 23 are optionally replaced by CN, a halogen atom, a hydroxy group, or a carboxy group;

when the group represented by R 11 , R 12 , R 13 , R 21 , R 22 , or R 23 has an alkylene moiety, the alkylene moiety is optionally interrupted one to five times by —O—, —S—, —COO—, —OCO—, —NR 24 —, —NR 24 CO—, —NR 24 COO—, —OCONR 24 —, —SCO—, —COS—, —OCS—, or —CSO—;

R 24 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an aralkyl group having 7 to 30 carbon atoms, or a heterocyclic group having 2 to 20 carbon atoms;

when the group represented by R 11 , R 12 , R 13 , R 21 , R 22 , or R 23 has an alkyl moiety, the alkyl moiety is optionally branched or cyclic, and R 12 and R 13 , and R 22 and R 23 are each optionally joined together to form a ring; and

* represents a bond with a second molecular structure,

wherein the second molecular structure is a structure represented by the following formula (2):

wherein R 2 and R 3 each independently represent R 11 , OR 11 , SR 11 , COR 11 CONR 12 R 13 , NR 12 COR 11 , OCOR 11 , COOR 11 , SCOR 11 , OCSR 11 , COSR 11 , CSOR 11 , CN, or a halogen atom;

a plurality of R 2 , when present, are optionally the same or different;

a plurality of R 3 , when present, are optionally the same or different;

R 11 , R 12 , and R 13 have the same meaning as described above;

each of s and tis 0;

L represents a sulfur atom, CR 31 R 32 , CO, or NR 33 ;

R 31 , R 32 , and R 33 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, or an aralkyl group having 7 to 30 carbon atoms;

when the group represented by R 31 , R 32 , or R 33 has an alkyl moiety, the alkyl moiety is optionally branched or cyclic, and R 31 , R 32 , and R 33 are each independently and optionally joined together to form a ring with any of adjacent benzene rings;

R 4 represents a hydroxy group, a carboxy group, or a group represented by the following formula (2-1):

wherein L 1 represents —O—, —S—, —NR 22 NR 22 CO—, —SO 2 —, —CS—, —OCO—, or —COO—;

R 22 has the same meaning as described above;

L 2 represents a group obtained by removing v hydrogen atoms from an alkyl group having 1 to 20 carbon atoms, a group obtained by removing v hydrogen atoms from an aryl group having 6 to 30 carbon atoms, a group obtained by removing v hydrogen atoms from an aralkyl group having 7 to 30 carbon atoms, or a group obtained by removing v hydrogen atoms from a heterocyclic group having 2 to 20 carbon atoms;

when the group represented by L 2 has an alkylene moiety, the alkylene moiety is optionally interrupted one to five times by —O—, —S—, —COO—, —OCO—, —NR 22 —, —NR 22 COO—, —OCONR 22 —, —SCO—, —COS—, —OCS—, or —CSO—, and the alkylene moiety is optionally branched or cyclic;

R 4a is each independently OR 41 , SR 41 , CONR 42 R 43 , NR 42 COR 43 , OCOR 41 , COOR 41 , SCOR 41 , OCSR 41 , COSR 41 , CSOR 41 , CN, or a halogen atom;

a plurality of R 4a , when present, are optionally the same or different;

R 41 , R 42 , and R 43 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, or an aralkyl group having 7 to 30 carbon atoms, and when the group represented by R 41 , R 42 , and R 43 has an alkyl moiety, the alkyl moiety is optionally branched or cyclic, and R 42 and R 43 are optionally joined together to form a ring; and

v represents an integer of 1 to 3; and

* represents a bond with the first molecular structure of the oxime compound.

2 . The curable resin composition according to claim 1 , wherein L is a sulfur atom.

3 . The curable resin composition according to claim 1 , wherein R 4 is a group represented by the formula (2-1), L 1 is —O—, and R 4a is OH.

4 . The curable resin composition according to claim 1 , wherein a content ratio of the quantum dots (A) is 10% by mass or more and 50% by mass or less based on a total amount of a solid content of the curable resin composition.

5 . The curable resin composition according to claim 1 , wherein the photopolymerization initiator (D) contains the oxime compound and an acylphosphine compound.

6 . A cured film formed from the curable resin composition according to claim 1 .

7 . The cured film according to claim 6 , wherein a difference between a maximum value and a minimum value of a film thickness is 1.0 μm or less.

8 . A display device comprising the cured film according to claim 6 .