Processes for making mesophase pitch
A process for making a mesophase pitch may include passing an aromatics-rich feed into a reactor and subjecting the aromatics-rich feed to a temperature of greater than or equal to 350° C. and a pressure of from 20 bar to 40 bar for a duration of from 4 hours to 10 hours in the reactor to produce the mesophase pitch. The total amount of molecular oxygen and peroxides in the reactor may be less than 1 mol. %. The aromatics-rich feed may include at least 80 wt. % aromatics and the aromatics-rich feed may include less than 3 wt. % of a combination of sulfur, nitrogen, and oxygen.
1 . A process for making a mesophase pitch, the process comprising:
passing an aromatics-rich feed into a reactor, wherein:
the total amount of molecular oxygen and peroxides in the reactor is less than 1 mol. %;
the aromatics-rich feed comprises at least 80 wt. % aromatics selected from the group consisting of naphthalenes, acenaphthenes, acenaphthylenes, fluorenes, phenanthres, anthracenes, pyrenes, tetra-aromatics, penta-aromatics, or combinations thereof;
the aromatics-rich feed comprises less than 3 wt. % of a combination of sulfur, nitrogen, and oxygen; and
subjecting the aromatics-rich feed to a temperature of greater than or equal to 350° C. and a pressure of from 20 bar to 40 bar for a duration of from 4 hours to 10 hours in the reactor to produce the mesophase pitch.
2 . The process of claim 1 , wherein the aromatics-rich feed is subjected to a temperature of greater than or equal to 400° C.
3 . The process of claim 1 , wherein the aromatics-rich feed is subjected to a temperature of greater than or equal to 450° C.
4 . The process of claim 1 , wherein the aromatics-rich feed comprises a cycle oil from a fluid catalytic cracking system.
5 . The process of claim 1 , wherein the mesophase pitch is made in a batch process.
6 . The process of claim 1 , wherein the duration is from 5 to 7 hours.
7 . The process of claim 1 , wherein:
the aromatics-rich feed comprises less than 5 wt. % resins; and
the mesophase pitch comprises at least 10 wt. % resins.
8 . The process of claim 1 , wherein subjecting the aromatics-rich feed to the temperature of greater than or equal to 350° C. polymerizes the aromatics-rich feed in the reactor.
9 . The process of claim 1 , further comprising purging the reactor with an inert gas prior to passing the aromatics-rich feed to the reactor.
10 . The process of claim 1 , further comprising stirring the aromatics-rich feed in the reactor.
11 . The process of claim 10 , wherein stirring is continuous throughout the duration of the process.
12 . The process of claim 1 , wherein the aromatics-rich feed comprises:
from 1 wt. % to 10 wt. % saturates;
from 0.01 wt. % to 5 wt. % resins; and
from 0 wt. % to 1 wt. % asphaltenes.
13 . The process of claim 1 , wherein the aromatics-rich feed comprises from 85 wt. % to 95 wt. % carbon and from 5 wt. % to 15 wt. % hydrogen.
14 . The process of claim 1 , wherein the aromatics-rich feed comprises less than 1 wt. % of a combination of sulfur, nitrogen, and oxygen.
15 . The process of claim 1 , wherein the aromatics-rich feed has a hydrogen-to-carbon ratio of greater than 1.
16 . The process of claim 1 , wherein the aromatics-rich feed comprises:
from 4 wt. % to 8 wt. % saturates;
from 90 wt. % to 95 wt. % aromatics;
from 0.01 wt. % to 3 wt. % resins; and
from 0 wt. % to 0.1 wt. % asphaltenes.
17 . The process of claim 1 , wherein the mesophase pitch comprises:
from 0 wt. % to 1 wt. % saturates;
from 65 wt. % to 75 wt. % aromatics;
from 10 wt. % to 20 wt. % resins; and
from 10 wt. % to 20 wt. % asphaltenes.
18 . The process of claim 1 , wherein the mesophase pitch has a softening point of from 150° C. to 350° C.
19 . The process of claim 1 , wherein the temperature is greater than or equal to 400° C. and the duration is from 5 hours to 7 hours.
20 . The process of claim 1 , wherein the temperature is greater than or equal to 450° C. and the duration is from 5 hours to 7 hours.
21 . The process of claim 1 , wherein the aromatics-rich feed comprises from 0 wt. % to 1 wt. % asphaltenes.