Visible spectrum anti-reflective coatings with reduced reflections in ultraviolet and infrared spectral bands
Lens coatings and coated lenses which offer full-spectrum protection by reducing back-side reflection of all light spanning from the ultraviolet sub-band B (UVB) to infrared (IR-A) region are provided. The full-spectrum back-side anti-reflective coatings disclosed herein are comprised of multiple thin-film layers of high refractive index (HighIndex) and low refractive index (LowIndex) materials. In many embodiments, the penultimate layer distal from the substrate lens is a HighIndex layer, and the final layer distal from the substrate lens is a LowIndex layer.
1 . An optical lens comprising:
a substrate lens having a frontside and a backside;
an antireflective coating (AR) disposed one of either adjacent to or distal from the backside of the substrate lens, the AR coating formed of at least three thin-film layers each formed of one of either a high refractive index (HighIndex) metal oxide material or a low refractive index (LowIndex) material, wherein the HighIndex metal oxide material has a refractive index of at least 1.6 and the LowIndex material has a refractive index of no greater than 1.5;
wherein the at least three thin-film layers form a coating stack having an innermost end configured to be disposed atop the backside of the substrate lens, and an outermost end configured to be disposed distal to the backside of the substrate lens, and wherein the coating stack comprising at least a final layer formed from a LowIndex material having a thickness of from 90-110 nm and disposed distal to the backside, and a final layer of a HighIndex material having a thickness of from 50-70 nm and disposed distal to the backside; and
wherein a backside mean reflectance factor Rm of the coating measured across wavelengths 400-700 nm does not exceed 2.15%, a backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and a backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°.
2 . The lens of claim 1 , wherein the coating has a set of properties selected from the group consisting of:
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 10% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13% measured at an angle of incidence of 45° or does not exceed 9.5% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 5% measured at angles of incidence 30° and 45°; and
the backside mean reflectance factor R M of the coating measured across wavelengths 400-700 nm does not exceed a value selected from the group consisting of 1.65% and 1.15%.
3 . The lens of claim 1 , further comprising a top-coat layer disposed distal to the final LowIndex layer, wherein:
the topcoat is comprised of material selected from one or more of the group consisting of a hydrophobic coat and an oleophobic coat; and
the top-coat has a thickness of no greater than 20 nm.
4 . The lens of claim 1 , wherein the AR backside coating further comprises at least one intermediary HighIndex layer and an intermediary LowIndex layer disposed more proximal than the final layers, and wherein the at least one intermediary HighIndex layer is more proximal than the intermediary LowIndex layer.
5 . The lens of claim 4 , wherein the at least one intermediary HighIndex layer has a thickness of from 13-15 nm and the intermediary LowIndex layer has a thickness of from 30-36 nm.
6 . The lens of claim 1 , wherein:
the HighIndex metal oxide material is selected from the group consisting of oxides of Zr, Ti, AI, Y, Ta, Nd, La, Nb and PrTi or mixtures thereof; and
the LowIndex material is selected from the group consisting of SiO 2 and mixtures of SiO 2 with alumina.
7 . The lens of claim 1 , further comprising at least one additional layer, wherein the at least one additional layer is selected from the group consisting of a scratch-resistance coating, tinting, polarization, transitions and photochromatic treatment.
8 . The lens of claim 1 , further comprising an electrically conductive layer disposed between at least two of the thin-film layers of the AR coating, the electrically conductive layer having a thickness no greater than 15 nm.
9 . The lens of claim 1 , wherein a backside luminous reflectance factor R V of the coating measured across wavelengths 380-780 nm does not exceed 2%.
10 . The lens of claim 1 , wherein the thickness of the final layer of the HighIndex material is from 58-65 nm, and wherein the thickness of the final layer of the LowIndex material is from 99-105 nm.
11 . A method of coating an optical lens with an antireflective coating comprising:
providing a substrate lens having a frontside and a backside;
disposing an antireflective (AR) coating on the substrate lens, the AR coating formed of at least three thin- film layers each formed of one of either a high refractive index (HighIndex) metal oxide material or a low refractive index (LowIndex) material, wherein the HighIndex metal oxide material has a refractive index of at least 1.6 and the LowIndex material has a refractive index of no greater than 1.5;
wherein the at least three thin-film layers form a coating stack disposed atop the backside of the substrate lens, the coating stack comprising, a final layer of a LowIndex material having a thickness of from 97-105 nm disposed distal to the backside, and a final layer of a HighIndex material having a thickness of from 55-65 nm and disposed distal to the backside; and
wherein a backside mean reflectance factor R m of the coating measured across wavelengths 400-700 nm does not exceed 2.15%, a backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and a backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°.
12 . The method of claim 11 , wherein the substrate lens is comprised of a material selected from the group consisting of glass, plastic, poly-carbonate, crown glass, TrivexTM, methyl poly(methacrylate), thi(meth) acrylic (co)polymers, polyvinylbutyral, polycarbonates, polyurethanes, poly(thourethanes), polyolallylcarbonate (co)polymers), ethylene/vinyl acetate, polyesters(including PET or PBT), polyepisulfides, polyepoxides, polycarbonate/polyester copolymers, cycloolefin copolymers (including ethylene/norbornene copolymers), high-index materials, and combinations thereof.
13 . The method of claim 11 , wherein the coating has a set of properties selected from the group consisting of:
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 10% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13% measured at an angle of incidence of 45° or does not exceed 9.5% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 5% measured at angles of incidence 30° and 45°; and
the backside mean reflectance factor R m of the coating measured across wavelengths 400-700 nm does not exceed a value selected from the group consisting of 1.65% and 1.15%.
14 . The method of claim 11 , further comprising a top-coat layer disposed distal to the final LowIndex layer, wherein:
the topcoat is comprised of material selected from one or more of the group consisting of a hydrophobic coat and an oleophobic coat; and
the top-coat has a thickness of no greater than 20 nm.
15 . The method of claim 11 , wherein the AR coating further comprises at least one intermediary HighIndex layer and an intermediary LowIndex layer disposed more proximal than the final layers, and wherein the at least one intermediary HighIndex layer is more proximal than the intermediary LowIndex layer.
16 . The method of claim 15 , wherein the at least one intermediary HighIndex layer has a thickness of from 13-15 nm and the intermediary LowIndex layer has a thickness of from 30-36 nm.
17 . The method of claim 11 , wherein:
the HighIndex metal oxide material is selected from the group consisting of oxides of Zr, Ti, Al, Y, Ta, Nd, La, Nb and PrTi or mixtures thereof; and
the LowIndex material is selected from the group consisting of SiO 2 and mixtures of SiO 2 with alumina.
18 . The method of claim 11 , wherein the AR coating is disposed on a sub-layer of SiO 2 wherein the sub-layer of SiO 2 has a set thickness configured for mechanical integrity of the AR coating.
19 . The method of claim 11 , further comprising at least one additional layer, wherein the at least one additional layer is selected from the group consisting of a scratch-resistance coating, tinting, polarization, transitions and photochromatic treatment.
20 . The method of claim 11 , further comprising an electrically conductive layer disposed between at least two of the thin-film layers of the AR coating, the electrically conductive layer having a thickness no greater than 15 nm.
21 . A method of coating an optical lens with an antireflective coating comprising:
providing a substrate lens having a frontside and a backside;
disposing an antireflective (AR) coating on the substrate lens, the AR coating formed of at least three thin-film layers each formed of one of either a high refractive index (HighIndex) metal oxide material or a low refractive index (LowIndex) material, wherein the HighIndex metal oxide material has a refractive index of at least 1.6 and the LowIndex material has a refractive index of no greater than 1.5;
wherein the at least three thin-film layers form a coating stack disposed atop the backside of the substrate lens, the coating stack comprising, a final layer of a LowIndex material having a thickness of from 99-105 nm disposed distal to the backside, and a final layer of a HighIndex material having a thickness of from 58-65 nm and disposed distal to the backside; and
wherein a backside mean reflectance factor Rm of the coating measured across wavelengths 400-700 nm does not exceed 2.15%, a backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and a backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°.
22 . The method of claim 21 , wherein the substrate lens is comprised of a material selected from the group consisting of glass, plastic, poly-carbonate, crown glass, TrivexTM, methyl poly(methacrylate), thi(meth)acrylic (co)polymers, polyvinylbutyral, polycarbonates, polyurethanes, poly(thourethanes), polyolallylcarbonate (co)polymers), ethylene/vinyl acetate, polyesters (including PET or PBT), polyepisulfides, polyepoxides, polycarbonate/polyester copolymers, cycloolefin copolymers (including ethylene/norbornene copolymers), high-index materials, and combinations thereof.
23 . The method of claim 21 , wherein the coating has a set of properties selected from the group consisting of:
the backside mean UV reflection factor Ruv of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor Ruv of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 10% measured at an angle of incidence of 30°;
the backside mean UV reflection factor Ruv of the coating measured across wavelengths 280-380 nm does not exceed 13% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13% measured at an angle of incidence of 45° or does not exceed 9.5% measured at an angle of incidence of 30°
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 14% measured at angles of incidence 30° or 45°;
the backside mean UV reflection factor Ruv of the coating measured across wavelengths 280-380 nm does not exceed 9% measured at angles of incidence 30° and 45°, and the backside IR reflection factor R IR of the coating measured across 780-1400 nm does not exceed 13.5% measured at an angle of incidence of 45° or does not exceed 12% measured at an angle of incidence of 30°;
the backside mean UV reflection factor R UV of the coating measured across wavelengths 280-380 nm does not exceed 5% measured at angles of incidence 30° and 45°; and
the backside mean reflectance factor R m of the coating measured across wavelengths 400-700 nm does not exceed a value selected from the group consisting of 1.65% and 1.15%.
24 . The method of claim 21 , further comprising a top-coat layer disposed distal to the final LowIndex layer, wherein:
the topcoat is comprised of material selected from one or more of the group consisting of a hydrophobic coat and an oleophobic coat; and
the top-coat has a thickness of no greater than 20 nm.
25 . The method of claim 21 , wherein the AR coating further comprises at least one intermediary HighIndex layer and an intermediary LowIndex layer disposed more proximal than the final layers, and wherein the at least one intermediary HighIndex layer is more proximal than the intermediary LowIndex layer.
26 . The method of claim 25 , wherein the at least one intermediary HighIndex layer has a thickness of from 13 - 15 nm and the intermediary LowIndex layer has a thickness of from 30-36 nm.
27 . The method of claim 21 , wherein:
the HighIndex metal oxide material is selected from the group consisting of oxides of Zr, Ti, Al, Y, Ta, Nd, La, Nb and PrTi or mixtures thereof; and
the LowIndex material is selected from the group consisting of SiO 2 and mixtures of SiO 2 with alumina.
28 . The method of claim 21 , wherein the AR coating is disposed on a sub-layer of SiO 2 wherein the sub-layer of SiO 2 has a set thickness configured for mechanical integrity of the AR coating.
29 . The method of claim 21 , further comprising at least one additional layer, wherein the at least one additional layer is selected from the group consisting of a scratch-resistance coating, tinting, polarization, transitions and photochromatic treatment.
30 . The method of claim 21 , further comprising an electrically conductive layer disposed between at least two of the thin-film layers of the AR coating, the electrically conductive layer having a thickness no greater than 15 nm.