Electrode assembly for lithium secondary battery, and lithium secondary battery comprising same
An electrode assembly for a lithium secondary battery and a positive electrode for the lithium secondary battery including the electrode assembly. By controlling a ratio (CR Lip /CR S i) between a content percentage of a positive electrode additive and a silicon (Si)-containing material that is a negative electrode active material, which are contained in a positive electrode mixture layer and a negative electrode mixture layer, respectively, to a specific range, the electrode assembly has an advantage in that high charging/discharging capacity and charging/discharging efficiency can be realized during initial charging/discharging, a capacity retention rate can be excellent during subsequent charging/discharging, and a lithium secondary battery including the electrode assembly can exhibit a high energy density and long lifetime.
1 . An electrode assembly for a lithium secondary battery, comprising:
a positive electrode in which a positive electrode mixture layer includes a positive electrode active material and a positive electrode additive of Chemical Formula 1;
a negative electrode in which a negative electrode mixture layer includes a carbon material and a silicon (Si)-containing material as a negative electrode active material; and
a separator located between the positive electrode and the negative electrode,
wherein a content of the positive electrode additive ranges from 0.01 to 5 parts by weight based on 100 parts by weight of the positive electrode mixture layer, and
a ratio (CR Lip /CR si ) between a content percentage of the positive electrode additive (CR Lip ) based on a total weight of the positive electrode mixture layer and a content percentage of the Si-containing material (CR si ) based on a total weight of the negative electrode mixture layer ranges from 0.03 to 0.30:
Li p Co (1-q) M 1 q O 4 Chemical Formula 1
in Chemical Formula 1,
M 1 denotes at least one element selected from the group consisting of W, Cu, Fe, V, Cr, Ti, Zr, Zn, Al, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo,
Wherein p and q are 5≤p≤7 and 0≤q≤0.5.
2 . The electrode assembly of claim 1 , wherein the ratio (CR Lip /CR si ) between the content percentage of the positive electrode additive (CR Lip ) based on the total weight of the positive electrode mixture layer and the content percentage of the Si-containing material (CR si ) based on the total weight of the negative electrode mixture layer ranges from 0.05 to 0.20.
3 . The electrode assembly of claim 1 , wherein the positive electrode additive has a tetragonal structure with a space group of P4 2 /nmc.
4 . The electrode assembly of claim 1 , wherein the positive electrode active material is a lithium metal composite oxide of Chemical Formula 2:
Li x [ni y Co z Mn w M 2 v ]O u Chemical Formula 2
in Chemical Formula 2,
M 2 denotes at least one element selected from the group consisting of W, Cu, Fe, V, Cr, Ti, Zr, Zn, Al, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo, and
Wherein x, y, z, w, v, and u are 1.0≤x≤1.30, 0≤y<0.95, 0<z≤0.5, 0<w≤0.5, 0≤v≤0.2, and 1.5≤u≤4.5.
5 . The electrode assembly of claim 1 , wherein the carbon material includes one or more of natural graphite, artificial graphite, graphene, or carbon nanotubes.
6 . The electrode assembly of claim 5 , wherein the carbon material includes one or more of graphene or carbon nanotubes included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of a total amount of the carbon material.
7 . The electrode assembly of claim 1 , wherein the positive electrode mixture layer includes 0.1 to 5 parts by weight of a conductive material based on the total weight of the positive electrode mixture layer.
8 . The electrode assembly of claim 1 , wherein the positive electrode mixture layer includes one or more conductive materials selected from the group consisting of natural graphite, artificial graphite, carbon black, acetylene black, Ketjen black, and a carbon fiber.
9 . The electrode assembly of claim 1 , wherein the Si-containing material includes one or more among Si, silicon monoxide (SiO), or silicon dioxide (SiO 2 ).
10 . The electrode assembly of claim 1 , wherein:
an average thickness of the positive electrode mixture layer ranges from 50 μm to 300 μm; and
an average thickness of the negative electrode mixture layer ranges from 100 μm to 300 μm.
11 . The electrode assembly of claim 1 , wherein an average area ratio of the negative electrode mixture layer and the positive electrode mixture layer ranges from 1.0 to 1.1.
12 . A lithium secondary battery comprising the electrode assembly according to claim 1 , and an electrolyte.