Polymer and organic light emitting device comprising same
The present disclosure provides a polymer and an organic light emitting device including the same, wherein the polymer comprising a repeating unit represented by the following Chemical Formula 1: wherein L, R 1 to R 5 , and * are described herein.
1 . An organic light emitting device comprising an anode; a cathode that is disposed opposite to the anode; a light emitting layer that is provided between the anode and the cathode; and a hole transport layer that is provided between the anode and the light emitting layer,
wherein the hole transport layer comprises a polymer comprising a repeating unit represented by Chemical Formula 1′ or 1″:
in Chemical Formula 1′ and 1″,
each L is independently a substituted or unsubstituted C 6-10 arylene,
each R 1 is independently a substituted or unsubstituted C 4-10 alkyl,
each R 2 is independently a substituted or unsubstituted C 1-4 alkyl,
each R 3 is independently a substituted or unsubstituted C 1-10 alkyl, and
* indicates the point of attachment within the polymer,
in Chemical Formula 1′,
each R 4 is independently a substituted or unsubstituted C 1-4 alkyl, and
in Chemical Formula 1″,
each R 5 is independently a substituted or unsubstituted C 1-4 alkyl.
2 . The organic light emitting device according to claim 1 , wherein
each L is independently phenylene, or biphenyl.
3 . The organic light emitting device according to claim 1 , wherein
each L is independently
4 . The organic light emitting device according to claim 1 , wherein
each R 1 is independently a straight-chain hexyl, a straight-chain heptyl, a straight-chain octyl, a straight-chain nonyl, or a straight-chain decyl.
5 . The organic light emitting device according to claim 1 , wherein
each R 2 is independently methyl, ethyl, or propyl.
6 . The organic light emitting device according to claim 1 , wherein
each R 3 is independently methyl, ethyl, or propyl.
7 . The organic light emitting device according to claim 1 , wherein
each R 4 is independently methyl, ethyl, or propyl.
8 . The organic light emitting device according to claim 1 , wherein:
the repeating unit is represented by one of the following formulas:
9 . The organic light emitting device according to claim 1 , wherein:
the polymer further comprises a repeating unit represented by the following Chemical Formula 2:
in Chemical Formula 2,
each L′ is independently a single bond; or a substituted or unsubstituted C 6-60 arylene,
Z is C, Si, N, Si (phenyl), or an n-valent substituted or unsubstituted C 6-60 aromatic ring,
n is 3 or 4, with the proviso that n is 4 if Z is C or Si and n is 3 if Z is N or Si (phenyl), and
* indicates the point of attachment within the polymer.
10 . The organic light emitting device according to claim 9 , wherein:
each L′ is independently a single bond, or phenylene.
11 . The organic light emitting device according to claim 9 , wherein:
Z is C, N, Si, or a trivalent benzene.
12 . The organic light emitting device according to claim 9 , wherein:
the Chemical Formula 2 is any one selected from the group consisting of:
13 . The organic light emitting device according to claim 1 , wherein:
the polymer further comprises a terminal group represented by the following Chemical Formula 3:
Ar [Chemical Formula 3]
in Chemical Formula 3,
Ar is a substituted or unsubstituted C 6-60 aryl,
* indicates the point of attachment within the polymer.
14 . The organic light emitting device according to claim 13 , wherein:
Ar is phenyl, or biphenylyl, and
the Ar is unsubstituted or substituted with a C 1-10 alkyl, a photocurable group, or a thermosetting group.
15 . The organic light emitting device according to claim 13 , wherein:
the Chemical Formula 3 is any one selected from the group consisting of:
16 . The organic light emitting device according to claim 1 , wherein:
the polymer has a weight average molecular weight of 3,000 to 1,000,000 g/mol.
17 . The organic light emitting device according to claim 9 , wherein:
the repeating unit of Chemical Formula 2 is contained in an amount of 10 to 50 moles based on 100 moles of the repeating unit of Chemical Formula 1.
18 . The organic light emitting device according to claim 13 , wherein:
the repeating unit of Chemical Formula 3 is contained in an amount of 20 to 65 moles based on 100 moles of the repeating unit of Chemical Formula 1.