Organic light emitting diode and organic light emitting device including the same
An organic light emitting diode and an organic light emitting device including the organic light emitting diode are discussed. The organic light emitting diode can include a first compound represented by the following formula, a second compound as a p-type host, and a third compound as an n-type host in an emitting material layer. As a result, the organic light emitting diode and the organic light emitting device have advantages in the driving voltage, the luminous efficiency and the lifespan.
1 . An organic light emitting diode, comprising:
a first electrode;
a second electrode facing the first electrode; and
a first emitting part including a first red emitting material layer and positioned between the first and second electrodes,
wherein the first red emitting material layer includes a first compound and a second compound,
wherein the first compound is represented by Formula 1-1:
wherein
M is iridium (Ir);
R is an unsubstituted or substituted C 1 -C 20 alkyl group,
wherein each of X 21 to X 27 is independently CR 1 ,
wherein Y 3 is CR 2 R 3 ,
each of R 1 to R 3 is independently hydrogen, an unsubstituted or substituted C 1 -C 20 alkyl group or an unsubstituted or substituted C 6 -C 30 aromatic group,
optionally,
two adjacent R 1 of X 25 to X 27 form an unsubstituted or substituted C 6 -C 30 aromatic ring;
is an auxiliary ligand; wherein Z 1 and Z 2 are independently selected from the group consisting of an oxygen atom, a nitrogen atom, and a phosphorus atom;
m is an integer of 1 to 3;
n is an integer of 0 to 2; and
m+n is an oxidation number of M,
wherein the second compound is represented by Formula 2-1:
wherein
each of X and Y is independently selected from the group consisting of an unsubstituted or substituted C 6 -C 30 aryl group,
R 4 is selected from the group consisting of an unsubstituted or substituted C 1 -C 20 alkyl group and an unsubstituted or substituted C 6 -C 30 aryl group,
a1 is an integer of 0,
L 1 is selected from the group consisting of an unsubstituted or substituted C 6 -C 30 arylene group, and
a2 is 1.
2 . The organic light emitting diode of claim 1 , wherein Formula 1-1 is represented by Formula 1-4:
wherein each of X 41 to X 45 is independently CR 1 , and
wherein each of M, R,
m, n, and R 1 to R 3 , X 21 to X 24 and Y 3 is same as defined in Formula 1-1.
3 . The organic light emitting diode of claim 1 , wherein Formula 1-1 is represented by Formula 1-8:
wherein R in Formulas 1-8 is same as defined in Formula 1-1,
wherein each of X 21 to X 24 and X 41 to X 45 is independently CR 1 ,
wherein Y 3 is CR 2 R 3 ,
wherein each of R 1 to R 3 is same as defined in Formula 1-1,
wherein each of R 11 to R 13 is independently selected from the group consisting of hydrogen and an unsubstituted or substituted C 1 -C 20 alkyl group,
wherein m is an integer of 1 to 3, and n is an integer of 0 to 2, and
wherein m+n is 3.
4 . The organic light emitting diode of claim 1 , wherein a weight % of the second compound is greater than a weight % of the first compound.
5 . The organic light emitting diode of claim 1 , further comprising:
a second emitting part including a second red emitting material layer and positioned between the first emitting part and the second electrode; and
a charge generation layer positioned between the first and second emitting parts.
6 . The organic light emitting diode of claim 5 , wherein the second emitting material layer includes a fourth compound represented by Formula 1-1 and a fifth compound represented by Formula 2-1.
7 . The organic light emitting diode of claim 1 , further comprising:
a second emitting part including a first blue emitting material layer and positioned between the first electrode and the first emitting part; and
a first charge generation layer positioned between the first and second emitting parts.
8 . The organic light emitting diode of claim 7 , further comprising:
a third emitting part including a second blue emitting material layer and positioned between the first emitting part and the second electrode; and
a second charge generation layer positioned between the first and third emitting parts.
9 . The organic light emitting diode of claim 8 , wherein the first emitting part further includes a green emitting material layer positioned between the red emitting material layer and the second charge generation layer.
10 . The organic light emitting diode of claim 9 , wherein the first emitting part further includes a yellow-green emitting material layer positioned between the red and green emitting material layers.
11 . An organic light emitting device, comprising:
a substrate;
the organic light emitting diode of claim 1 positioned on the substrate.
12 . The organic light emitting diode of claim 1 , wherein the first compound is one of the following compounds:
13 . The organic light emitting diode of claim 1 , wherein the second compound is the following compound: