Glass body
The glass body according to the present invention includes a plate-like glass plate having a first surface and a second surface; and an antibacterial film that is formed on the first surface and in which copper ions are dispersed.
1 . A glass body comprising:
a glass plate having a first surface and a second surface; and
an antibacterial film that is formed on the first surface and in which copper ions are dispersed,
wherein the antibacterial film contains boron, and
D 2 /D 1 >0.8 is satisfied, where a thickness of the antibacterial film is D 1 and a thickness of the antibacterial film obtained after the glass body is heated at 600° C. is D 2 , and
wherein the antibacterial film comprises a network structure of Si and O, and wherein the copper ions are ionically bonded to the network structure.
2 . The glass body according to claim 1 ,
wherein the antibacterial film does not contain copper particles or copper compound particles with an outer diameter of 100 nm or more.
3 . The glass body according to claim 1 ,
wherein the antibacterial film contains at least one of a silicon oxide, zirconia, titania, and alumina as a main component.
4 . The glass body according to claim 1 ,
wherein the antibacterial film contains the copper ions in an amount of 1 to 40 mass % with respect to a main component that constitutes the antibacterial film.
5 . The glass body according to claim 1 ,
wherein the antibacterial film has a film thickness of 20 to 500 nm.
6 . The glass body according to claim 1 ,
wherein, when the maximum thickness of the antibacterial film is Dmax and the minimum thickness of the antibacterial film is Dmin, Dmax/Dmin≤7 is satisfied.
7 . The glass body according to claim 6 ,
wherein a portion of the antibacterial film with a thickness of the Dmin is located at an end portion of the antibacterial film.
8 . The glass body according to claim 1 ,
wherein the antibacterial film contains an acidic oxide serving as a network former.
9 . The glass body according to claim 1 ,
wherein the antibacterial film contains the boron in an amount of 0.1 to 10 mass % with respect to a main component that constitutes the antibacterial film.
10 . The glass body according to claim 1 ,
wherein after the glass body is immersed in water for 16 hours, an elution amount of the copper ions is 20 mass % or less of the copper ions contained therein before the immersion.
11 . The glass body according to claim 1 ,
wherein the glass body has a visible light transmittance of 90% or more.
12 . The glass body according to claim 1 ,
wherein the antibacterial film has a surface roughness Ra of less than 120 nm.
13 . The glass body according to claim 1 ,
wherein the glass body has a haze ratio of 3% or less.
14 . The glass body according to claim 1 , further comprising:
an anti-fingerprint layer formed on at least a portion of the antibacterial film.
15 . A method for producing the glass body of claim 1 , comprising:
producing a coating liquid by adding a copper salt and boric acid to a solution containing silicon alkoxide;
applying the coating liquid to at least one surface of a glass plate; and
heating the glass plate to which the coating liquid has been applied to a predetermined temperature or higher.