IP Library Granted Patent US 12686771
Granted Patent B2
US 12686771 · App. 18/254,987 · Granted Jul 21, 2026

Anti-fouling silicone composite sheet and method for performing prevention of graffiti using same

Inventors: Keiji Imaizumi (Takasaki, JP); Akihiro Endo (Annaka, JP); Masaki Moteki (Takasaki, JP)
Assignee: SHIN-ETSU CHEMICAL CO., LTD.
C08L83/04B32B7/12B32B27/08B32B27/16B32B27/322B32B27/36C09J7/29C09J7/38C09J183/04B32B2250/24B32B2255/10B32B2255/26B32B2307/536B32B2307/554B32B2307/7376B32B2307/748B32B2405/00
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Quick Facts
Patent No.
US 12686771
App. No.
18/254,987
Granted
Jul 21, 2026
Kind
B2
Abstract

An anti-fouling silicone composite sheet including: a substrate layer containing a fluororesin; and a silicone adhesive layer stacked on one surface of the substrate layer, having a hardness of 5 or less as measured with an Asker C hardness tester, and having an adhesive force with respect to a mortar test piece of 5 N/25 mm or more, wherein the substrate layer has a surface on which the silicone adhesive layer is stacked and the other surface is an anti-fouling surface. By the above configuration, the present invention provides an anti-fouling silicone composite sheet capable of exhibiting anti-fouling performance, washability, easiness of washing, and wear resistance stably for a long period, easily attachable to an adherend, and conformable even to cracking and shifting on the application surface; and a method for performing a prevention of graffiti by using the anti-fouling silicone composite sheet.

Claims (16)

1 . An anti-fouling silicone composite sheet comprising:

a substrate layer containing a fluororesin; and a silicone adhesive layer stacked on one surface of the substrate layer, having a hardness of 5 or less as measured with an Asker C hardness tester, and having an adhesive force with respect to a mortar test piece of 5 N/25 mm or more, wherein

the substrate layer has a surface on which the silicone adhesive layer is stacked and the other surface is an anti-fouling surface,

the fluororesin is as the substrate layer itself,

at least the surface opposite to the anti-fouling surface is subjected to anchoring property improving treatment in surfaces of the fluororesin constituting the substrate layer.

2 . The anti-fouling silicone composite sheet according to claim 1 , further comprising a reinforcing material in the substrate layer.

3 . The anti-fouling silicone composite sheet according to claim 2 , wherein a reinforcing material layer is further stacked between the substrate layer and the silicone adhesive layer.

4 . The anti-fouling silicone composite sheet according to claim 3 , wherein the substrate layer and the reinforcing material layer are stacked via an adhesion layer having a UV resistance property.

5 . The anti-fouling silicone composite sheet according to claim 3 , wherein the reinforcing material layer comprises a PET film.

6 . The anti-fouling silicone composite sheet according to claim 1 , wherein a reinforcing material layer is further stacked between the substrate layer and the silicone adhesive layer.

7 . The anti-fouling silicone composite sheet according to claim 6 , wherein the substrate layer and the reinforcing material layer are stacked via an adhesion layer having a UV resistance property.

8 . The anti-fouling silicone composite sheet according to claim 7 , wherein the reinforcing material layer comprises a PET film.

9 . The anti-fouling silicone composite sheet according to claim 6 , wherein the reinforcing material layer comprises a PET film.

10 . The anti-fouling silicone composite sheet according to claim 1 , wherein one or more of the respective layers have an anti-light-reflective effect.

11 . The anti-fouling silicone composite sheet according to claim 1 , wherein a thickness of the substrate layer is 0.05 to 0.3 mm, a thickness of the adhesive layer is 0.5 to 3 mm, and a total thickness of the anti-fouling silicone composite sheet is 0.55 to 3.3 mm.

12 . A method for performing a prevention of graffiti, comprising: attaching the silicone adhesive layer of the anti-fouling silicone composite sheet according to claim 1 to a certain adherend; and exposing the anti-fouling surface of the substrate layer constituted of the fluororesin to prevent graffiti on the adherend.