Acrylic-based adhesive composition with ethylene-based polymer
The present disclosure is directed to a water-based pressure-sensitive adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes (A) an acrylic dispersion composed of particles of (i) an acrylic-based polymer with a glass transition temperature (Tg) less than −20° C., and (ii) a surfactant. The water-based pressure-sensitive adhesive composition also includes (B) an ethylene-based polymer dispersion comprising an ethylene and vinyl acetate copolymer and an ethylene acid copolymer. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.
1 . A water-based pressure-sensitive adhesive composition comprising:
(A) an acrylic dispersion comprising particles of
(i) an acrylic-based polymer with a glass transition temperature (Tg) less than −20° C., and
(ii) a surfactant; and
(B) an ethylene-based polymer dispersion comprising an ethylene and vinyl acetate copolymer and an ethylene acid copolymer, the ethylene acid copolymer having a melt index from 1 g/10 min to 1500 g/10 min as measured in accordance with ASTM D1238 (190° C./2.16 kg).
2 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the acrylic-based polymer includes one or more acrylic-based monomers selected from the group consisting of acrylic acid (AA), butyl acrylate (BA), ethylhexyl acrylate (2-EHA), ethyl acrylate (EA), methyl acrylate (MA), butyl methacrylate (BMA), octyl acrylate, isooctyl acrylate, decyl acrylate, isodecyl acrylate, lauryl acrylate, cyclohexyl acrylate, methyl methacrylate (MMA), isobutyl methacrylate, octyl methacrylate, isooctyl methacrylate, decyl methacrylate, isodecyl methacrylate, lauryl methacrylate, pentadecyl methacrylate, stearyl methacrylate, n-butyl methacrylate, C 12 to C 18 alkyl methacrylates, cyclohexyl methacrylate, methacrylic acid, and combinations thereof.
3 . The water-based pressure-sensitive adhesive of claim 2 wherein the acrylic-based polymer further comprises a monomer selected from the group consisting of styrene, vinyl ester, and combinations thereof.
4 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the acrylic-based polymer has a Tg from −80° C. to −20° C.
5 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the ethylene-based polymer dispersion comprises a blend of
(i) particles composed of the ethylene and vinyl acetate copolymer having a volume average particle size from 0.05 microns to 2.0 microns; and
(ii) particles composed of the ethylene acid copolymer having a volume average particle size from 0.05 microns to 2.0 microns.
6 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the ethylene and vinyl acetate copolymer comprises from 10 wt % to less than 50 wt % vinyl acetate; and
the ethylene acid copolymer comprises from 3 wt % to less than 50 wt % acrylic acid comonomer.
7 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the ethylene and vinyl acetate copolymer comprises from 10 wt % to less than 50 wt % vinyl acetate; and
the ethylene acid copolymer comprises from 3 wt % to less than 50 wt % methacrylic acid comonomer.
8 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the ethylene-based polymer dispersion comprises
composite particles composed of the ethylene and vinyl acetate copolymer and the ethylene acid copolymer.
9 . The water-based pressure-sensitive adhesive composition of claim 8 wherein the ethylene and vinyl acetate copolymer comprises from 10 wt % to less than 50 wt % vinyl acetate; and
the ethylene acid copolymer comprises from 10 wt % to less than 50 wt % acrylic acid comonomer.
10 . The water-based pressure-sensitive adhesive composition of claim 8 wherein the ethylene and vinyl acetate copolymer comprises from 10 wt % to less than 50 wt % vinyl acetate; and
the ethylene acid copolymer comprises from 10 wt % to less than 50 wt % methacrylic acid comonomer.
11 . The water-based pressure-sensitive adhesive composition of claim 8 wherein the composite particles have a volume average particle size from 0.05 micron to 4.0 microns.
12 . The water-based pressure-sensitive adhesive composition of claim 1 wherein the ethylene-based polymer dispersion comprises a component selected from the group consisting of a dispersant, a neutralizing agent, and combinations thereof.
13 . The water-based pressure-sensitive adhesive composition of claim 1 comprising
(A) from 40 wt % to 99.8 wt % of the acrylic-based polymer;
(B) from 10 wt % to 0.2 wt % of the ethylene and vinyl acetate copolymer and an ethylene acid copolymer;
(C) from 0 wt % to 50 wt % tackifier;
wherein weight percent is based on the total dry weight of the water-based pressure-sensitive adhesive composition.
14 . An article comprising:
a first substrate; and
a layer of a water-based pressure-sensitive adhesive composition on the first substrate, the water-based pressure-sensitive adhesive composition comprising:
(A) an acrylic dispersion comprising particles of
(i) an acrylic-based polymer with a glass transition temperature (Tg) less than −20° C., and
(ii) a surfactant;
(B) an ethylene-based polymer dispersion comprising an ethylene and vinyl acetate copolymer and an ethylene acid copolymer, the ethylene acid copolymer having a melt index from 1 g/10 min to 1500 g/10 min as measured in accordance with ASTM D1238 (190° C./2.16 kg).
15 . The article of claim 14 wherein the first substrate is selected from the group consisting of a film, a cellulose-based material, a fabric, a tape, and a release liner.