Control device for secondary battery

1 . A control device for a secondary battery including an electrode and an electrolyte, the control device comprising a processor configured to implement:

a diagnosis unit configured to diagnose a deterioration state of the secondary battery, wherein the diagnosis unit has:

a resistance calculator configured to calculate a direct current resistance and a reaction resistance based on an impedance measurement result of the secondary battery by an alternating current impedance method;

an index value calculator configured to calculate an index value related to the direct current resistance and the reaction resistance;

a deterioration determination unit configured to compare the index value with a determination threshold based on an impedance characteristic at a time of deterioration of the secondary battery so as to determine a specific deterioration associated with charging and discharging of the secondary battery; and

a charge and/or discharge control unit configured to control charging and/or discharging of the secondary battery by limiting a charge and/or discharge current when the deterioration determination unit determines that the specific deterioration has occurred;

wherein:

the secondary battery is configured as a battery module in which a plurality of single cells is combined, each of which including the electrode and the electrolyte,

the resistance calculator calculates the direct current resistance and the reaction resistance for each of the plurality of single cells, and

the index value calculator calculates the index value as a value representing a relationship between a plurality of calculated sets of the direct current resistance and the reaction resistance.

2 . The control device according to claim 1 , wherein:

the index value calculator calculates the index value as a slope or an intercept of an expression representing a relationship between a plurality of sets of the direct current resistance and the reaction resistance,

the deterioration determination unit compares the index value with a slope threshold or an intercept threshold set based on an expression representing the relationship between the plurality of calculated sets of the direct current resistance and the reaction resistance in the plurality of single cells at the time of deterioration, and

the deterioration determination unit determines that the specific deterioration has occurred when the slope is equal to or less than the slope threshold or when the intercept is equal to or more than the intercept threshold.

3 . The control device according to claim 1 , wherein:

the deterioration determination unit permits a deterioration determination when at least one variation in the direct current resistances or the reaction resistances corresponding to the plurality of single cells is equal to or greater than a reference value.

4 . The control device according to claim 3 , wherein:

the index value calculator calculates the index value as a change amount or a change rate of the direct current resistances over time and a change amount of the reaction resistances over time,

the deterioration determination unit compares the index value with a first threshold set based on a change in the direct current resistances at the time of specific deterioration with respect to the time of deterioration, and a second threshold set based on a change in the reaction resistances at the time of specific deterioration with respect to the time of deterioration, and

the deterioration determination unit determines that the specific deterioration has occurred when a change amount or a change rate of the direct current resistances is equal to or less than the first threshold and a change amount of the direct current resistances is equal to or less than the second threshold.

5 . The control device according to claim 4 , wherein the deterioration determination unit permits a deterioration determination when the secondary battery is in a stable state and not being charged or when a temperature variation of the secondary battery or a change amount of the temperature variation over time is equal to or less than a reference value.

6 . The control device according to claim 1 , wherein:

when a capacity of the secondary battery is defined as C, the resistance calculator applies a current to acquire an impedance measurement.

7 . The control device according to claim 1 , wherein:

when a superimposed current in which a plurality of frequency components is superimposed is applied to the secondary battery, the resistance calculator acquires the impedance measurement result for each of the frequency components.