Negative electrode material, electrochemical apparatus, and electronic device
A negative electrode material includes a silicon-based material, or a silicon-based material and graphite. The silicon-based material includes a silicon oxide material and a carbon layer located on a surface of the silicon oxide material. A particle size distribution of the silicon-based material 1≤(D n 99−D n 10)/D n 50≤4, D n 10≥1 μm, and D n50 ≥3 μm. In the negative electrode material, a number distribution of particle sizes of the silicon-based material can be controlled so that large and small particles are better matched, thereby improving cycling performance of an electrochemical apparatus.
1 . An electrochemical apparatus, comprising:
a negative electrode material, comprising:
a silicon-based material; wherein the silicon-based material comprises a silicon oxide material and a carbon layer located on a surface of the silicon oxide material; and
a particle size distribution of the silicon-based material satisfies 1≤(D n 99−D n 10)/D n 50≤2.02, D n 10≥1 μm, D n 50≥3 μm, and 6.2 μm≤D n 99≤12.3 μm, wherein D n 10, D n 50 and D n 99 are particle sizes when a cumulative number of particles calculated in ascending order of particle sizes reaches 10%, 50%, and 99% of the total number of particles, respectively, in a number distribution diagram of particle sizes of the silicon-based material;
wherein the electrochemical apparatus further comprises an electrolyte,
wherein the electrolyte comprises an organic solvent and a lithium salt, and the organic solvent comprises fluoroethylene carbonate (FEC), wherein a mass percentage of FEC in the electrolyte is from 3% to less than 10%.
2 . The electrochemical apparatus according to claim 1 , wherein the negative electrode material further comprises graphite.
3 . The electrochemical apparatus according to claim 2 , wherein a mass of the silicon-based material accounts for 5% to 100% of a total mass of the silicon-based material and the graphite.
4 . The electrochemical apparatus according to claim 2 , wherein the graphite comprises at least one of natural graphite, artificial graphite, or meso-carbon microbeads.
5 . The electrochemical apparatus according to claim 1 , wherein
the silicon oxide material comprises SiOx, wherein x satisfies 0.5<x<1.6; and
SiOx comprises at least one of a crystal state or an amorphous state.
6 . The electrochemical apparatus according to claim 1 , wherein
in a Raman spectrum of the carbon layer, a ratio of a peak intensity at 1350 cm −1 I 1350 to a peak intensity at 1580 cm −1 I 1580 satisfies 1.0<I 1350 /I 1580 <2.5.
7 . The electrochemical apparatus according to claim 1 , wherein the carbon layer is a velvet structure with a length of 20 nm to 50 nm.
8 . An electrochemical apparatus, comprising:
a positive electrode plate, a negative electrode plate, and a separator disposed between the positive electrode plate and the negative electrode plate; wherein
the negative electrode plate comprises a negative electrode current collector and a negative electrode active substance layer disposed on the negative electrode current collector, wherein the negative electrode active substance layer comprises a negative electrode material, wherein the negative electrode material comprises
a silicon-based material, wherein
the silicon-based material comprises a silicon oxide material and a carbon layer located on a surface of the silicon oxide material; and
a particle size distribution of the silicon-based material satisfies 1≤(D n 99−D n 10)/D n 50≤2.02, D n 10≥1 μm, D n 50≥3 μm, and 6.2 μm≤D n 99≤12.3 μm, wherein D n 10, D n 50 and D n 99 are particle sizes when a cumulative number of particles calculated in ascending order of particle sizes reaches 10%, 50%, and 99% of the total number of particles, respectively, in a number distribution diagram of particle sizes of the silicon-based material;
wherein the electrochemical apparatus further comprises an electrolyte,
wherein the electrolyte comprises an organic solvent and a lithium salt, and the organic solvent comprises fluoroethylene carbonate (FEC), wherein a mass percentage of FEC in the electrolyte is from 3% to less than 10%.
9 . The electrochemical apparatus according to claim 8 , wherein the negative electrode material further comprises graphite.
10 . The electrochemical apparatus according to claim 9 , wherein a mass of the silicon-based material accounts for 5% to 100% of a total mass of the silicon-based material and the graphite.
11 . The electrochemical apparatus according to claim 9 , wherein the graphite comprises at least one of natural graphite, artificial graphite, or meso-carbon microbeads.
12 . The electrochemical apparatus according to claim 8 , wherein in a Raman spectrum of the carbon layer, a ratio of a peak intensity at 1350 cm −1 I 1350 to a peak intensity at 1580 cm −1 I 1580 satisfies 1.0<I 1350 /I 1580 <2.5.
13 . The electrochemical apparatus according to claim 8 , wherein the carbon layer is a velvet structure with a length of 20 nm to 50 nm.
14 . The electrochemical apparatus according to claim 8 , wherein the negative electrode active substance layer comprises a binder, wherein
the binder comprises at least one of polyacrylate, polyimide, polyamide, polyamideimide, polyfluoroethylene, styrene butadiene rubber, sodium alginate, polyvinyl alcohol, polytetrafluoroethylene, polyacrylonitrile, sodium carboxymethyl cellulose, potassium carboxymethyl cellulose, sodium hydroxymethyl cellulose, or potassium hydroxymethyl cellulose.
15 . The electrochemical apparatus according to claim 8 ,
wherein the organic solvent further comprises at least one of ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), dimethyl carbonate (DMC), polypropylene carbonate, or ethyl propionate.
16 . An electronic apparatus, comprising the electrochemical apparatus according to claim 8 .