Ion-conductive solid and all-solid-state battery
Provided are: an ion-conductive solid which can be produced by heat treatment at a low temperature and which has high ion conductivity; and, an all-solid-state battery having the ion-conductive solid. An ion-conductive solid containing an oxide represented by the general formula Li 6-3a-2b-c-d Yi 1-c-d Al a Mg b Zr c Ce d B 3 O 9 ; and, an all-solid-state battery having at least a positive electrode, a negative electrode, and an electrolyte, at least one element selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte containing the ion-conductive solid (In the formula, a is such that 0.000≤a≤0.800, b is such that 0.000≤b≤0.800, c is such that 0.000≤c≤0.400, d is such that 0.000≤d≤0.400, and a and b are real numbers satisfying 0.005≤a+b≤0.800.).
1 . An ion-conductive solid comprising an oxide represented by Formula Li 6-3a-2b-c-d Y 1-c-d Al a Mg b Zr c Ce d B 3 O 9 ,
wherein in the formula, a, b, c and d are real numbers satisfying 0.000≤a≤0.800, 0.000≤b≤0.800, 0.000≤c≤0.400, 0.000≤d≤0.400, and 0.005≤a+b≤0.800.
2 . The ion-conductive solid according to claim 1 , wherein the c and the d are 0.000≤c≤0.200 and 0.000≤d≤0.200.
3 . The ion-conductive solid according to claim 1 , wherein the a is 0.000≤a≤0.400.
4 . The ion-conductive solid according to claim 1 , wherein the b is 0.000≤b≤0.400.
5 . The ion-conductive solid according to claim 1 , wherein the a+b is 0.010≤a+b≤0.800.
6 . The ion-conductive solid according to claim 1 , wherein the a+b is 0.010≤a+b≤0.400.
7 . The ion-conductive solid according to claim 1 , wherein the a, the b, the c and the d are 0.000≤c≤0.200, 0.000≤d≤0.200 and 0.010≤a+b≤0.100.
8 . An all-solid-state battery, comprising at least:
a positive electrode;
a negative electrode; and
an electrolyte,
wherein at least one selected from the group consisting of the positive electrode, the negative electrode and the electrolyte comprises the ion-conductive solid according to claim 1 .
9 . The all-solid-state battery according to claim 8 , wherein at least the electrolyte comprises the ion-conductive solid.