Surface treatment method, dry etching method, cleaning method, production method for semiconductor device, and etching device
The present disclosure aims to provide a surface treatment method using a gas composition capable of removing a metal oxide or metal at low temperatures without using plasma. The present disclosure provides a surface treatment method including bringing a gas into contact with a surface of a workpiece, wherein the gas contains a β-diketone, a first additive gas, and a second additive gas, the first additive gas is NO, and the second additive gas is at least one selected from the group consisting of O 2 and NO 2 .
1 . A dry etching method, comprising:
bringing an etching gas into contact with an etching target film for etching in a non-plasma state, the etching target film being formed on a surface of a workpiece and containing a metal or an oxide of the metal,
wherein the etching gas contains a β-diketone, a first additive gas, and second additive gas,
the first additive gas is NO,
the second additive gas is at least one selected from the group consisting of O 2 and NO 2 , and
the metal or the oxide of the metal is at least one selected from the group consisting of group 13 metals, group 14 metals, and oxides of these metals.