Method of purifying helium from mixed gas
In an aspect, a hydrogen separation unit includes an electrochemical cell stack that includes a separator stack located in between an anode side and a cathode side; a mixed gas conduit for receiving a mixed gas stream to the anode side; an anode removal conduit for removing a helium rich stream from the anode side; and a cathode removal conduit for removing a hydrogen rich stream from the cathode side. The separation stack includes a plurality of electrochemical cells, each of which includes a proton exchange membrane located in between an anode and a cathode. The proton exchange membrane can include a cation. The separation stack can be a cascading separation stack.
1 . A hydrogen separation unit comprising:
an electrochemical cell stack comprising a separator stack located in between an anode side and a cathode side;
a mixed gas conduit for receiving a mixed gas stream to the anode side;
an anode removal conduit for removing a helium rich stream from the anode side; and
a cathode removal conduit for removing a hydrogen rich stream from the cathode side;
wherein the separator stack comprises a plurality of electrochemical cells, each of which comprises a proton exchange membrane located in between an anode and a cathode; and
wherein at least one of
the proton exchange membrane comprises a cation other than H+, or
the separator stack is a cascading separation stack partitioned to maintain consistent gas velocity.
2 . The hydrogen separation unit of claim 1 , wherein the proton exchange membrane comprises the cation.
3 . The hydrogen separation unit of claim 1 , wherein the cation comprises at least one of lithium, sodium, potassium, magnesium, nickel, calcium, cobalt, or cesium.
4 . The hydrogen separation unit of claim 1 , wherein the cation can take up to 90% of the total sites available for cation exchange prior to the cation being introduced.
5 . The hydrogen separation unit of claim 1 , wherein the separator stack is the cascading separation stack.
6 . The hydrogen separation unit of claim 1 , wherein the separator stack is the cascading separation stack comprising a first portion of cells and a second portion of cells, wherein a first portion helium rich stream from the first portion of cells is in fluid communication with the second portion of cells.
7 . The hydrogen separation unit of claim 6 , wherein an average cation concentration in the proton exchange membranes in the first portion of cells is less than an average cation concentration in the proton exchange membranes in the second portion of cells.
8 . The hydrogen separation unit of claim 1 , further comprising a helium separation unit in fluid communication with the helium rich stream;
wherein the helium separation unit comprises a helium conduit for removing a helium product stream from the helium separation unit.
9 . The hydrogen separation unit of claim 8 , wherein the helium separation unit is a pressure swing adsorption unit or a membrane separation unit.
10 . The hydrogen separation unit of claim 1 , further comprising a mechanical compressor in fluid communication with the helium rich stream downstream of the electrochemical cell stack configured to increase the pressure of the helium rich stream.
11 . The hydrogen separation unit of claim 1 , further comprising a back-pressure valve or a vessel in fluid communication with the hydrogen-rich stream downstream of the electrochemical cell stack configured to increase the pressure of the hydrogen-rich stream.