Additive manufacturing method to achieve three dimensional parts having superior properties
Additive manufacturing methods to achieve three dimensional parts having superior properties are provided herein.
1 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir, wherein the photocurable composition comprises a solid functionalized component;
B. Subjecting the photocurable composition to conditions favorable to render the photocurable composition in a flowable state; and
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein in step B the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C. and
in step C the photocurable composition is exposed to a temperature of about 45° C. to about 160° C.
2 . The method of claim 1 , wherein in step B the photocurable composition is exposed to a temperature of between about 60° C. to about 120° C.
3 . The method of claim 1 , wherein in step B the photocurable composition has a vapor pressure less than about 1 mm Hg.
4 . The method of claim 1 , wherein in step B the photocurable composition has a vapor pressure less than about 0.1 mm Hg.
5 . The method of claim 1 , wherein in step B the photocurable composition has a vapor pressure less than about 0.01 mm Hg.
6 . The method of claim 1 , wherein in step C the photocurable composition has a vapor pressure less than about 0.1 mm Hg.
7 . The method of claim 1 , wherein in step C the photocurable composition has a vapor pressure less than about 0.01 mm Hg.
8 . The method of claim 1 , wherein in step B the photocurable composition is maintained in a reservoir, which is heated to a temperature of about 45° C. to about 160° C.
9 . The method of claim 1 , wherein in step B the photocurable composition is maintained in a reservoir, which is heated to a temperature of about 60° C. to about 120° C.
10 . The method of claim 1 , wherein in step C the photocurable composition is exposed to a temperature of about 60° C. to about 120° C.
11 . The method of claim 1 , wherein in step C the photocurable composition is maintained at a temperature that allows the photocurable composition to be flowable.
12 . The method of claim 1 , wherein in step B the photocurable composition is dispensed at a temperature of about 30° C. to about 120° C. greater than room temperature.
13 . The method of claim 1 , wherein in step C the photocurable composition is printed at a temperature of about 30° C. to about 120° C. greater than room temperature.
14 . The method of claim 1 , wherein in step C the photocurable composition is exposed to radiation in the electromagnetic spectrum in a range of 355 nm to 405 nm.
15 . The method of claim 1 , wherein in step C the photocurable composition is exposed to radiation in the electromagnetic spectrum emitted from a LED source.
16 . The method of claim 1 , wherein in step C the photocurable composition is exposed to radiation in the electromagnetic spectrum emitted from a LED source selected from a laser, a plurality of lasers, a projector or a plurality of projectors.
17 . The method of claim 1 , wherein in step C the photocurable composition is exposed to radiation in the electromagnetic spectrum emitted from a LED source applied from beneath a reservoir in which is contained the photocurable composition.
18 . The method of claim 1 , wherein in step C the photocurable composition is exposed to radiation in the electromagnetic spectrum emitted from a LED source applied from above a reservoir in which is contained the photocurable composition.
19 . The method of claim 1 , wherein in step C polymerization of the photocurable composition occurs through a single reaction mechanism.
20 . The method of claim 1 , wherein the solid functionalized component has at least one functional group selected from (meth)acrylates, α-olefins, N-vinyls, vinylamides, cyanoacrylates, (meth)acrylamides, acryloyls, styrenics, epoxides, thiols, 1,3-dienes, vinyl halides, acrylonitriles, vinyl esters, maleimides, nadimides, itaconimides, vinyl ethers, vinyl carbonates, and vinyl carbamates.
21 . The method of claim 1 , wherein the solid functionalized component has a molecular weight of greater than about 400 daltons.
22 . The method of claim 1 , wherein the solid functionalized component has a molecular weight of greater than about 800 daltons.
23 . The method of claim 1 , wherein the solid functionalized component has a molecular weight of greater than about 1200 daltons.
24 . The method of claim 1 , wherein the solid functionalized component comprises a crystalline structure at or above a temperature of about 25° C.
25 . The method of claim 1 , wherein in step A the photocurable composition comprises a solid functionalized component having a backbone selected from sulfones, styrenes, isocyanurates, cyanate esters, maleimides, nadimides, itaconamides, adamantyl, biphenyls, novolak, norbornyls, triazines, carbonates, amides, urethanes, ureas, polyesters and combinations thereof.
26 . The method of claim 1 , wherein in step A the photocurable composition comprises a photoinitiator.
27 . The method of claim 1 , wherein the solid functionalized component has no added thermal initiator.
28 . The method of claim 1 , wherein in step C in addition to exposure to radiation in the electromagnetic spectrum, the photocurable composition is exposed to a temperature condition greater than the elevated temperature conditions used in step B to render the photocurable composition flowable.
29 . The method of claim 1 , further comprising step D:
D. Contacting the three-dimensional part with a solvent or a wash liquid.
30 . The method of claim 1 , further comprising step E:
E. Exposing the three-dimensional part formed in step C to an elevated temperature condition that is greater than the temperature condition to which the photocurable composition is exposed in step C.
31 . The method of claim 29 , further comprising step E:
E. Exposing the three-dimensional part formed in step C to an elevated temperature condition that is greater than the temperature condition to which the photocurable composition is exposed in step C.
32 . The method of claim 30 , wherein in step E the elevated temperature condition is a temperature condition greater than the elevated temperature condition to which the photocurable composition is exposed in step B.
33 . The method of claim 30 , wherein in step E the elevated temperature condition is achieved by ramping at a pre-determined rate from the temperature condition of step B to at least one higher temperature condition.
34 . The method of claim 30 , wherein in step E the elevated temperature condition is at least 160° C.
35 . The method of claim 30 , wherein in step E polymerization of the photocurable composition occurs through a single reaction mechanism.
36 . The method of claim 1 , further comprising step F:
F. Exposing the three-dimensional part formed in step C to radiation in the electromagnetic spectrum of a wavelength different from the radiation in the electromagnetic spectrum used in step C.
37 . The method of claim 36 , wherein in step F the three-dimensional part is exposed to radiation in the electromagnetic spectrum emitted from a light source selected from an LED light source or a broad-band light source.
38 . The method of claim 36 , wherein in step F the three-dimensional part is exposed to a second form of radiation in the electromagnetic spectrum.
39 . The method of claim 36 , wherein in step F the three-dimensional part is exposed to a second form of radiation in the electromagnetic spectrum selected from gamma irradiation, electron beam or microwave irradiation.
40 . The method of claim 1 , wherein the photocurable composition is provided as chips, pellets, powder, wire, spooled or some other granule solid form factor.
41 . The method of claim 1 , wherein the photocurable composition is exposed to an elevated temperature of between about 45° C. to about 160° C. in a hopper system to render it into a flowable state.
42 . The method of claim 1 , wherein the photocurable composition is exposed to an elevated temperature in a continuous manner, through a nozzle, heated core, hot end, heated extruder or similar device.
43 . The method of claim 1 wherein the photocurable composition is provided in a physical form factor with a surface area to volume ratio greater than 0.5:1.
44 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir;
B. Subjecting the photocurable composition to conditions favorable to render the photocurable composition in a flowable state; and
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein in step B and/or step C the photocurable composition has a vapor pressure less than about 1 mm Hg,
wherein in step B the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C. and
in step C the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C.
45 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir;
B. Subjecting the photocurable composition to conditions favorable to render the photocurable composition in a flowable state; and
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein in step A the photocurable composition comprising a solid functionalized component demonstrates a phase change from solid to liquid within a 5° C. increase in temperature measured by DSC over a period of time of 20 minutes.
46 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir;
B. Subjecting the photocurable composition to conditions favorable to render the photocurable composition in a flowable state; and
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein the three-dimensional part formed in step C has a heat deflection temperature (@0.455 MPa) at least as high as the elevated temperature of step B and/or step C,
wherein in step B the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C. and
in step C the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C.
47 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir;
B. Subjecting the photocurable composition to conditions favorable to render the photocurable composition in a flowable state; and
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein the three-dimensional part formed after step C achieves at least about 50% of at least one of its ultimate strength, its ultimate stiffness and its ultimate heat deflection temperature,
wherein in step B the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C. and
in step C the photocurable composition is exposed to a temperature of between about 45° C. to about 160° C.
48 . The method of claim 47 , wherein the three-dimensional part formed after step E achieves about 100% of at least one of its ultimate strength, its ultimate stiffness and its ultimate heat deflection temperature.
49 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates substantially homogeneous strength, stiffness and heat deflection temperature throughout its volume, regardless of size, geometry, internal complexity or surfaces irrespective of where the measurement is taken on the part.
50 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a tensile elongation>=yield strength of the three-dimensional part.
51 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a tensile elongation of at least about 6%.
52 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a tensile elongation of at least about 10%.
53 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a heat deflection temperature (@ 0.455 MPa) of greater than 100° C.
54 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a heat deflection temperature (@ 0.455 MPa) of greater than 120° C.
55 . The method of claim 48 , wherein the three-dimensional part formed after step E demonstrates a heat deflection temperature (@ 0.455 MPa) of greater than 160° C.
56 . A method for performing additive manufacturing using a photocurable composition to form a three-dimensional part having superior physical properties, said three-dimensional part made according to data indicating a pre-determined pattern, comprising the steps of:
A. Providing a photocurable composition in a non-flowable state to a reservoir;
B. Subjecting the photocurable composition to a temperature condition favorable to render the photocurable composition in a flowable state, wherein the temperature condition is between about 45° C. and about 160° C.;
C. Exposing the flowable photocurable composition to radiation in the electromagnetic spectrum appropriate to initiate polymerization thereof as the three-dimensional printed part is made according to data indicating a pre-determined pattern, wherein in step C the photocurable composition is exposed to a temperature of between about 45° C. and about 160° C.; and
D. Exposing the three-dimensional part formed in step C to an elevated temperature condition that is greater than the temperature condition to which the photocurable composition is exposed in step B and/or step C.