IP Library Granted Patent US 12691686
Granted Patent B2
US 12691686 · App. 18/816,796 · Granted Jul 28, 2026

Ink jet recording method and ink jet recording apparatus

Inventors: Keita Ishimi (Kanagawa, JP); Toshimitsu Danzuka (Tokyo, JP); Rie Takekoshi (Kanagawa, JP); Akihiro Tomida (Kanagawa, JP); Akiko Aichi (Tokyo, JP); Hiroto Kango (Tokyo, JP)
Assignee: Canon Kabushiki Kaisha
B41J2/16508B41M3/001C09D9/04C09D11/033C09D11/30C09D11/54
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Quick Facts
Patent No.
US 12691686
App. No.
18/816,796
Granted
Jul 28, 2026
Kind
B2
Abstract

An ink jet recording method for recording an image on a recording medium by ejecting an aqueous ink from a print head of an ink jet recording apparatus includes applying an aqueous ink onto a recording medium, and cleaning a liquid contact member coming into contact with the aqueous ink in the ink jet recording apparatus with an aqueous cleaning liquid. The cleaning liquid contains a surfactant, a first water-soluble organic solvent with a lower vapor pressure than water, a second water-soluble organic solvent with an SP value, measured by a Fedors method, of 9.8 or more to 14.2 or less, and a third water-soluble organic solvent with a water retention capacity of 50% or less in an amount by mass of 0.7 or more relative to the total amount by mass of the water-soluble organic solvents. The cleaning liquid has a pH of 8.5 or more.

Claims (117)

1 . An ink jet recording method for recording an image on a recording medium by ejecting an aqueous ink from a print head of an ink jet recording apparatus, the method comprising:

applying an aqueous ink onto a recording medium, the aqueous ink comprising a pigment and a resin particulate; and

cleaning a liquid contact member that comes into contact with the aqueous ink in the ink jet recording apparatus with an aqueous cleaning liquid,

wherein the ink jet recording apparatus includes a cleaning liquid supply path through which the cleaning liquid is supplied to the liquid contact member,

wherein the cleaning liquid comprises a surfactant, a first water-soluble organic solvent with a lower vapor pressure than water, a second water-soluble organic solvent with an SP value, measured by a Fedors method, of 9.8 or more to 14.2 or less, and a third water-soluble organic solvent with a water retention capacity of 50% or less in an amount by mass of 0.7 times or more relative to the total amount by mass of the water-soluble organic solvents, and the cleaning liquid has a pH of 8.5 or more,

wherein the first water-soluble organic solvent, the second water-soluble organic solvent, and the third water-soluble organic solvent are the same or different, and

wherein the water retention capacity is determined by allowing 10.0 g of 20% by mass aqueous liquid of the third water-soluble organic solvent placed in a laboratory dish to stand in an environment at a temperature of 30° C. and a relative humidity of 10%, measuring the mass of the residue in the laboratory dish when the mass no longer varies, and calculating the following equation (i):

Water

retention

capacity

(

%

)

=

[

mass

of

the

residue

in

the

laboratory

dish

(

g

)

-

2.

(

g

)

]

/

2.

(

g

)

.

(

i

)

2 . The ink jet recording method according to claim 1 , wherein the water retention capacity of the third water-soluble organic solvent is 30% or more.

3 . The ink jet recording method according to claim 1 , wherein the amount by mass (% by mass) of the third water-soluble organic solvent in the cleaning liquid is 0.9 times or more relative to the total amount by mass (% by mass) of the water-soluble organic solvents.

4 . The ink jet recording method according to claim 1 , wherein the liquid contact member includes a recovery mechanism for the print head.

5 . The ink jet recording method according to claim 1 , wherein the liquid contact member includes a supply mechanism for the aqueous ink.

6 . The ink jet recording method according to claim 1 , wherein the aqueous ink comprises at least one water-soluble organic solvent, and in the aqueous ink, the water-soluble organic solvent contained in the largest amount (% by mass) of the at least one water-soluble organic solvent has a higher vapor pressure (kPa) than the water-soluble organic solvent contained in the largest amount in the cleaning liquid.

7 . The ink jet recording method according to claim 1 , wherein the first water-soluble organic solvent in the cleaning liquid has a relative dielectric constant of 20.0 or more.

8 . The ink jet recording method according to claim 1 , wherein at least one of the water-soluble organic solvents in the cleaning liquid accounts for 10.0% by mass or more of the total mass of the cleaning liquid.

9 . The ink jet recording method according to claim 1 , wherein the cleaning liquid comprises a fourth water-soluble organic solvent with an SP value, measured by a Fedors method, of 9.8 or more to 12.2 or less in an amount of 10.0% by mass or less relative to the total amount by mass (% by mass) of the water-soluble organic solvents.

10 . The ink jet recording method according to claim 1 , wherein the surfactant in the cleaning liquid is a hydrocarbon-based nonionic surfactant with an HLB value, measured by a Griffin method, of 17 or less.

11 . The ink jet recording method according to claim 1 , wherein the cleaning liquid has a pH of 9.0 or more.

12 . The ink jet recording method according to claim 1 , further comprising applying an aqueous reaction liquid that reacts with the aqueous ink onto the recording medium.

13 . The ink jet recording method according to claim 1 , wherein the recording medium exhibits a water absorption of 10 mL/m 2 or less for a period of 30 ms 1/2 from the beginning of contact with water when measured by a Bristow method.

14 . An ink jet recording apparatus for recording an image on a recording medium by ejecting an aqueous ink from a print head, the apparatus comprising:

an ink application device configured to apply the aqueous ink onto a recording medium;

a cleaning device configured to clean a liquid contact member that comes into contact with the aqueous ink in the ink jet recording apparatus with an aqueous cleaning liquid; and

a cleaning liquid supply path through which the cleaning liquid is supplied to the liquid contact member,

wherein the aqueous ink contains a pigment and a water-soluble organic solvent with a higher vapor pressure than water,

wherein the cleaning liquid comprises a surfactant, a first water-soluble organic solvent with a lower vapor pressure than water, a second water-soluble organic solvent with an SP value, measured by a Fedors method, of 9.8 or more to 14.2 or less, and a third water-soluble organic solvent with a water retention capacity of 50% or less in an amount by mass of 0.7 times or more relative to the total amount by mass of the water-soluble organic solvents,

wherein the first water-soluble organic solvent, the second water-soluble organic solvent, and the third water-soluble organic solvent are the same or different, and

wherein the water retention capacity is determined by allowing 10.0 g of 20% by mass aqueous liquid of the third water-soluble organic solvent placed in a laboratory dish to stand in an environment at a temperature of 30° C. and a relative humidity of 10%, measuring the mass of the residue in the laboratory dish when the mass no longer varies, and calculating the following equation (i):

Water

retention

capacity

(

%

)

=

(

mass

(

g

)

of

the

residue

in

the

laboratory

dish

-

2.

(

g

)

)

/

2.

(

g

)

.

(

i

)