Silica sol, silica aerogel blanket manufactured using same, and method for manufacturing same
A silica sol, a silica aerogel blanket using the same, and a method for manufacturing the same, wherein a hydrophobizing agent, a base catalyst, an organic solvent, and water are included in a catalyst composition when manufacturing the silica aerogel blanket, so that a wet aging step which is performed under high-temperature conditions and increases the amount of a solvent used, and a surface modification step which uses a large amount of an organic solvent and an expensive surface modifier, resulting in a process that is complex and long and thus inhibiting economic feasibility and productivity, can be omitted.
1 . A method for manufacturing a silica sol, the method comprising:
1) preparing a silica precursor composition in a first container,
2) preparing a catalyst composition comprising a hydrophobizing agent, a base catalyst, water, and an organic solvent in a second container different from the first container, and
3) preparing the silica sol by mixing the silica precursor composition and the catalyst composition together,
wherein the base catalyst included in the catalyst composition is in an amount of 0.4 parts by weight to 1.0 part by weight based on 100 parts by weight of the silica sol, and
wherein the hydrophobizing agent is different from the base catalyst.
2 . The method of claim 1 , wherein the water is included in an amount of 3 equivalents to 8 equivalents based on 1 equivalent of the hydrophobizing agent.
3 . The method of claim 1 , wherein the hydrophobizing agent is included in an amount of 3 parts by weight to 15 parts by weight based on 100 parts by weight of the catalyst composition.
4 . The method of claim 1 , wherein the hydrophobizing agent comprises one or more selected from the group consisting of trimethylethoxysilane (TMES), trimethylsilanol (TMS), hexamethyldisiloxane (HMDSO), trimethylchlorosilane (TMCS), methyltrimethoxysilane (MTMS), methyltriethoxysilane (MTES), dimethyldiethoxysilane (DMDEOS), ethyltriethoxysilane, and phenyltriethoxysilane.
5 . The method of claim 1 , wherein the silica precursor in the silica precursor composition includes one or more selected from the group consisting of tetra methyl ortho silicate (TMOS), tetra ethyl ortho silicate (TEOS), methyl triethyl ortho silicate, dimethyl diethyl ortho silicate, tetra propyl ortho silicate, tetra isopropyl ortho silicate, tetra butyl ortho silicate, tetra secondary-butyl ortho silicate, tetra tertiary-butyl ortho silicate, tetra hexyl ortho silicate, tetra cyclohexyl ortho silicate, and tetra dodecyl ortho silicate, or a prehydrolysate of thereof.
6 . The method of claim 1 , wherein the silica precursor composition comprises a silica precursor, an organic solvent, and water.
7 . A method for manufacturing a silica aerogel blanket, the method comprising:
1) preparing a silica sol;
2) impregnating the silica sol into a substrate for a blanket; and
3) leaving the silica sol-substrate for a blanket composite to stand, wherein the silica sol is manufactured by the method of claim 1 .
8 . The method of claim 7 , wherein gelation, surface modification, and aging are performed in Step 3).
9 . The method of claim 7 , wherein Step 3) is performed without using a separate surface modification solution and an aging solution.
10 . The method of claim 7 , wherein Step 3) is performed under conditions of room temperature or temperatures exceeding room temperature.
11 . The method of claim 8 , wherein the time during which gelation is performed in Step 3) is 3 to 10 minutes.
12 . The method of claim 7 , further comprising a step of drying after Step 3).