Light emitting diode

1 . A light emitting diode, comprising:

a first electrode;

a second electrode disposed on the first electrode; and

an emission layer disposed between the first electrode and the second electrode, and comprising a polycyclic compound, wherein

the polycyclic compound comprises:

a first aromatic hydrocarbon ring;

a second aromatic hydrocarbon ring directly bonded to the first aromatic hydrocarbon ring;

a first atom directly bonded to the first aromatic hydrocarbon ring;

a second atom directly bonded to the first aromatic hydrocarbon ring or to the second aromatic hydrocarbon ring;

a first compound directly bonded to the first atom;

a second compound directly bonded to the first atom;

a third compound directly bonded to the second atom; and

a fourth compound directly bonded to the second atom,

the first atom and the second atom are each independently B, Al, or Ga,

at least one of the first compound or the second compound comprises a heteroatom,

at least one of the third compound or the fourth compound comprises a heteroatom,

at least one of the first to fourth compounds is combined with an adjacent group to form a ring, and

the first electrode and the second electrode each independently comprises at least one selected from Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, Zn, oxides thereof, compounds thereof, and mixtures thereof,

wherein the first aromatic hydrocarbon ring and the second aromatic hydrocarbon ring are each independently a substituted or unsubstituted benzene ring.

2 . The light emitting diode of claim 1 , wherein the first atom and the second atom are each a boron atom (B).

3 . The light emitting diode of claim 1 , wherein

the first compound to the fourth compound are each independently O(R 1a ) m1 , N(R 1b ) m2 , P(R 1c ) m3 , P(═O)(R 1d ) m4 , P(═S)(R 1e ) m5 , S(R 1f ) m6 , Si(R 1g ) m7 , Al(R 1h ) m8 , Ga(R 1i ) m9 , As(R 1j ) m10 , Ge(R 1k ) m11 , or C(R 1l ) m12 ,

R 1a to R 1l are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring,

m1 and m6 are each independently 0 or 1,

m2, m3, m4, m5, m8, m9, and m10 are each independently an integer from 0 to 2, and

m7, m11, and m12 are each independently an integer from 0 to 3.

4 . The light emitting diode of claim 1 , wherein the first compound or the second compound is directly bonded to the second aromatic hydrocarbon ring to form a ring.

5 . The light emitting diode of claim 1 , wherein in the case where the second atom is directly bonded to the first aromatic hydrocarbon ring,

the third compound or the fourth compound is directly bonded to the second aromatic hydrocarbon ring to form a ring.

6 . A light emitting diode, comprising:

a first electrode;

a second electrode disposed on the first electrode; and

an emission layer disposed between the first electrode and the second electrode, and comprising a polycyclic compound, wherein

the polycyclic compound comprises:

a first aromatic hydrocarbon ring;

a second aromatic hydrocarbon ring directly bonded to the first aromatic hydrocarbon ring;

a first atom directly bonded to the first aromatic hydrocarbon ring;

a second atom directly bonded to the first aromatic hydrocarbon ring or to the second aromatic hydrocarbon ring;

a first compound directly bonded to the first atom;

a second compound directly bonded to the first atom;

a third compound directly bonded to the second atom; and

a fourth compound directly bonded to the second atom,

the first atom and the second atom are each independently B, Al, or Ga,

at least one of the first compound or the second compound comprises a heteroatom,

at least one of the third compound or the fourth compound comprises a heteroatom,

at least one of the first to fourth compounds is combined with an adjacent group to form a ring, and

the first electrode and the second electrode each independently comprises at least one selected from Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, Zn, oxides thereof, compounds thereof, and mixtures thereof,

wherein in the case where the second atom is directly bonded to the second aromatic hydrocarbon ring, and

the third compound or the fourth compound is directly bonded to the first aromatic hydrocarbon ring to form a ring.

7 . The light emitting diode of claim 1 , wherein the second aromatic hydrocarbon ring is directly bonded to the first aromatic hydrocarbon ring at an ortho position with respect to the first atom.

8 . The light emitting diode of claim 1 , wherein the polycyclic compound is represented by Formula A or Formula B:

wherein in Formula A and Formula B,

X 1 and X 2 are each independently B, Al, or Ga,

Y 1 , Y 2 , Y 3 , and Y 4 are each independently O(R 1a ) m1 , N(R 1b ) m2 , P(R 1c ) m3 , P(═O)(R 1d ) m4 , P(═S)(R 1e ) m5 , S(R 1f ) m6 , Si(R 1g ) m7 , Al(R 1h ) m8 , Ga(R 1i ) m9 , As(R 1j ) m10 , Ge(R 1k ) m11 , or C(R 1l ) m12 ,

R 1 , R 2 , and R 1a to R 1l are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring,

a and b are each independently an integer from 0 to 3,

m1 and m6 are each independently 0 or 1,

m2, m3, m4, m5, m8, m9, and m10 are each independently an integer from 0 to 2, and

m7, m11, and m12 are each independently an integer from 0 to 3.

9 . The light emitting diode of claim 1 , wherein

the emission layer comprises a dopant and a host, and

the dopant comprises the polycyclic compound.

10 . The light emitting diode of claim 1 , wherein the emission layer emits blue light.

11 . The light emitting diode of claim 1 , wherein the emission layer emits thermally activated delayed fluorescence.

12 . The light emitting diode of claim 1 , wherein the polycyclic compound comprises one selected from Compound Group 1:

13 . A light emitting diode, comprising:

a first electrode;

a second electrode disposed on the first electrode; and

at least one functional layer disposed between the first electrode and the second electrode, wherein

the first electrode and the second electrode each independently comprises at least one selected from Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, Zn, oxides thereof, compounds thereof, and mixtures thereof, and

the at least one functional layer comprises a polycyclic compound represented by Formula A or Formula B:

wherein in Formula A and Formula B,

X 1 and X 2 are each independently B, Al, or Ga,

Y 1 , Y 2 , Y 3 , and Y 4 are each independently O(R 1a ) m1 , N(R 1b ) m2 , P(R 1c ) m3 , P(═O)(R 1d ) m4 , P(═S)(R 1e ) m5 , S(R 1f ) m6 , Si(R 1g ) m7 , Al(R 1h ) m8 , Ga(R 1i ) m9 , As(R 1j ) m10 , Ge(R 1k ) m11 , or C(R 1l ) m12 ,

R 1 , R 2 , and R 1a to R 1l are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring,

a and b are each independently an integer from 0 to 3,

m1 and m6 are each independently 0 or 1,

m2, m3, m4, m5, m8, m9, and m10 are each independently an integer from 0 to 2, and

m7, m11, and m12 are each independently an integer from 0 to 3.

14 . The light emitting diode of claim 13 , wherein

the polycyclic compound represented by Formula A is represented by Formula A-1, and

the polycyclic compound represented by Formula B is represented by Formula B-1:

wherein in Formula A-1 and Formula B-1,

Y 1 to Y 4 , R 1 , R 2 , a, and b are the same as defined in Formula A and Formula B.

15 . The light emitting diode of claim 13 , wherein

the polycyclic compound represented by Formula A is represented by Formula A-2, and

the polycyclic compound represented by Formula B is represented by Formula B-2:

wherein in Formula A-2 and Formula B-2,

Cy 1 , Cy 2 , Cy 3 , and Cy 4 are each independently a substituted or unsubstituted aromatic hydrocarbon ring,

c is 0 or 1,

d and e are each independently an integer from 0 to 2, and

X 1 , X 2 , Y 1 to Y 4 , R 1 , R 2 , and b are the same as defined in Formula A and Formula B.

16 . The light emitting diode of claim 13 , wherein the polycyclic compound represented by Formula A or Formula B is represented by one of Formula C-1 to Formula C-6:

wherein in Formula C-1 to Formula C-6,

X 11 to X 36 are each independently B, Al, or Ga,

Y 11 to Y 62 are each independently O(R 1a ) m1 , N(R 1b ) m2 , P(R 1c ) m3 , P(═O)(R 1d ) m4 , P(═S)(R 1e ) m5 , S(R 1f ) m6 , Si(R 1g ) m7 , Al(R 1h ) m8 , Ga(R 1 ) m9 , As(R 1j ) m10 , Ge(R 1k ) m11 , or C(R 1l ) m12 ,

R 11 to R 47 , and R 1a to R 1l are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted boron group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, or are combined with an adjacent group to form a ring,

n1, n10, n11, n14, n19, n24, n27, n28, n30, n31, n32, n35, and n36 are each independently 0 or 1,

n7, n17, n21, n23, n25, n34, and n37 are each independently an integer from 0 to 2,

n2, n6, and n8 are each independently an integer from 0 to 3,

n3, n4, n5, n9, n12, n13, n15, n16, n18, n20, n22, n26, n29, and n33 are each independently an integer from 0 to 4,

m1 and m6 are each independently 0 or 1,

m2, m3, m4, m5, m8, m9, and m10 are each independently an integer from 0 to 2, and

m7, m11, and m12 are each independently an integer from 0 to 3.

17 . The light emitting diode of claim 16 , wherein the polycyclic compound represented by one of Formula C-1 to Formula C-6 is represented by one of Formula D-1 to Formula D-6:

wherein in Formula D-1 to Formula D-6,

Y 11 to Y 62 , R 11 to R 47 , and n1 to n37 are the same as defined in Formula C-1 to Formula C-6.

18 . The light emitting diode of claim 16 , wherein Y 11 to Y 62 are each independently O(R 1a ) m1 , N(R 1b ) m2 , S(R 1f ) m6 , or C(R 1l ) m12 .

19 . The light emitting diode of claim 13 , wherein the polycyclic compound represented by Formula A or Formula B comprises one selected from Compound Group 1: