Graphene-modified polymeric foam and articles made thereof
Graphene-modified polymeric foam materials are provided that are amenable to conventional foams to yield articles with superior properties relative to like articles absent the graphene cell modifier. Graphene-based cell modifiers are incorporated in the polymer before or during the foaming process to not only improve the mechanical, thermal, electrical, fire retardant, or barrier properties of the polymer matrix itself, but also help modify the size, density, and morphology of cells in the foam, thereby tailoring the properties of the final foam articles. The graphene-modified polymeric foam materials may be utilized for the manufacturing of articles for mechanical, thermal, noise reduction, or sound absorption applications. The graphene-modified foams and articles made thereof have the advantages higher mechanical strength, better thermal stability, and better sound absorption properties as compared to the conventional polymeric foams such as materials made by copolymer polyol.
1 . An article made of graphene-modified polymeric foam comprising:
a graphene-based cell modifier and at least one polymer resin in which said graphene-based cell modifier used as a filler is intermixed;
the graphene-based cell modifier being a two-dimensional flake material with a thickness of from 0.34 nm to less than 5 nm and a diameter from 0.1 micron to less than 0.9 micron; and
the graphene-based cell modifier being incorporated by infusing said graphene-based cell modifier in one or more of precursors for the polymer resin, wherein the graphene-modified polymeric foam exhibits a flexural strength increase of from about 30% to about 100% relative to a comparable polymeric foam lacking the graphene-based cell modifier.
2 . The article of claim 1 , wherein the polymeric resin is one of polyurethane (PU), polystyrene (PS), polyvinyl chloride (PVC), epoxy, silicone, polypropylene (PP), polyethylene (PE), polyolefin, polyester, polyimide (PI), nitrile rubber, styrene-butadiene rubber (SBR), ethylene-vinyl acetate (EVA), polychloroprene (PCP), isoprene, neoprene, ethylene propylene diene terpolymer (EPDM), fluoroelastomer, and a combination of any of the above polymers thereof.
3 . The article of claim 1 , further comprising: one or more additives of a catalyst, a cell stabilizer, a barrier, an anti-oxidant, an anti-corrosion agent, a flame retardant, a lubricant, a dye, a pigment, a plasticizer, a thermal conductive agent, an electrically conductive agent, an insulator, and a filler.
4 . The article of claim 1 , wherein the foam material is made by one of batch foaming, extrusion foaming, or foam-injection molding.
5 . The article of claim 1 , wherein the graphene-based cell modifier is one or more of: graphene, few-layer graphene, graphene nanoplatelet, graphene oxide, reduced graphene oxide, doped graphene, functionalized graphene, and a combination thereof.
6 . The article of claim 1 , wherein the graphene-based cell modifier is present from 0.0001 wt % to 10 wt %.
7 . The article of claim 1 , wherein the graphene-based cell modifier is present from 0.001% to 5 wt %.
8 . The article of claim 1 , wherein the graphene-based cell modifier is present from 0.01% to 2 wt %.
9 . The article of claim 1 , wherein the graphene-based cell modifier is present from 0.1% to 1 wt %.
10 . An article made of graphene-modified polymeric foam comprising:
a graphene-based cell modifier and at least a polyurethane resin in which said graphene-based cell modifier used as a filler is intermixed;
the graphene-based cell modifier being a two-dimensional flake material with a thickness of from 0.34 nm to less than 5 nm and a diameter from 0.1 micron to less than 0.9 micron; and
the graphene-based cell modifier being incorporated by infusing said graphene-based cell modifier in one or more of polyol precursors for the polyurethane resin, wherein the graphene-modified polymeric foam exhibits a flexural strength increase of from about 30% to about 100% relative to a comparable polymeric foam lacking the graphene-based cell modifier.
11 . The article of claim 10 , wherein the graphene-based cell modifier is one or more of: graphene, few-layer graphene, graphene nanoplatelet, graphene oxide, reduced graphene oxide, doped graphene, functionalized graphene, and a combination thereof.
12 . The article of claim 10 , further comprising: one or more additives of a catalyst, a cell stabilizer, a barrier, an anti-oxidant, an anti-corrosion agent, a flame retardant, a lubricant, a dye, a pigment, a plasticizer, a thermal conductive agent, an electrically conductive agent, an insulator, and a filler.
13 . The article of claim 10 , wherein the foam material is made by one of batch foaming, extrusion foaming, and foam-injection molding.
14 . The article of claim 10 , wherein the graphene-based cell modifier is present from 0.0001 wt % to 10 wt %.
15 . The article of claim 10 , wherein the graphene-based cell modifier is present from 0.001% to 5 wt %.
16 . The article of claim 10 , wherein the graphene-based cell modifier is present from 0.01% to 2 wt %.
17 . The article of claim 10 , wherein the graphene-based cell modifier is present from 0.1% to 1 wt %.
18 . An article made of graphene-modified polymeric foam comprising:
a graphene-based cell modifier and at least one polymer resin in which said graphene-based cell modifier used as a filler is intermixed, the at least one polymer resin having a cellular structure including a plurality of cells with an average size;
the graphene-based cell modifier being a two-dimensional flake material with a thickness of from 0.34 nm to less than 5 nm and a diameter from 0.1 micron to less than 5 microns, the diameter of the graphene-based cell modifier being less than the average size of the cells, and having a surface area of 500 m 2 /g; and
the graphene-based cell modifier being incorporated by infusing said graphene-based cell modifier in one or more of precursors for the polymer resin.
19 . The article of claim 18 , wherein the polymeric resin is one of polyurethane (PU), polystyrene (PS), polyvinyl chloride (PVC), epoxy, silicone, polypropylene (PP), polyethylene (PE), polyolefin, polyester, polyimide (PI), nitrile rubber, styrene-butadiene rubber (SBR), ethylene-vinyl acetate (EVA), polychloroprene (PCP), isoprene, neoprene, ethylene propylene diene terpolymer (EPDM), fluoroelastomer, and a combination of any of the above polymers thereof.
20 . The article of claim 18 , further comprising: one or more additives of a catalyst, a cell stabilizer, a barrier, an anti-oxidant, an anti-corrosion agent, a flame retardant, a lubricant, a dye, a pigment, a plasticizer, a thermal conductive agent, an electrically conductive agent, an insulator, and a filler.
21 . The article of claim 18 , wherein the graphene-based cell modifier is one or more of: graphene, few-layer graphene, graphene nanoplatelet, graphene oxide, reduced graphene oxide, doped graphene, functionalized graphene, and a combination thereof.
22 . The article of claim 18 , wherein the graphene-based cell modifier is present from 0.0001 wt % to 10 wt %.
23 . An article made of graphene-modified polymeric foam comprising:
a graphene-based cell modifier and at least one polymer resin in which said graphene-based cell modifier used as a filler is intermixed, the at least one polymer resin having a cellular structure including a plurality of cells with an average size;
the graphene-based cell modifier being a two-dimensional flake material with a thickness of from 0.34 nm to less than 5 nm and a diameter from 0.1 micron to less than 5 microns, the diameter of the graphene-based cell modifier being less than the average size of the cells, and having a surface area of 300 m 2 /g; and
the graphene-based cell modifier being incorporated by infusing said graphene-based cell modifier in one or more of precursors for the polymer resin.
24 . The article of claim 23 , wherein the polymeric resin is one of polyurethane (PU), polystyrene (PS), polyvinyl chloride (PVC), epoxy, silicone, polypropylene (PP), polyethylene (PE), polyolefin, polyester, polyimide (PI), nitrile rubber, styrene-butadiene rubber (SBR), ethylene-vinyl acetate (EVA), polychloroprene (PCP), isoprene, neoprene, ethylene propylene diene terpolymer (EPDM), fluoroelastomer, and a combination of any of the above polymers thereof.
25 . The article of claim 23 , further comprising: one or more additives of a catalyst, a cell stabilizer, a barrier, an anti-oxidant, an anti-corrosion agent, a flame retardant, a lubricant, a dye, a pigment, a plasticizer, a thermal conductive agent, an electrically conductive agent, an insulator, and a filler.
26 . The article of claim 23 , wherein the graphene-based cell modifier is one or more of: graphene, few-layer graphene, graphene nanoplatelet, graphene oxide, reduced graphene oxide, doped graphene, functionalized graphene, and a combination thereof.
27 . The article of claim 23 , wherein the graphene-based cell modifier is present from 0.0001 wt % to 10 wt %.