Seal member and method for manufacturing same
A seal member includes a γ′ precipitation-hardening alloy, in which the γ′ precipitation-hardening alloy has a component composition of, in mass %: Ni: from 40 to 62%; Cr: from 13 to 20%; Ti: from 1.5 to 2.8%; Al: from 1.0 to 2.0% (provided that Ti/Al: 2.0 or less); Nb: 2.0% or less; Ta: 2.0% or less (provided that Nb+Ta: from 0.2 to 2.0%); B: from 0.001 to 0.010%; W: 3.0% or less; and Mo: 2.0% or less (provided that Mo+(½)W: from 1.0 to 2.5%), and optionally, C: 0.08% or less; Si: 1.0% or less; Mn: 1.0% or less; P: 0.02% or less; and S: 0.01% or less, with the balance being Fe and inevitable impurities, and in which the seal member has a hardness of 250 Hv or more, and includes a cold-rolled microstructure obtained by a cold rolling.
1 . A seal member made of a γ′ precipitation-hardening alloy,
wherein the γ′ precipitation-hardening alloy has a component composition consisting of, in mass %:
Ni: from 40 to 62%;
Cr: from 13 to 20%;
Ti: from 1.5 to 2.8%;
Al: from 1.0 to 2.0% provided that Ti/Al: 2.0 or less;
Nb: 2.0% or less;
Ta: 2.0% or less provided that Nb+Ta: from 0.2 to 2.0%;
B: from 0.001 to 0.010%;
W: 3.0% or less; and
Mo: 2.0% or less provided that Mo+(½)W: from 1.0 to 2.5%, and optionally,
C: 0.08% or less;
Si: 1.0% or less;
Mn: 1.0% or less;
P: 0.02% or less;
S: 0.01% or less;
Co: 5% or less; and
Cu: from 0.1% to 3.0%,
with the balance being Fe and inevitable impurities, and
wherein the seal member has a hardness of 250 Hv or more, and has a cold-rolled microstructure where precipitates comprising a γ′ phase are dispersed in a crystal grain, and
wherein the cold-rolled microstructure maintains an area ratio of an unrecrystallized grain comprising the γ′ phase in a crystal grain at 20% or more in an observation cross-section after heating at 900° C. for 400 hours.
2 . The seal member according to claim 1 , wherein the cold-rolled microstructure comprises 0.05% or more of an inhomogeneous strain.
3 . The seal member according to claim 1 , wherein the cold-rolled microstructure maintains an area ratio of an unrecrystallized grain comprising the γ′ phase in a crystal grain at 30% or more in an observation cross-section after heating at 900° C. for 400 hours.
4 . The seal member according to claim 1 , wherein the seal member has a thickness in the range of from 0.05 mm to 0.5 mm.
5 . The seal member according to claim 1 , wherein the cold-rolled microstructure includes an inhomogeneous strain in the range of from 0.05% to 0.33%.
6 . The seal member according to claim 1 , wherein the seal member exhibits a high-temperature hardness in the range of from 170 Hv to 230 Hv at 900° C.
7 . The seal member according to claim 1 , wherein the cold-rolled microstructure is obtained without heat treatment after cold rolling, maintaining the cold-rolled microstructure in the seal member as used.