Method for producing wet-running friction paper
A method is for producing a wet-running friction paper, at least containing a fiber fraction consisting of at least one type of fiber, a fraction of at least one filler, and a fraction of a binder based on phenol resin. The fiber fraction, the filler fraction and the binder dissolved as a phenolate solution are processed together in a paper production process to form a pulp, and the binder is subsequently precipitated by means of a precipitating agent, preferably diluted sulfuric acid, and the pulp applied to a long screen is dried and cured while the temperature is raised.
1 . A method for producing a wet-running friction paper comprising:
at least one fiber fraction consisting of at least one type of fiber,
a fraction of at least one filler, and
a fraction of a binder based on phenol resin, the method comprising:
processing the fiber fraction, the filler fraction and the binder dissolved as a phenolate solution together in a paper production process to form a pulp;
subsequently precipitating the binder by a precipitating agent;
drying the pulp on a long screen and curing the pulp while a temperature of the pulp is raised,
wherein particles of the binder are precipitated with a particle size between 200 and 1600 nm as a result of the precipitating of the binder.
2 . The method according to claim 1 , wherein the binder is phenolate resol.
3 . The method according to claim 1 , wherein a zeta potential of the pulp corresponds substantially to 80 mV.
4 . The method according to claim 1 , wherein the pulp is adjusted to a viscosity of less than 3000 Pa*s, based on a dwell time of 800 s.
5 . The method according to claim 1 , wherein the binder is adjusted to an activation energy greater than 60 KJ/mol with a frequency factor ln20 and a reaction order <1.5 during the curing thereof.
6 . The method according to claim 1 , wherein a particle size of precipitated binder particles is adjusted by a predetermined addition rate of the precipitating agent.
7 . The method according to claim 1 , wherein the binder is brought to a predetermined degree of hardness in a dry phase of the paper production process.
8 . The method according to claim 7 , wherein a degree of hardness of the binder is adjusted during curing of the pulp by a predetermined temperature curve.
9 . The method according to claim 1 , wherein the fiber fraction is of 30 to 60% by weight, the binder fraction is of 20 to 40% by weight, and the filler fraction is of 20 to 40% by weight.
10 . The method as recited in claim 1 wherein the precipitating of the binder by the precipitating agent includes lowering a pH of the pulp by adding an acid to the pulp to precipitate the dissolved binder.
11 . The method as recited in claim 10 wherein the acid converts the phenolate into an insoluble phenol resin.
12 . The method as recited in claim 10 wherein the acid neutralizes the pulp.
13 . The method as recited in claim 10 wherein the acid is sulfuric acid.
14 . The method as recited in claim 10 wherein the lowering of the pH of the pulp by adding the acid to the pulp to precipitate the dissolved binder is carried out in a wet phase at room temperature or ambient temperature.
15 . The method as recited in claim 1 wherein the binder is dissolved in an alkaline solution.
16 . The method as recited in claim 15 wherein the alkaline solution is a sodium or potassium hydroxide solution.
17 . The method as recited in claim 1 wherein the dissolved binder is present as a as a phenolate of a phenol resin.
18 . The method as recited in claim 1 wherein particles of the binder are precipitated with a particle size between 200 and 1600 nm as a result of the precipitation of the dissolved binder.