Rubber composition for a winter tire and a winter tire
The present invention is directed to a rubber composition comprising 35 phr to 60 phr of a first polybutadiene rubber having a glass transition temperature within a range of −80° C. to −105° C., 5 phr to 30 phr of a second polybutadiene rubber having a glass transition temperature within a range of −20° C. to −40° C., 10 phr to 60 phr of polyisoprene selected from one or more of synthetic polyisoprene and natural rubber, 30 phr to 200 phr of at least one filler, and 40 phr to 120 phr of at least one plasticizer having a glass transition temperature within a range of −40° C. to −110° C. Furthermore, the present invention is directed to a tire comprising the rubber composition.
1 . A rubber composition comprising:
35 phr to 60 phr of a first low cis polybutadiene rubber having a glass transition temperature within a range of −80° C. to −105° C., the first polybutadiene rubber being functionalized;
5 phr to 30 phr of a second high vinyl polybutadiene rubber having a glass transition temperature within a range of −20° C. to −40° C.;
10 to 60 phr of polyisoprene selected from one or more of synthetic polyisoprene and natural rubber;
30 phr to 200 phr of at least one filler; and
40 phr to 120 phr of at least one plasticizer having a glass transition temperature within a range of −40° C. to −110° C.
2 . The rubber composition according to claim 1 , wherein the first polybutadiene rubber has a vinyl content of less than 25%.
3 . The rubber composition according to claim 1 , wherein the second polybutadiene rubber has a vinyl content of at least 50%.
4 . The rubber composition according to claim 1 , wherein the rubber composition comprises more of the first polybutadiene rubber than of the polyisoprene, all by weight.
5 . The rubber composition according to claim 1 , wherein the rubber composition comprises one or more of:
from 40 to 60 phr of the first polybutadiene rubber,
from 10 to 20 phr of the second polybutadiene rubber, and
from 30 to 50 phr of the polyisoprene.
6 . The rubber composition according to claim 1 , wherein the filler comprises predominantly silica.
7 . The rubber composition according to claim 1 , wherein the rubber composition comprises 80 phr to 150 phr of silica.
8 . The rubber composition according to claim 1 , wherein the rubber composition comprises 105 phr to 140 phr of silica which has a BET surface area within a range of 90 m 2 /g to 140 m 2 /g.
9 . The rubber composition according to claim 1 , wherein said plasticizer is a liquid plasticizer.
10 . The rubber composition according to claim 1 , wherein said plasticizer comprises at least one oil having a glass transition temperature below −40° C.
11 . The rubber composition according to claim 1 comprising 55 phr to 95 phr of liquid plasticizer having a glass transition temperature within a range of −40° C. and −100° C.
12 . The rubber composition according to claim 1 , wherein said plasticizer comprises one or more of i) a first oil having a glass transition temperature within a range of −40° C. and −85° C., and ii) a second oil having a glass transition temperature within the range of −90° C. and −100° C.
13 . The rubber composition according to claim 12 , wherein the second oil is a triglyceride oil.
14 . The rubber composition according to claim 12 , wherein the first oil is a mineral oil.
15 . The rubber composition according to claim 1 , wherein the rubber composition comprises from 8 phf to 15 phf of at least one silane.
16 . A tire comprising the rubber composition according to claim 1 .
17 . The tire according to claim 16 , wherein the tire is a winter tire.
18 . The tire according to claim 16 , wherein the rubber composition is comprised in a tread of the tire.
19 . The tire according to claim 18 , wherein the rubber composition is comprised in a radially outermost layer of the tread.