Thermoplastic resin composition, method of preparing the same, and molded article including the same
The present disclosure relates to a thermoplastic resin composition, a method of preparing the same, and a molded article including the same. For example, the present disclosure relates to a thermoplastic resin composition including 35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm and 15 to 65% by weight of a polymethacrylate resin (B). The thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1. The thermoplastic resin composition may have beneficial mechanical properties, such as impact strength, tensile strength, and flexural strength, surface hardness, transparency, and colorability and may be capable of preventing occurrence of whitening during bending due to beneficial non-whitening properties.
1 . A thermoplastic resin composition, comprising:
35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm; and
15 to 65% by weight of a polymethylmethacrylate resin (B),
wherein the thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1 below:
X ={( G−Y )/ Y}× 100, [Equation 1]
wherein G represents a content (wt %) of a gel based on a total weight of the thermoplastic resin composition, and Y represents a content (wt %) of the alkyl acrylate in the gel based on the total weight of the thermoplastic resin composition,
wherein the content of the gel is measured by a method that includes: adding 1 g of a thermoplastic resin composition to 30 g of acetone, followed by stirring at room temperature for 12 hours, then performing centrifugation to separate insoluble matter that is not dissolved in acetone, followed by drying for 12 hours, and measuring and calculating the content of the gel from by Equation 2:
Content of gel (%)=[Weight (g) of insoluble matter (gel)/Weight (g) of sample]×100. [Equation 2]
2 . The thermoplastic resin composition according to claim 1 , wherein the polymethylmethacrylate resin (B) has a weight average molecular weight of 50,000 to 150,000 g/mol.
3 . The thermoplastic resin composition according to claim 1 , wherein the graft copolymer (A) comprises 20 to 60% by weight of the alkyl acrylate rubber and 40 to 80% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer (a-2).
4 . The thermoplastic resin composition according to claim 1 , wherein the graft copolymer (A) has a grafting degree of 60% or more as calculated by Equation 3 below:
Grafting degree (%)=[Weight (g) of grafted monomers/Rubber weight (g)]×100, [Equation 3]
wherein:
the weight (g) of the grafted monomers is obtained by subtracting the rubber weight (g) from a weight (g) of the gel, the gel is obtained by dissolving the graft copolymer (A) in acetone and performing centrifugation, and
the rubber weight (g) is a weight (g) of rubber components added during polymerization.
5 . The thermoplastic resin composition according to claim 1 , further comprising one or more selected from the group consisting of a heat stabilizer, a light stabilizer, a dye, a pigment, a colorant, a lubricant, a release agent, an antistatic agent, an antibacterial agent, a processing aid, a metal deactivator, a flame retardant, a smoke suppressant, an anti-drip agent, an anti-friction agent, and an anti-wear agent.
6 . The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a total light transmittance (Tt) of 75% or more as measured using a specimen having a thickness of 3T according to ASTM D1003.
7 . The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a haze of 11% or less as measured using a specimen having a thickness of 3T according to ASTM D1003.
8 . The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a gloss of 120 or more as measured at an angle of incidence of 45° according to ASTM D2457.
9 . The thermoplastic resin composition according to claim 1 , wherein:
the thermoplastic resin composition is in a form of an extruded film having dimensions of 0.15 mm×5 cm×5 cm in thickness, width, and length, and
when a 1 kg weight is vertically dropped onto the extruded film from a height of 25 cm using a Gardner impact tester, haze values before and after impact are measured for a portion of the extruded film hit by the weight according to ASTM D1003, a difference in the haze values before and after the impact is calculated, and a haze difference is 10 or less.
10 . A method of preparing a thermoplastic resin composition, comprising:
kneading and extruding, at 200 to 300° C. and 100 to 500 rpm, 35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm and 15 to 65% by weight of a polymethylmethacrylate resin (B),
wherein the thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1 below:
X ={( G−Y )/ Y}× 100, [Equation 1]
wherein G represents a content (wt %) of a gel based on a total weight of the thermoplastic resin composition, and Y represents a content (wt %) of the alkyl acrylate in the gel based on the total weight of the thermoplastic resin composition,
wherein the content of the gel is measured by a method that includes: adding 1 g of a thermoplastic resin composition to 30 g of acetone, followed by stirring at room temperature for 12 hours, then performing centrifugation to separate insoluble matter that is not dissolved in acetone, followed by drying for 12 hours, and measuring and calculating the content of the gel from by Equation 2:
Content of gel (%)=[Weight (g) of insoluble matter (gel)/Weight (g) of sample]×100. [Equation 2]
11 . A molded article, comprising the thermoplastic resin composition according to claim 1 .