Polycarbonate composition, method for the manufacture thereof, and articles formed therefrom
A polycarbonate composition includes particular amounts of a bisphenol A polycarbonate homopolymer, a particular polycarbonate-siloxane copolymer a poly(ester-carbonate), and, optionally, an organophosphorus flame retardant. Methods of making the composition and articles including the composition are also described.
1 . A polycarbonate composition comprising:
10 to 99 weight percent, based on the total weight of the polycarbonate composition, of a bisphenol A polycarbonate homopolymer;
a polycarbonate-siloxane copolymer having a siloxane content of greater than 30 to 70 weight percent, based on the total weight of the polycarbonate-siloxane copolymer;
wherein the polycarbonate-siloxane copolymer is present in an amount to provide a total siloxane content of 0.5 to 20 weight percent, based on the total weight of the polycarbonate composition;
15 to 45 weight percent of a poly(ester-carbonate); and
optionally, 0.5 to 6 weight percent, based on the total weight of the polycarbonate composition, of an organophosphorus flame retardant;
wherein a molded sample of the composition exhibits:
a tensile elongation retention of at least 80% after exposure to DOT 4 or DOT 5.1 brake fluid for 72 hours at a temperature of 23° C. under 0% strain compared to non-exposed reference sample of the same composition; and
an Izod notched impact strength of greater than 650 kilojoules per meter at a temperature of 23° C., as determined according to ASTM D256-10; and
optionally, an Izod notched impact strength of greater than 400 kilojoules per meter at a temperature of −30° C., as determined according to ASTM D256-10.
2 . The polycarbonate composition of claim 1 , wherein a molded sample of the composition exhibits
an Izod notched impact strength of greater than 400 kilojoules per meter at a temperature of −30° C., as determined according to ASTM D256-10.
3 . The polycarbonate of claim 1 , wherein the organophosphorus flame retardant is present, and wherein the polycarbonate composition further exhibits a UL-94 rating of V0 at a thickness of 1.5 millimeters or less.
4 . The polycarbonate composition of claim 1 ,
wherein the bisphenol A polycarbonate homopolymer comprises a linear bisphenol A polycarbonate homopolymer having a weight average molecular weight of 15,000 to 40,000 grams per mole, as determined by gel permeation chromatography relative to linear bisphenol A polycarbonate standards.
5 . The polycarbonate composition of claim 1 , wherein the polycarbonate-siloxane copolymer comprises bisphenol A carbonate repeating units and poly(dimethyl siloxane) repeating units.
6 . The polycarbonate composition of claim 1 , wherein the polycarbonate-siloxane copolymer has a weight average molecular weight of 17,000 to 50,000 g/mol, as determined by gel permeation chromatography using a crosslinked styrene-divinyl benzene column, at a sample concentration of 1 milligram per milliliter, and as calibrated with bisphenol A polycarbonate standards.
7 . The polycarbonate composition of claim 1 , wherein the poly(ester-carbonate) comprises a poly(phthalate-carbonate).
8 . The polycarbonate composition of claim 1 , wherein the organophosphorus flame retardant is present and comprises a phosphazene, a phosphate ester, an oligomeric phosphate ester, or a combination thereof.
9 . The polycarbonate composition of claim 1 , wherein one or more of the bisphenol A homopolymer carbonate, the polycarbonate-siloxane copolymer, and the poly(ester-carbonate) are derived from post-consumer recycled or post-industrial recycled materials or can be produced from at least one monomer derived from bio-based or plastic waste feedstock.
10 . The polycarbonate composition of claim 1 , wherein the polycarbonate composition further comprises 0.1 to 10 weight percent, based on the total weight of the polycarbonate composition, of an additive composition.
11 . The polycarbonate composition of claim 1 , wherein the polycarbonate composition further comprises 0.001 to 10 weight percent of an antimicrobial agent.
12 . The polycarbonate composition of claim 1 , comprising
25 to 75 weight percent of the bisphenol A polycarbonate homopolymer;
5 to 20 weight percent of the polycarbonate-siloxane copolymer; and
20 to 40 weight percent of the poly(ester carbonate).
13 . The polycarbonate composition of claim 12 , wherein
the bisphenol A polycarbonate homopolymer comprises a linear bisphenol A polycarbonate homopolymer having a weight average molecular weight of 26,000 to 40,000 grams per mole, as determined by gel permeation chromatography relative to linear bisphenol A polycarbonate standards;
the polycarbonate-siloxane copolymer comprises bisphenol A carbonate repeating units and poly(dimethyl siloxane) repeating units;
the polycarbonate-siloxane copolymer has a siloxane content of 35 to 65 weight percent based on the total weight of the polycarbonate-siloxane copolymer;
the poly(ester-carbonate) comprises a poly(phthalate-carbonate); and
when present, the organophosphorus flame retardant comprises a cyclic phosphazene, preferably hexaphenoxycyclotriphosphazene, or an oligomeric phosphate ester flame retardant comprising 5 to 15 weight percent phosphorus, based on the total weight of the oligomeric phosphate ester, preferably wherein the oligomeric phosphate ester is a solid at room temperature; wherein a molded sample of the polycarbonate composition exhibits:
a tensile elongation retention of at least 80% after exposure to DOT 4 or DOT 5.1 brake fluid for 72 hours at a temperature of 23° C. under 0% strain compared to non-exposed reference sample of the same composition;
an Izod notched impact strength of greater than 650 joules per meter at a temperature of 23° C., as determined according to ASTM D256-10;
an Izod notched impact strength of greater than 400 joules per meter at a temperature of −30° C., as determined according to ASTM D256-10; and
when the organophosphorus flame retardant is present, a UL-94 rating of V0 at a thickness of 1.5 millimeters or less.
14 . A method of making the polycarbonate composition of claim 1 , the method comprising melt-mixing the components of the composition, and, optionally, extruding the composition.
15 . An article comprising the polycarbonate composition of claim 1 .
16 . The polycarbonate composition of claim 1 , comprising
40 to 90 weight percent of the bisphenol A polycarbonate homopolymer;
20 to 15 weight percent of the polycarbonate-siloxane copolymer;
20 to 40 weight percent of the poly(ester carbonate); and
1 to 6 weight percent of the organophosphorus flame retardant.