Adjoint automatic monitoring device and method for deposition rate of salt mist
The present disclosure provides an adjoint automatic monitoring device and method for a deposition rate of salt mist. The adjoint automatic monitoring device includes: a wet candle method-based salt mist deposition rate acquisition unit, a single chip, a digital-to-analog (D/A) conversion circuit, and a data acquisition module. According to the present disclosure, a current value and a height variation of a solution in a trapping pool of the wet candle method-based salt mist deposition rate acquisition unit are acquired by the data acquisition module, and then the deposition rate of salt mist is calculated by the single chip. Real-time online monitoring of the deposition rate of salt mist is realized.
1 . An automatic monitoring device for a deposition rate of salt mist, comprising a wet candle method-based salt mist deposition rate acquisition unit, a single chip, a digital-to-analog (D/A) conversion circuit, and a data acquisition module;
wherein the single chip is connected to the D/A conversion circuit; the D/A conversion circuit is connected to the wet candle method-based salt mist deposition rate acquisition unit; the single chip is configured to send a digital signal instruction; the D/A conversion circuit is configured to convert the digital signal instruction into an analog signal instruction and send the analog signal instruction to the wet candle method-based salt mist deposition rate acquisition unit;
the data acquisition module is connected to a chloride ion selective electrode of the wet candle method-based salt mist deposition rate acquisition unit and the single chip separately; the data acquisition module is configured to acquire a current value and a liquid level height variation of a solution in a trapping pool output by the wet candle method-based salt mist deposition rate acquisition unit; and the single chip is configured to calculate a deposition rate of salt mist based on the current value and the liquid level height variation.
2 . The automatic monitoring device for a deposition rate of salt mist according to claim 1 , wherein the data acquisition module comprises a current-to-voltage (I/V) conversion circuit, a two-stage amplifying circuit, and an analog-to-digital (A/D) conversion circuit.
3 . The automatic monitoring device for a deposition rate of salt mist according to claim 1 , further comprising: a device base, a device top cover, a temperature and humidity sensor, a lithium battery pack, a switch, a circular connector, and an organic light-emitting diode (OLED) display module;
wherein the wet candle method-based salt mist deposition rate acquisition unit is fixed to the device base; a gauze for depositing salt mist in an environment into a solution in the wet candle method-based salt mist deposition rate acquisition unit is exposed to the environment through a through hole formed in the device top cover and covered with a metal mesh enclosure;
the temperature and humidity sensor is disposed on the device top cover;
the lithium battery pack is disposed in the device base, and connected to the wet candle method-based salt mist deposition rate acquisition unit, the temperature and humidity sensor, the single chip, the D/A conversion circuit, the data acquisition module, and the OLED display module;
the switch and the circular connector are both disposed on a sidewall of the device base; the switch is connected to a power output terminal of the lithium battery pack; the circular connector is connected to the single chip through an RS422 serial port module and configured for connection with an external apparatus; and
the OLED display module is disposed on the device top cover and connected to the single chip.
4 . The automatic monitoring device for a deposition rate of salt mist according to claim 1 , wherein the wet candle method-based salt mist deposition rate acquisition unit comprises a wet candle, the gauze, a trapping pool, the chloride ion selective electrode, and a liquid level height detection module;
the gauze has one end wound around the wet candle and the other end deposited into the solution in the trapping pool and serves for depositing the salt mist in the environment into the solution;
the chloride ion selective electrode has one end placed deep into the solution in the trapping pool and is configured to sense a current value of the solution in the trapping pool;
the liquid level height detection module is disposed on an outer side of the trapping pool and configured to sense a height variation of the solution in the trapping pool; and
the current value and the height variation are used for calculating the deposition rate of salt mist.
5 . The automatic monitoring device for a deposition rate of salt mist according to claim 4 , wherein the trapping pool comprises a trapping pool body and a trapping pool top cover;
a sealing ring is disposed between the trapping pool body and the trapping pool top cover;
a taper hole is formed in the trapping pool top cover; and the other end of the gauze passes through the taper hole to be placed into the solution in the trapping pool body.
6 . The automatic monitoring device for a deposition rate of salt mist according to claim 5 , wherein an injection hole is further formed in the trapping pool top cover and sealed with a sealing plug.
7 . The automatic monitoring device for a deposition rate of salt mist according to claim 1 , wherein a formula for calculating the deposition rate of salt mist is as follows:
S
d
=
m
t
-
m
0
At
;
m
t
=
35.5
×
10
I
cl
-
0.19822
0.02848
×
1
2
×
(
3
-
Δ
h
)
;
wherein S d represents the deposition rate of salt mist, and m t a mass of chloride ions in the solution in the trapping pool at time t, m 0 an initial mass of chloride ions in the solution in the trapping pool, A an exposed surface area of the gauze, I Cl the sensed current value of the solution in the trapping pool, Δh the height variation of the solution in the trapping pool, wherein a unit of m t and m 0 is mg, a unit of A is cm 2 , a unit of I Cl is μA, and a unit of Δh is cm.
8 . An automatic monitoring method for a deposition rate of salt mist, comprising the following steps:
arranging a wet candle method-based salt mist deposition rate acquisition unit in an environment to be measured;
acquiring a current value and a height variation of a solution in a trapping pool of the wet candle method-based salt mist deposition rate acquisition unit in real time;
calculating a concentration logarithm of chloride ions of the solution in the trapping pool by using a calibration relationship according to the current value, wherein the calibration relationship is used for characterizing a relationship between a current and a concentration of chloride ions; and
calculating the deposition rate of salt mist based on the concentration logarithm of chloride ions and the height variation of the solution in the trapping pool.
9 . The automatic monitoring method for a deposition rate of salt mist according to claim 8 , wherein the calibration relationship is as follows: I Cl =0.02848C+0.19822;
wherein I Cl represents a sensed current value of the solution in the trapping pool, and C the concentration logarithm of chloride ions.
10 . The automatic monitoring method for a deposition rate of salt mist according to claim 8 , wherein a formula for calculating the deposition rate of salt mist is as follows:
S
d
=
m
t
-
m
0
At
;
m
t
=
35.5
×
10
I
cl
-
0.19822
0.02848
×
1
2
×
(
3
-
Δ
h
)
;
wherein S d represents the deposition rate of salt mist, and m t a mass of chloride ions in the solution in the trapping pool at time t, m 0 an initial mass of chloride ions in the solution in the trapping pool, A an exposed surface area of the gauze, I Cl the sensed current value of the solution in the trapping pool, Δh the height variation of the solution in the trapping pool, wherein a unit of m t and m 0 is mg, a unit of A is cm 2 , a unit of I Cl is μA, and a unit of Δh is cm.