Electrochemical apparatus and electronic apparatus
An electrochemical apparatus, including a positive electrode, a negative electrode, and an electrolyte. The negative electrode includes a negative electrode current collector and a negative electrode active substance layer formed on the negative electrode current collector. The negative electrode current collector has a high tensile strength and the negative electrode active substance layer has a specific weight. The electrochemical apparatus has improved high-temperature storage expansion performance and cyclic expansion performance.
1 . An electrochemical apparatus, comprising: a positive electrode, a negative electrode, and an electrolyte; wherein the negative electrode comprises a negative electrode current collector and a negative electrode active substance layer formed on the negative electrode current collector;
wherein
the negative electrode current collector has a tensile strength of F N/mm 2 , wherein F is greater than 400;
wherein a weight per unit area of the negative electrode active substance layer is W mg/cm 2 , wherein W is within a range of 3 to 12;
wherein a density of the negative electrode active substance layer is D g/cm 3 , and D is within a range of 1.7 to 2.0, wherein 900≤F×D≤1200;
wherein the electrolyte comprises a compound having cyano group, and wherein based on a weight of the electrolyte, a content percentage of the compound having cyano group is b % and b is within a range of 3.5 to 10,
wherein the negative electrode current collector comprises copper and a first metal, the first metal comprises silver and tin, and based on the weight of the negative electrode current collector, a content percentage of the first metal is a %, wherein a is within a range of 0.01 to 0.5;
wherein the negative electrode current collector further comprises at least one rare earth element, and the rare earth element comprises yttrium.
2 . The electrochemical apparatus according to claim 1 , wherein 4≤F×a≤200.
3 . The electrochemical apparatus according to claim 1 , wherein 100/3≤F/W≤200.
4 . The electrochemical apparatus according to claim 1 , wherein the negative electrode current collector has at least one of the following characteristics:
1) An average surface roughness is 0.05 μm to 1.5 μm;
2) a 0.2% endurance is greater than 30 N/mm 2 ; or
3) a thickness is 1 μm to 100 μm.
5 . The electrochemical apparatus according to claim 1 , wherein the negative electrode active substance layer has at least one of the following characteristics:
a) a reflectance Ra at a wavelength of 550 nm is 7% to 15%; or
b) a porosity Pa is 20% to 40%.
6 . The electrochemical apparatus according to claim 1 , wherein the electrolyte further comprises at least one of the following compounds:
i. propionate;
ii. lithium difluorophosphate; or
iii. a compound of Formula 1:
wherein,
W is
each L is independently a single bond or methylene;
m is 1, 2, 3, or 4; and
n is 0, 1, or 2.
7 . The electrochemical apparatus according to claim 6 , wherein the compound of Formula 1 comprises at least one of the following compounds:
8 . The electrochemical apparatus according to claim 6 , wherein 1≤b/a≤300.
9 . The electrochemical apparatus according to claim 6 , wherein 0.5≤W/b≤24.
10 . An electronic apparatus, comprising: an electrochemical apparatus; wherein the electrochemical apparatus comprises a positive electrode, a negative electrode, and an electrolyte; the negative electrode comprises a negative electrode current collector and a negative electrode active substance layer formed on the negative electrode current collector;
wherein the negative electrode current collector has a tensile strength of F N/mm 2 , wherein F is greater than 400;
wherein a weight per unit area of the negative electrode active substance layer is W mg/cm 2 , wherein W is within a range of 3 to 12;
wherein a density of the negative electrode active substance layer is D g/cm 3 , and D is within a range of 1.7 to 2.0, wherein 900≤F×D<1200;
wherein the electrolyte comprises a compound having cyano group, and wherein based on a weight of the electrolyte, a content percentage of the compound having cyano group is b % and b is within a range of 3.5 to 10,
wherein the negative electrode current collector comprises copper and a first metal, the first metal comprises silver and tin, and based on the weight of the negative electrode current collector, a content percentage of the first metal is a %, wherein a is within a range of 0.01 to 0.5; and
wherein the negative electrode current collector further comprises at least one rare earth element, and the rare earth element comprises yttrium.
11 . The electronic apparatus according to claim 10 , wherein 100/3≤F/W≤200.
12 . The electronic apparatus according to claim 10 , wherein the negative electrode current collector has at least one of the following characteristics:
1) An average surface roughness is 0.05 μm to 1.5 μm;
2) a 0.2% endurance is greater than 30 N/mm 2 ; or
3) a thickness is 1 μm to 100 μm.
13 . The electrochemical apparatus according to claim 1 , wherein b is within a range of 7.5 to 10.