IP Library Granted Patent US 12701856
Granted Patent B2
US 12701856 · App. 18/396,801 · Granted Aug 4, 2026

Light-emitting element, light-emitting device, electronic device, and lighting device

Inventors: Hiromi Nowatari (Atsugi, JP); Satoshi Seo (Kawasaki, JP); Nobuharu Ohsawa (Zama, JP); Takahiro Ushikubo (Atsugi, JP); Tetsuo Tsutsui (Kasuga, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H10K50/13B82Y10/00H10K50/11H10K50/131H10K50/19H10K85/221H10K85/324H10K85/615H10K85/621H10K85/626H10K85/633H10K85/636H10K85/6572H10K2101/40
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Quick Facts
Patent No.
US 12701856
App. No.
18/396,801
Granted
Aug 4, 2026
Kind
B2
Abstract

An object is to provide a light-emitting element capable of emitting light with a high luminance even at a low voltage, and having a long lifetime. The light-emitting element includes n EL layers between an anode and a cathode (n is a natural number of two or more), and also includes, between m-th EL layer from the anode and (m+1)-th EL layer (m is a natural number, 1≤m≤n−1), a first layer including a first donor material in contact with the m-th EL layer, a second layer including an electron-transport material and a second donor material in contact with the first layer, and a third layer including a hole-transport material and an acceptor material in contact with the second layer and the (m+1)-th EL layer.

Claims (65)

1 . A light-emitting device comprising:

a first electrode;

a first hole-transport layer over the first electrode;

a first light-emitting layer over the first hole-transport layer;

a first electron-transport layer over the first light-emitting layer;

an intermediate layer over the first electron-transport layer, the intermediate layer comprising:

a first region comprising a first electron-transport material;

a second region comprising a second electron-transport material; and

a third region comprising a hole-transport material and a first substance;

a second hole-transport layer over the intermediate layer;

a second light-emitting layer over the second hole-transport layer; and

a second electrode over the second light-emitting layer,

wherein the first region comprises one of an alkaline metal element and an alkaline earth metal element,

wherein the second electron-transport material has one of a perylene skeleton and a phenanthroline skeleton, and

wherein the first substance is a compound having one of a cyano group and a fluoro group or a transition metal oxide compound.

2 . The light-emitting device according to claim 1 , further comprising:

a second electron-transport layer over the second light-emitting layer;

a third hole-transport layer over the second electron-transport layer; and

a third light-emitting layer between the third hole-transport layer and the second electrode.

3 . The light-emitting device according to claim 1 , wherein the one of the perylene skeleton and the phenanthroline skeleton is substituted with one of a cyano group and a fluoro group.

4 . The light-emitting device according to claim 1 , wherein the second electron-transport material has a LUMO level greater than or equal to −5.0 eV and lower than or equal to −3.0 eV.

5 . The light-emitting device according to claim 1 , wherein the third region is in contact with the second hole-transport layer.

6 . An electronic device comprising the light-emitting device according to claim 1 .

7 . A light-emitting device comprising:

a first electrode;

a first electroluminescent unit over the first electrode;

a first intermediate layer over the first electroluminescent unit, the first intermediate layer comprising:

a first region comprising a first electron-transport material;

a second region comprising a second electron-transport material; and

a third region comprising a hole-transport material and a first substance;

a second electroluminescent unit over the first intermediate layer; and

a second electrode over the second electroluminescent unit,

wherein the first region comprises one of an alkaline metal element and an alkaline earth metal element,

wherein the second electron-transport material has one of a perylene skeleton and a phenanthroline skeleton, and

wherein the first substance is a compound having one of a cyano group and a fluoro group or a transition metal oxide compound.

8 . The light-emitting device according to claim 7 , further comprising:

a second intermediate layer between the second electroluminescent unit and the second electrode, the second intermediate layer comprising the first electron-transport material, the second electron-transport material, the hole-transport material and the first substance; and

a third electroluminescent unit between the second intermediate layer and the second electrode.

9 . The light-emitting device according to claim 7 , wherein the one of the perylene skeleton and the phenanthroline skeleton is substituted with one of a cyano group and a fluoro group.

10 . The light-emitting device according to claim 7 , wherein the second electron-transport material has a LUMO level greater than or equal to −5.0 eV and lower than or equal to −3.0 eV.

11 . The light-emitting device according to claim 7 , wherein the third region is in contact with the second electroluminescent unit.

12 . An electronic device comprising the light-emitting device according to claim 7 .

13 . A light-emitting device comprising:

a first electrode;

a first hole-transport layer over the first electrode;

a first light-emitting layer over the first hole-transport layer;

a first electron-transport layer over the first light-emitting layer;

an intermediate layer over the first electron-transport layer, the intermediate layer comprising:

a first region comprising a first electron-transport material;

a second region comprising a second electron-transport material; and

a third region comprising a hole-transport material and a first substance;

a second hole-transport layer over the intermediate layer;

a second light-emitting layer over the second hole-transport layer; and

a second electrode over the second light-emitting layer,

wherein the first region comprises one of an alkaline metal element and an alkaline earth metal element,

wherein the second electron-transport material has one of a perylene skeleton and a nitrogen-containing condensed aromatic ring skeleton,

wherein the second electron-transport material has a LUMO level greater than or equal to −5.0 eV and lower than or equal to −3.0 eV, and

wherein the first substance is a compound having one of a cyano group and a fluoro group or a transition metal oxide compound.

14 . The light-emitting device according to claim 13 , further comprising:

a second electron-transport layer over the second light-emitting layer;

a third hole-transport layer over the second electron-transport layer; and

a third light-emitting layer between the third hole-transport layer and the second electrode.

15 . The light-emitting device according to claim 13 , wherein the one of the perylene skeleton and the nitrogen-containing condensed aromatic ring skeleton is substituted with one of a cyano group and a fluoro group.

16 . The light-emitting device according to claim 13 , wherein the third region is in contact with the second hole-transport layer.

17 . An electronic device comprising the light-emitting device according to claim 13 .