System and method for purifying hydrogen, and system for producing hydrogen by water electrolysis
Disclosed are a system and method for purifying hydrogen, and a system for producing hydrogen by water electrolysis. The system for purifying hydrogen includes three dryers, and the three dryers share one regeneration cycle module. This significantly reduces a quantity of regeneration cycle modules, and therefore, manufacturing cost of the system is relatively low. In addition, a first gas-gas heat exchanger ( 4 ) is arranged in a regeneration cycle system, so that heat exchange can be performed between low-temperature regeneration hydrogen before regeneration and high-temperature regeneration tail gas after regeneration. In this way, residual heat of the high-temperature regeneration tail gas can be fully utilized, and power consumption of a subsequent heater and regeneration cooler can be significantly reduced. Therefore, energy consumption of the system is relatively low.
1 . A system for purifying a feed stream comprising hydrogen, wherein the system comprises:
a drying module comprising a first dryer and a second dryer;
a regeneration cycle module connected to the drying module, wherein the regeneration cycle module comprises a first heat exchanger having a first gas channel and a second gas channel;
a first stream control module configured to introduce the feed stream into the first dryer to produce a purified hydrogen stream; and
a second stream control module configured to:
introduce a first portion of the purified hydrogen stream into the first gas channel of the first heat exchanger to heat the first portion of the purified hydrogen stream;
introduce the first portion of the purified hydrogen stream after heating into the second dryer to regenerate a desiccant in the second dryer; and
introduce a regeneration tail gas of the second dryer into the second gas channel of the first heat exchanger to exchange heat with the first gas channel of the first heat exchanger, wherein the regeneration tail gas comprises the first portion of the purified hydrogen stream that passes through the second dryer.
2 . The system according to claim 1 , wherein the drying module comprises a third dryer, wherein the second stream control module is configured to:
introduce the regeneration tail gas of the second dryer from the second gas channel of the first heat exchanger into the third dryer to produce a recycled hydrogen stream.
3 . The system according to claim 2 , wherein the first dryer, the second dryer, and the third dryer are connected to the regeneration cycle module in parallel.
4 . The system according to claim 2 , wherein the system further comprises a deoxygenation module for removing oxygen from the feed stream, wherein the first stream control module is configured to introduce the feed stream into the deoxygenation module before introducing the feed stream into the first dryer.
5 . The system according to claim 4 , wherein the deoxygenation module comprises a deoxygenator and a second heat exchanger, wherein the first stream control module is configured to:
introduce the feed stream into a first gas channel of the second heat exchanger to heat the feed stream;
introduce the feed stream after heating into the deoxygenator to remove oxygen from the feed stream; and
introduce the feed stream from the deoxygenator into a second gas channel of the second heat exchanger to exchange heat with the first gas channel of the second heat exchanger.
6 . The system according to claim 4 , wherein the first dryer, the second dryer, and the third dryer each have a first opening and a second opening,
wherein the first opening of the first dryer, the first opening of the second dryer, and the first opening of the third dryer are each connected to:
an outlet of the deoxygenation module;
an inlet of the second gas channel of the first heat exchanger; and
an outlet of the second gas channel of the first heat exchanger, and
wherein the second opening of the first dryer, the second opening of the second dryer, and the second opening of the third dryer are each connected to:
a first outlet for outputting the purified hydrogen stream;
an inlet of the first gas channel of the first heat exchanger; and
a second outlet for outputting the recycled hydrogen stream.
7 . The system according to claim 6 , wherein the first stream control module comprises a first control valve located in at least one of the following positions:
between the outlet of the deoxygenation module and the first openings of the first dryer, the second dryer and the third dryer; or
between the first outlet and the second openings of the first dryer, the second dryer and the third dryer.
8 . The system according to claim 6 , wherein the second stream control module comprises a second control valve located in one of the following positions:
between the inlet of the first gas channel of the first heat exchanger and the second openings of the first dryer, the second dryer and the third dryer;
between the inlet of the second gas channel of the first heat exchanger and the first openings of the first dryer, the second dryer and the third dryer;
between the outlet of the second gas channel of the first heat exchanger and the first openings of the first dryer, the second dryer and the third dryer; or
between the second outlet and the second openings of the first dryer, the second dryer and the third dryer.
9 . The system according to claim 1 , wherein the regeneration cycle module further comprises a heater for heating the first portion of the purified hydrogen stream, and wherein the second stream control module is configured to:
prior to introducing the first portion of the purified hydrogen stream into the second dryer, introduce the first portion of the purified hydrogen stream from the first gas channel of the first heat exchanger into the heater.
10 . The system according to claim 2 , wherein the regeneration cycle module further comprises a cooler, and
wherein the system further comprises a third stream control module configured to sequentially introduce a second portion of the purified hydrogen stream into:
the cooler to cool the second portion of the purified hydrogen stream;
the second dryer to cool the desiccant in the second dryer; and
the second gas channel of the first heat exchanger to exchange heat with the first gas channel of the first heat exchanger.
11 . The system according to claim 10 , wherein an inlet of the cooler is connected to a second opening of the first dryer, a second opening of the second dryer, and a second opening of the third dryer, and
wherein an outlet of the cooler is connected to the second opening of the first dryer, the second opening of the second dryer, and the second opening of the third dryer.
12 . The system according to claim 11 , wherein the third stream control module comprises a third control valve, wherein the third control valve is located in one of the following positions:
between the inlet of the cooler and the second openings of the first dryer, the second dryer and the third dryer; or
between the outlet of the cooler and the second openings of the first dryer, the second dryer and third dryer.
13 . A method for purifying a feed stream comprising hydrogen, comprising:
introducing the feed stream into a first dryer to produce a purified hydrogen stream;
regenerating a desiccant in a second dryer using a first portion of the purified hydrogen stream, comprising:
introducing the first portion of the purified hydrogen stream into a first gas channel of a first heat exchanger to heat the first portion of the purified hydrogen stream;
introducing the first portion of the purified hydrogen stream after heating into the second dryer to regenerate the desiccant; and
introducing a regeneration tail gas from the second dryer into a second gas channel of the first heat exchanger to exchange heat with the first gas channel of the first heat exchanger, wherein the first portion of the purified hydrogen stream is comprised in the regeneration tail gas.
14 . The method of claim 13 , further comprising recycling the first portion of the purified hydrogen stream, comprising:
introducing the regeneration tail gas from the second dryer into a third dryer to produce a recycled hydrogen stream.
15 . The method of claim 14 , wherein recycling the first portion of the purified hydrogen stream further comprises:
prior to introducing the regeneration tail gas into the third dryer, introducing the regeneration tail gas into a first cooler for condensation treatment and into a moisture separator for separating moisture from the first portion of hydrogen stream comprised in the regeneration tail gas.
16 . The method of claim 13 , further comprising:
prior to introducing the feed stream into the first dryer, introducing the feed stream into a deoxygenator to remove oxygen from the feed stream.
17 . The method of claim 16 , further comprising:
prior to introducing the feed stream into the deoxygenator, introducing the feed stream into a first gas channel of a second heat exchanger to heat the feed stream; and
after introducing the feed stream into the deoxygenator to produce a deoxygenated stream, introducing the deoxygenated stream into a second gas channel of the second heat exchanger to exchange heat with the first gas channel of the second heat exchanger.
18 . The method of claim 13 , wherein a volume of the first portion of the purified hydrogen stream accounts for 10% to 15% of a volume of the purified hydrogen stream.
19 . The method of claim 13 , further comprising:
cooling the desiccant in the second dryer using a second portion of the purified hydrogen stream, comprising:
introducing the second portion of the purified hydrogen stream into a second cooler to cool the second portion of the purified hydrogen stream;
introducing the second portion of the purified hydrogen stream after cooling into the second dryer to cool the desiccant in the second dryer; and
introducing the second portion of the purified hydrogen stream from the second dryer to the second gas channel of the first heat exchanger to exchange heat with the first gas channel of the first heat exchanger.
20 . A system for producing hydrogen by water electrolysis, comprising:
a water electrolysis module for producing a feed stream comprising hydrogen;
a deoxygenation module for removing oxygen from the feed stream;
a drying module for removing water vaper from the feed stream, wherein the drying module comprises a first dryer and a second dryer;
a regeneration cycle module for regenerating desiccants in the drying module, wherein the regeneration cycle module comprises a first heat exchanger having a first gas channel and a second gas channel;
a first stream control module configured to introduce the feed stream into the deoxygenation module and the first dryer to produce a purified hydrogen stream; and
a second stream control module configured to:
introduce a portion of the purified hydrogen stream into the first gas channel of the first heat exchanger to heat the portion of the purified hydrogen stream;
introduce the portion of the purified hydrogen stream after heating into the second dryer to regenerate a desiccant in the second dryer; and
introduce a regeneration tail gas of the second dryer into the second gas channel of the first heat exchanger to exchange heat with the first gas channel of the first heat exchanger, wherein the regeneration tail gas comprises the portion of the purified hydrogen stream that passes through the second dryer.