Method of producing lithium sulfide without using hydrogen sulfide gas
Disclosed is a method of producing lithium sulfide (Li 2 S) without using hydrogen sulfide (H 2 S) gas. Particularly, the method of producing lithium sulfide (Li 2 S) includes preparing a starting material including a metal oxide by subjecting a mixed powder including an inorganic compound containing lithium and oxygen, a metal reducing agent, and sulfur (S) to synthesis reaction using mechanical force, preparing a mixed solution by mixing the starting material and a solvent, and obtaining a lithium sulfide (Li 2 S) powder by removing the metal oxide from the mixed solution and then performing drying.
1 . A method of producing lithium sulfide (Li 2 S) comprising:
preparing a starting material by subjecting a mixed powder to synthesis reaction, wherein the starting material includes a metal oxide, and wherein the mixed powder includes an inorganic compound comprising lithium and oxygen, a metal reducing agent, and sulfur (S);
preparing a mixed solution by mixing the starting material and a solvent; and
obtaining a lithium sulfide (Li 2 S) powder by removing the metal oxide and drying the mixed solution.
2 . The method of claim 1 , wherein the inorganic compound is selected from the group consisting of Li 2 O, Li 2 O 2 , LiOH, LiCO 3 , Li 2 CO 3 , LiNO 3 , and Li 2 SO 4 .
3 . The method of claim 1 , wherein the metal reducing agent is selected from the group consisting of magnesium (Mg) powder, aluminum (Al) powder, silicon (Si) powder, and combinations thereof.
4 . The method of claim 1 , wherein the mixed powder further comprises carbon.
5 . The method of claim 1 , wherein the mixed powder comprises the inorganic compound, the metal reducing agent, and the sulfur (S) in a ratio of 1-3:1-6:0-4.
6 . The method of claim 1 , wherein the starting material is prepared using mechanical force, the mechanical force being produced by using any one selected from the group consisting of a planetary mill, a vibration mill, an attrition mill, and combinations thereof.
7 . The method of claim 1 , wherein preparing the starting material is performed at room temperature for 1 to 300 minutes.
8 . The method of claim 1 , wherein preparing the starting material is performed in a sealed state.
9 . The method of claim 1 , wherein the starting material comprises lithium sulfide (Li 2 S) and the metal oxide.
10 . The method of claim 1 , wherein the metal oxide comprises magnesium oxide, aluminum oxide, silicon oxide, or a composite oxide thereof.
11 . The method of claim 1 , wherein the solvent comprises at least one selected from the group consisting of ethanol, methanol, isopropyl alcohol, and combinations thereof.
12 . The method of claim 1 , wherein obtaining the lithium sulfide (Li 2 S) powder comprises removing the metal oxide from the mixed solution using at least one process selected from the group consisting of precipitation, centrifugation, and filtration.
13 . The method of claim 1 , wherein obtaining the lithium sulfide (Li 2 S) powder comprises drying the mixed solution from which the metal oxide is removed through heat treatment in a vacuum at a temperature ranging from room temperature to 400° C. for 1 hour to 24 hours.
14 . The method of claim 1 , wherein hydrogen sulfide is not used as a reactant.