Electrophotographic ink compositions
A method of producing a liquid electrophotographic ink composition includes combining a pigment with a charge director in a carrier liquid to produce a pigment dispersion; and combining a thermoplastic resin with the pigment dispersion to produce a liquid electrophotographic ink composition; wherein the charge director comprises a metal salt of a sulfonic acid. A method of printing the liquid electrophotographic ink composition and a printing set comprising the liquid electrophotographic ink composition are also included.
1 . A method of producing a liquid electrophotographic ink composition, comprising:
combining a pigment with a charge director in a carrier liquid, and grinding the pigment with the charge director to produce a pigment dispersion including a pre-treated pigment therein;
combining a thermoplastic resin with the carrier liquid to produce a thermoplastic resin paste; and
combining the thermoplastic resin paste, the pigment dispersion, a charge adjuvant, and the carrier liquid, and grinding the thermoplastic resin paste, the pigment dispersion, and the charge adjuvant to produce a liquid electrophotographic ink composition;
wherein the charge director consists of a metal salt of a sulfonic acid.
2 . The method according to claim 1 , wherein the pigment dispersion is produced by dissolving the charge director in the carrier liquid to form a charge director solution before combining the pigment with the charge director solution.
3 . The method according to claim 1 , wherein the sulfonic acid is selected from C1 to C30 alkyl sulfonic acids.
4 . The method according to claim 1 , wherein a metal of the metal salt is selected from the group consisting of calcium, barium, sodium and aluminium.
5 . The method according to claim 1 , wherein the charge director is present in an amount of up to 20 mg/g solids of the liquid electrophotographic ink composition.
6 . A method of liquid electrophotographic printing, the method comprising:
combining a charging composition with the liquid electrophotographic ink composition produced according to the method of claim 1 to form a print ready liquid electrophotographic ink composition; and
liquid electrophotographically printing the print ready liquid electrophotographic ink composition;
wherein the charging composition comprises:
a lecithin;
a sulfonic acid amine salt; and
a metal salt of a sulfonic acid.
7 . The method according to claim 6 , wherein the sulfonic acid is selected from C1 to C30 alkyl sulfonic acids.
8 . A liquid electrophotographic printing set, comprising:
the liquid electrophotographic ink composition produced according to the method of claim 1 ; and
a charging composition, comprising:
a lecithin;
a sulfonic acid amine salt; and
a metal salt of a sulfonic acid.
9 . The liquid electrophotographic printing set according to claim 8 , wherein the sulfonic acid is selected from C1 to C30 alkyl sulfonic acids.
10 . The method according to claim 1 , wherein the charge adjuvant is aluminum di-stearate or aluminum tri-stearate.
11 . The method according to claim 1 , wherein the charge adjuvant is a combination of aluminum stearate and aluminum palmitate.